RUST-OLEUM 366439 High Performance Wheel Spray Paint Owner’s Manual

RUST-OLEUM 366439 High Performance Wheel Spray Paint

Identification

USA
Preparer:| Regulatory Department
Emergency Telephone:| 24 Hour Hotline: 847-367-7700
Revision Date:| 12/6/2022
Super cedes Date:| 9/14/2022
Manufacturer:| Rust-Oleum Corporation 11 Hawthorn Parkway Vernon Hills, IL 60061 USA

Hazards Identification

Classification

Symbol(s) of Product

Signal Word
Danger

Possible Hazards
25% of the mixture consists of ingredient(s) of unknown acute toxicity

GHS HAZARD STATEMENTS

explode if heated.
Reproductive Toxicity, category 2| H361| Suspected of damaging fertility or the unborn child.
STOT, Repeated Exposure, category 2| H373| May cause damage to organs through prolonged or repeated exposure.
STOT, Single Exposure, category 3, NE| H336| May cause drowsiness or dizziness.

GHS LABEL PRECAUTIONARY STATEMENTS

P201 Obtain special instructions before use.
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. NO SMOKING.
P211 Do not spray on an open flame or other ignition source.
P251 Do not pierce or burn, even after use.
P260 Do not breathe dust/fume/gas/mist/vapors/spray.
P264 Wash hands thoroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P308+P313 IF exposed or concerned: Get medical advice/attention.
P312 Call a POISON CENTER or doctor/physician if you feel unwell.
P337+P313 If eye irritation persists: Get medical advice/attention.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P405 Store locked up.
P410+P403 Protect from sunlight. Store in a well-ventilated place.
P410+P412 Protect from sunlight. Do not expose to temperatures exceeding 50°C (122°F).
P501 Dispose of contents/container in accordance with local, regional and national regulations.

Composition / Information on Ingredients

HAZARDOUS SUBSTANCES

Chemical Name| CAS-No.| Wt.%
Range| GHS Symbols| GHS Statements
---|---|---|---|---
Acetone| 67-64-1| 25-50| GHS02-GHS07| H225-319-332-336
Propane| 74-98-6| 10-25| GHS04| H280
n-Butyl Acetate| 123-86-4| 2.5-10| GHS02-GHS07| H226-336
Toluene| 108-88-3| 2.5-10| GHS02-GHS07-
GHS08| H225-304-315-332-336-361-373
n-Butane| 106-97-8| 2.5-10| GHS04| H280
Dimethyl Carbonate| 616-38-6| 2.5-10| GHS02-GHS06| H225-331
Methyl n-Amyl Ketone| 110-43-0| 2.5-10| GHS02-GHS07| H226-302-332-336

First-Aid Measures

FIRST AID – EYE CONTACT: Immediately flush eyes with plenty of water for at least 15 minutes holding eyelids open. Get medical attention. Do NOT allow rubbing of eyes or keeping eyes closed.
FIRST AID – SKIN CONTACT: Wash skin with soap and water. Remove contaminated clothing. Get medical attention if irritation develops or persists.
FIRST AID – INHALATION: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get immediate medical attention. Do NOT use mouth-to-mouth resuscitation. If you experience difficulty in breathing, leave the area to obtain fresh air. If continued difficulty is experienced, get medical assistance immediately.
FIRST AID – INGESTION: Aspiration hazard: Do not induce vomiting or give anything by mouth because this material can enter the lungs and cause severe lung damage. Get immediate medical attention. If swallowed, get medical attention.

Fire-Fighting Measures

EXTINGUISHING MEDIA: Alcohol Film Forming Foam, Carbon Dioxide, Dry Chemical, Dry Sand, Water Fog
UNUSUAL FIRE AND EXPLOSION HAZARDS: FLASH POINT IS LESS THAN -7°C (20°F). EXTREMELY FLAMMABLE LIQUID AND VAPOR!Water spray may be ineffective. Closed containers may explode when exposed to extreme heat due to buildup of steam. Closed containers may explode when exposed to extreme heat. Vapors may form explosive mixtures with air. Vapors can travel to a source of ignition and flash back. Isolate from heat, electrical equipment, sparks and open flame. Perforation of the pressurized container may cause bursting of the can.
SPECIAL FIREFIGHTING PROCEDURES: Water may be used to cool closed containers to prevent pressure buildup and possible autoignition or explosion. Full protective equipment including self-contained breathing apparatus should be used. Evacuate area and fight fire from a safe distance. Use water spray to keep fire-exposed containers cool. Containers may explode when heated.

