RUST-OLEUM 366438 High Performance Wheel Spray Paint Owner’s Manual

RUST-OLEUM 366438 High Performance Wheel Spray Paint

Identification

USA
Preparer:| Regulatory Department
Emergency Telephone:| 24 Hour Hotline: 847-367-7700
Revision Date:| 12/6/2022
Supersedes Date:| 9/14/2022
Manufacturer:| Rust-Oleum Corporation 11 Hawthorn Parkway Vernon Hills, IL 60061 USA

Hazards Identification

Classification

Symbol(s) of Product

Signal Word

Danger

Possible Hazards

33% of the mixture consists of ingredient(s) of unknown acute toxicity.

GHS HAZARD STATEMENTS

explode if heated.
Reproductive Toxicity, category 2| H361| Suspected of damaging fertility or the unborn child.
STOT, Repeated Exposure, category 2| H373| May cause damage to organs through prolonged or repeated exposure.
STOT, Single Exposure, category 3, NE| H336| May cause drowsiness or dizziness.

GHS LABEL PRECAUTIONARY STATEMENTS

ignition sources. NO SMOKING.
P211| Do not spray on an open flame or other ignition source.
P251| Do not pierce or burn, even after use.
P260| Do not breathe dust/fume/gas/mist/vapors/spray.
P264| Wash hands thoroughly after handling.
P271| Use only outdoors or in a well-ventilated area.
P280| Wear protective gloves/protective clothing/eye protection/face protection.
P304+P340| IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P305+P351+P338| IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing
P308+P313| IF exposed or concerned: Get medical advice/attention.
P312| Call a POISON CENTER or doctor/physician if you feel unwell.
P337+P313| If eye irritation persists: Get medical advice/attention
P403+P233| Store in a well-ventilated place. Keep container tightly closed.
P405| Store locked up.
P410+P403|  Protect from sunlight. Store in a well-ventilated place
P410+P412| Protect from sunlight. Do not expose to temperatures exceeding 50°C (122°F).
P501| Dispose of contents/container in accordance with local, regional and national regulations.

Composition / Information on Ingredients

H226-315-319-332
Ethylbenzene| 100-41-4| 0.1-1.0| GHS02-GHS07-
GHS08| H225-304-332-351-373
Solvent Naphtha, Light Aromatic| 64742-95-6| 0.1-1.0| GHS07-GHS08| H304-332
Carbon Black| 1333-86-4| 0.1-1.0| Not Available| Not Available
Mineral Spirits| 64742-88-7| 0.1-1.0| GHS08| H304-372
Amorphous Precipitated Silica| 112926-00-8| 0.1-1.0| Not Available| Not Available

First-Aid Measures

F IRST AID – EYE CONTACT: Immediately flush eyes with plenty of water for at least 15 minutes holding eyelids open. Get medical attention. Do NOT allow rubbing of eyes or keeping eyes closed.
FIRST AID – SKIN CONTACT: Wash skin with soap and water. Remove contaminated clothing. Get medical attention if irritation develops or persists.
FIRST AID – INHALATION: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get immediate medical attention. Do NOT use mouth-to-mouth resuscitation. If you experience difficulty in breathing, leave the area to obtain fresh air. If continued difficulty is experienced, get medical assistance immediately.
FIRST AID – INGESTION: Aspiration hazard: Do not induce vomiting or give anything by mouth because this material can enter the lungs and cause severe lung damage. Get immediate medical attention. If swallowed, get medical attention.

Fire-Fighting Measures

EXTINGUISHING MEDIA: Alcohol Film Forming Foam, Carbon Dioxide, Dry Chemical, Dry Sand, Water Fog

UNUSUAL FIRE AND EXPLOSION HAZARDS : FLASH POINT IS LESS THAN -7°C (20°F). EXTREMELY FLAMMABLE LIQUID AND VAPOR! Water spray may be ineffective. Closed containers may explode when exposed to extreme heat due to buildup of steam. Closed containers may explode when exposed to extreme heat. Vapors may form explosive mixtures with air. Vapors can travel to a source of ignition and flash back. Isolate from heat, electrical equipment, sparks and open flame. Perforation of the pressurized container may cause bursting of the can.
SPECIAL FIREFIGHTING PROCEDURES: Water may be used to cool closed containers to prevent pressure buildup and possible autoignition or explosion. Full protective equipment including self-contained breathing apparatus should be used. Evacuate area and fight fire from a safe distance. Use water spray to keep fire-exposed containers cool. Containers may explode when heated. Special Fire and Explosion Hazard (Combustible Dust): No Information.

Accidental Release Measures

STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: Contain spilled liquid with sand or earth. DO NOT use combustible materials such as sawdust. Isolate the hazard area and deny entry to unnecessary and unprotected personnel. Remove all sources of ignition, ventilate area and remove with inert absorbent and non-sparking tools. Dispose of according to local, state (provincial) and federal regulations. Do not incinerate closed containers. Ventilate area, isolate spilled material, and remove with inert absorbent. Dispose of contaminated absorbent, container, and unused contents in accordance with local, state, and federal regulations.

Handling and Storage

HANDLING: Wash thoroughly after handling. Wash hands before eating. Remove contaminated clothing and launder before reuse. Use only with adequate ventilation. Follow all SDS and label precautions even after container is emptied because it may retain product residues. Avoid breathing fumes, vapors, or mist. Avoid contact with eyes, skin and clothing.
STORAGE : Keep containers tightly closed. Isolate from heat, electrical equipment, sparks and open flame. Contents under pressure. Do not store above 120°F (49°C). Store large quantities in buildings designed and protected for storage of flammable aerosols. Keep away from heat, sparks, flame and sources of ignition. Avoid excess heat. Product should be stored in tightly sealed containers and protected from heat, moisture, and foreign materials. Advice on Safe Handling of Combustible Dust: No Information.

Exposure Controls / Personal Protection

Chemical Name| CAS-No.| Weight % Less Than| ACGIH TLV- TWA| ACGIH TLV- STEL| OSHA PEL-TWA| OSHA PEL- CEILING
---|---|---|---|---|---|---
Acetone| 67-64-1| 30.0| 250 ppm| 500 ppm| 1000 ppm| N.E.
Propane| 74-98-6| 20.0| N.E.| N.E.| 1000 ppm| N.E.
Dimethyl Carbonate| 616-38-6| 20.0| N.E.| N.E.| N.E.| N.E.
n-Butane| 106-97-8| 10.0| N.E.| 1000 ppm| N.E.| N.E.
Toluene| 108-88-3| 10.0| 20 ppm| N.E.| 200 ppm| 300 ppm
n-Butyl Acetate| 123-86-4| 10.0| 50 ppm| 150 ppm| 150 ppm| N.E.
Methyl n-Amyl Ketone| 110-43-0| 5.0| 50 ppm| N.E.| 100 ppm| N.E.
Xylenes (o-, m-, p- Isomers)| 1330-20-7| 5.0| 20 ppm| N.E.| 100 ppm| N.E.
Ethylbenzene| 100-41-4| 1.0| 20 ppm| N.E.| 100 ppm| N.E.
Solvent Naphtha, Light Aromatic| 64742-95-6| 1.0| N.E.| N.E.| N.E.| N.E.
Carbon Black| 1333-86-4| 1.0| 3 mg/m3| N.E.| 3.5 mg/m3| N.E.
Mineral Spirits| 64742-88-7| 1.0| N.E.| N.E.| N.E.| N.E.
Amorphous Precipitated Silica| 112926-00-8| 1.0| N.E.| N.E.| 20 mppcf| N.E.

PERSONAL PROTECTION

ENGINEERING CONTROLS : Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels below recommended exposure limits. Use explosion-proof ventilation equipment. Provide general dilution of local exhaust ventilation in volume and pattern to keep TLV of hazardous ingredients below acceptable limits. Prevent build-up of vapors by opening all doors and windows to achieve cross-ventilation.
RESPIRATORY PROTECTION: A respiratory protection program that meets OSHA 1910.134 and ANSI Z88.2 requirements must be followed whenever workplace conditions warrant a respirator’s use. A NIOSH/MSHA approved air purifying respirator with organic vapor cartridge or canister may be permissible under certain circumstances where airborne concentrations are expected to exceed exposure limits.
SKIN PROTECTION: Use gloves to prevent prolonged skin contact. Nitrile or Neoprene gloves may afford adequate skin protection.
EYE PROTECTION: Use safety eyewear designed to protect against splash of liquids.
OTHER PROTECTIVE EQUIPMENT : Refer to safety supervisor or industrial hygienist for further guidance regarding types of personal protective equipment and their applications.
HYGIENIC PRACTICES: Wash thoroughly with soap and water before eating, drinking or smoking. Remove contaminated clothing immediately and launder before reuse. Engineering Measures for Combustible Dust: No Information.

Physical and Chemical Properties

Stability and Reactivity

Conditions to Avoid : Avoid temperatures above 120°F (49°C). Avoid all possible sources of ignition.
Incompatibility: Incompatible with strong oxidizing agents, strong acids and strong alkalies.
Hazardous Decomposition: By open flame, carbon monoxide and carbon dioxide. When heated to decomposition, it emits acrid smoke and irritating fumes. Contains solvents which may form carbon monoxide, carbon dioxide, and formaldehyde.
Hazardous Polymerization: Will not occur under normal conditions.
Stability : This product is stable under normal storage conditions