Special Fire and Explosion Hazard (Combustible Dust): No Information

Accidental Release Measures

STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED : Contain spilled liquid with sand or earth. DO NOT use combustible materials such as sawdust. Isolate the hazard area and deny entry to unnecessary and unprotected personnel. Remove all sources of ignition, ventilate area and remove with inert absorbent and non-sparking tools. Dispose of according to local, state (provincial) and federal regulations. Do not incinerate closed containers. Ventilate area, isolate spilled material, and remove with inert absorbent. Dispose of contaminated absorbent, container, and unused contents in accordance with local, state, and federal regulations.

Handling and Storage

HANDLING: Wash thoroughly after handling. Wash hands before eating. Remove contaminated clothing and launder before reuse.
Use only with adequate ventilation. Follow all SDS and label precautions even after container is emptied because it may retain product residues. Avoid breathing fumes, vapors, or mist. Avoid contact with eyes, skin and clothing.
STORAGE: Keep containers tightly closed. Isolate from heat, electrical equipment, sparks and open flame. Contents under pressure. Do not store above 120°F (49°C). Store large quantities in buildings designed and protected for storage of flammable aerosols. Keep away from heat, sparks, flame and sources of ignition. Avoid excess heat. Product should be stored in tightly sealed containers and protected from heat, moisture, and foreign materials.
Advice on Safe Handling of Combustible Dust: No Information

Exposure Controls / Personal Protection

Chemical Name| CAS-No.| Weight %
Less Than| ACGIH TLV-
TWA| ACGIH TLV-
STEL| OSHA PEL-TWA| OSHA PEL-
CEILING
---|---|---|---|---|---|---
Acetone| 67-64-1| 40.0| 250 ppm| 500 ppm| 1000 ppm| N.E.
Propane| 74-98-6| 20.0| N.E.| N.E.| 1000 ppm| N.E.
n-Butyl Acetate| 123-86-4| 10.0| 50 ppm| 150 ppm| 150 ppm| N.E.
Toluene| 108-88-3| 10.0| 20 ppm| N.E.| 200 ppm| 300 ppm
n-Butane| 106-97-8| 10.0| N.E.| 1000 ppm| N.E.| N.E.
Dimethyl Carbonate| 616-38-6| 10.0| N.E.| N.E.| N.E.| N.E.
Methyl n-Amyl Ketone| 110-43-0| 5.0| 50 ppm| N.E.| 100 ppm| N.E.

PERSONAL PROTECTION

ENGINEERING CONTROLS : Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels below recommended exposure limits. Use explosion-proof ventilation equipment. Provide general dilution of local exhaust ventilation in volume and pattern to keep TLV of hazardous ingredients below acceptable limits. Prevent build-up of vapors by opening all doors and windows to achieve cross-ventilation.
RESPIRATORY PROTECTION: A respiratory protection program that meets OSHA 1910.134 and ANSI Z88.2 requirements must be followed whenever workplace conditions warrant a respirator’s use. A NIOSH/MSHA approved air purifying respirator with organic vapor cartridge or canister may be permissible under certain circumstances where airborne concentrations are expected to exceed exposure limits.
SKIN PROTECTION: Use gloves to prevent prolonged skin contact. Nitrile or Neoprene gloves may afford adequate skin protection.
EYE PROTECTION: Use safety eyewear designed to protect against splash of liquids.
OTHER PROTECTIVE EQUIPMENT: Refer to safety supervisor or industrial hygienist for further guidance regarding types of personal protective equipment and their applications.
HYGIENIC PRACTICES: Wash thoroughly with soap and water before eating, drinking or smoking. Remove contaminated clothing immediately and launder before reuse.
Engineering Measures for Combustible Dust: No Information.

Physical and Chemical Properties

Stability and Reactivity

Conditions to Avoid : Avoid temperatures above 120°F (49°C). Avoid all possible sources of ignition.
Incompatibility: Incompatible with strong oxidizing agents, strong acids and strong alkalies.
Hazardous Decomposition: By open flame, carbon monoxide and carbon dioxide. When heated to decomposition, it emits acrid smoke and irritating fumes. Contains solvents which may form carbon monoxide, carbon dioxide, and formaldehyde.
Hazardous Polymerization : Will not occur under normal conditions.
Stability: This product is stable under normal storage conditions.

Toxicological Information

EFFECTS OF OVEREXPOSURE – EYE CONTACT: Causes Serious Eye Irritation
EFFECTS OF OVEREXPOSURE – SKIN CONTACT: May be absorbed through the skin in harmful amounts.
EFFECTS OF OVEREXPOSURE – INHALATION: Harmful if inhaled. High gas, vapor, mist or dust concentrations may be harmful if inhaled. Avoid breathing fumes, spray, vapors, or mist. High vapor concentrations are irritating to the eyes, nose, throat and lungs.
Prolonged or excessive inhalation may cause respiratory tract irritation.
EFFECTS OF OVEREXPOSURE – INGESTION : Harmful if swallowed.
EFFECTS OF OVEREXPOSURE – CHRONIC HAZARDS: May damage fertility or the unborn child. May cause central nervous system disorder (e.g., narcosis involving a loss of coordination, weakness, fatigue, mental confusion, and blurred vision) and/or damage. High concentrations may lead to central nervous system effects (drowsiness, dizziness, nausea, headaches, paralysis, and blurred vision) and/or damage. Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. May cause genetic defects.
PRIMARY ROUTE(S) OF ENTRY: Eye Contact, Ingestion, Inhalation, Skin Absorption, Skin Contact

ACUTE TOXICITY VALUES
The acute effects of this product have not been tested. Data on individual components are tabulated below:

CAS-No| Chemical Name| Oral LD50| Dermal LD50| Vapor LC50
---|---|---|---|---
67-64-1| Acetone| 5800 mg/kg Rat| >15700 mg/kg Rabbit| 50.1 mg/L Rat
123-86-4| n-Butyl Acetate| 10768 mg/kg Rat| >17600 mg/kg Rabbit| > 21 mg/L Rat
108-88-3| Toluene| 2600 mg/kg Rat| 12000 mg/kg Rabbit| 12.5 mg/L Rat
106-97-8| n-Butane| N.E.| N.E.| 658 mg/L Rat
616-38-6| Dimethyl Carbonate| 13000 mg/kg Rat| >5000 mg/kg Rabbit| >5.36 mg/L Rat
110-43-0| Methyl n-Amyl Ketone| 1600 mg/kg Rat| 10300 mg/kg Rabbit| N.E.

Ecological Information

ECOLOGICAL INFORMATION: Product is a mixture of listed components.

Disposal Information

DISPOSAL: Do not incinerate closed containers. This product as supplied is a USEPA defined ignitable hazardous waste. Dispose of unusable product as a hazardous waste (D001) in accordance with local, state, and federal regulation.

Transport Information

| Domestic (USDOT)| International (IMDG)| Air (IATA)| TDG (Canada)
---|---|---|---|---
UN Number:| N.A.| 1950| 1950| N.A.
Proper Shipping Name:| Paint and Related Spray
Products in Ltd Qty| Aerosols| Aerosols, flammable| Aerosols
Hazard Class:| N.A| 2| 2.1| N.A
Packing Group:| N.A.| N.A| N.A| N.A
Limited Quantity:| Yes| Yes| Yes| Yes

Regulatory Information

U.S. Federal Regulations:

CERCLA – SARA Hazard Category
This product has been reviewed according to the EPA ‘Hazard Categories’ promulgated under Sections 311 and 312 of the Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, to meet the following categories:
Gas under pressure, Reproductive toxicity, Serious eye damage or eye irritation, Specific target organ toxicity (single or repeated exposure)

SARA Section 313

This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372:

Chemical Name CAS-No.
Toluene 108-88-3

Toxic Substances Control Act
This product contains the following chemical substances subject to the reporting requirements of TSCA 12(b) if exported from the United States:
No TSCA 12(b) components exist in this product.

U.S. State Regulations:

California Proposition 65

WARNING: Cancer and Reproductive Harm – www.P65Warnings.ca.gov.

Other Information

HMIS RATINGS

Health: 2*
Flammability: 4
Physical  Hazard: 0
Personal Protection: X

NFPA RATINGS

Health : 2
Flammability: 4
Instability : 0

Maximum Incremental Reactivity: 0.84

SDS REVISION DATE: 12/6/2022

REASON FOR REVISION: Product Composition Changed Substance and/or Product Properties Changed in  Section(s):
02 – Hazard Identification
15 – Regulatory Information
16 – Other Information
Revision Statement(s) Changed Legend: N.A. – Not Applicable, N.D. – Not Determined, N.E. – Not Established

Rust-Oleum Corporation believes, to the best of its knowledge, information and belief, the information contained herein to be accurate and reliable as of the date of this safety data sheet. However, because the conditions of handling, use, and storage of these materials are beyond our control, we assume no responsibility or liability for personal injury or property damage incurred by the use of these materials. Rust-Oleum Corporation makes no warranty, expressed or implied, regarding the accuracy or reliability of the data or results obtained from their use. All materials may present unknown hazards and should be used with caution. The information and recommendations in this material safety data sheet are offered for the users’ consideration and examination. It is the responsibility of the user to determine the final suitability of this information and to comply with all applicable international, federal, state, and local laws and regulations.

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