Toxicological Information

EFFECTS OF OVEREXPOSURE – EYE CONTACT: Causes Serious Eye Irritation
EFFECTS OF OVEREXPOSURE – SKIN CONTACT: May be absorbed through the skin in harmful amounts.
EFFECTS OF OVEREXPOSURE – INHALATION: Harmful if inhaled. High gas, vapor, mist or dust concentrations may be harmful if inhaled. Avoid breathing fumes, spray, vapors, or mist. High vapor concentrations are irritating to the eyes, nose, throat and lungs.
Prolonged or excessive inhalation may cause respiratory tract irritation.
EFFECTS OF OVEREXPOSURE – INGESTION : Harmful if swallowed.
EFFECTS OF OVEREXPOSURE – CHRONIC HAZARDS : May damage fertility or the unborn child. May cause central nervous system disorder (e.g., narcosis involving a loss of coordination, weakness, fatigue, mental confusion, and blurred vision) and/or damage. High concentrations may lead to central nervous system effects (drowsiness, dizziness, nausea, headaches, paralysis, and blurred vision) and/or damage. Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Overexposure to xylene in laboratory animals has been associated with liver abnormalities, kidney, lung, spleen, eye and blood damage as well as reproductive disorders. Effects in humans, due to chronic
overexposure, have included liver, cardiac abnormalities and nervous system damage. Contains carbon black. Chronic
inflammation, lung fibrosis, and lung tumors have been observed in some rats experimentally exposed for long periods of time to
excessive concentrations of carbon black and several insoluble fine dust particles. Tumors have not been observed in other animal
species (i.e., mouse and hamster) under similar circumstances and study conditions. Epidemiological studies of North American
workers show no evidence of clinically significant adverse health effects due to occupational exposure to carbon black.
Carbon black is listed as a Group 2B-“Possibly carcinogenic to humans” by IARC and is proposed to be listed as A4- “not classified
as a human carcinogen” by the American Conference of Governmental Industrial Hygienists. Significant exposure is not anticipated
during brush application or drying. Risk of overexposure depends on duration and level of exposure to dust from repeated sanding of surfaces or spray mist and the actual concentration of carbon black in the formula. IARC lists Ethylbenzene as a possible human
carcinogen (group 2B). May cause genetic defects.

PRIMARY ROUTE(S) OF ENTRY: Eye Contact, Ingestion, Inhalation, Skin Absorption, Skin Contact

ACUTE TOXICITY VALUES

Rat
106-97-8| n-Butane| N.E.| N.E.| 658 mg/L Rat
108-88-3| Toluene| 2600 mg/kg Rat| 12000 mg/kg Rabbit| 12.5 mg/L Rat
123-86-4| n-Butyl Acetate| 10768 mg/kg Rat| >17600 mg/kg Rabbit| > 21 mg/L Rat
110-43-0| Methyl n-Amyl Ketone| 1600 mg/kg Rat| 10300 mg/kg Rabbit| N.E.
1330-20-7| Xylenes (o-, m-, p- Isomers)| 3500 mg/kg Rat| >4350 mg/kg Rabbit| 29.08 mg/L Rat
100-41-4| Ethylbenzene| 3500 mg/kg Rat| 15400 mg/kg Rabbit| 17.4 mg/L Rat
64742-95-6| Solvent Naphtha, Light Aromatic| 8400 mg/kg Rat| >2000 mg/kg Rabbit| N.E.
1333-86-4| Carbon Black| >15400 mg/kg Rat| N.E.| N.E.
64742-88-7| Mineral Spirits| 19748 mg/kg Rat| >4000 mg/kg Rabbit| 4951 mg/L Rat

Ecological Information

ECOLOGICAL INFORMATION: Product is a mixture of listed components.

Disposal Information

DISPOSAL : Do not incinerate closed containers. This product as supplied is a USEPA defined ignitable hazardous waste. Dispose of unusable product as a hazardous waste (D001) in accordance with local, state, and federal regulation.

Transport Information

| Domestic (USDOT)| International (IMDG)| Air (IATA)| TDG (Canada)
---|---|---|---|---
UN Number:| N.A.| 1950| 1950| N.A.
Proper Shipping Name:| Paint and Related Spray Products in Ltd Qty| Aerosols| Aerosols, flammable| Aerosols
Hazard Class:| N.A| 2| 2.1| N.A
Packing Group:| N.A.| N.A.| N.A.| N.A
Limited Quantity:| Yes| Yes| Yes| Yes

Regulatory Information

U.S. Federal Regulations:

CERCLA – SARA Hazard Category

This product has been reviewed according to the EPA ‘Hazard Categories’ promulgated under Sections 311 and 312 of the Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, to meet the following categories:

Gas under pressure, Carcinogenicity, Reproductive toxicity, Serious eye damage or eye irritation, Specific target organ toxicity (single or repeated exposure)

SARA Section 313

This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372:

Toxic Substances Control Act

This product contains the following chemical substances subject to the reporting requirements of TSCA 12(b) if exported from
the United States:

No TSCA 12(b) components exist in this product.

U.S. State Regulations:

California Proposition 65

WARNING: Cancer and Reproductive Harm – www.P65Warnings.ca.gov.

Other Information

NFPA RATINGS
Health:| 2| Flammability:| 4| Instability:| 0
Maximum Incremental Reactivity:| 12/6/2022
REASON FOR REVISION:| Product Composition Changed Substance and/or Product Properties Changed in Section(s): 02 – Hazard Identification 16 – Other Information Revision Statement(s) Changed
Legend:| N.A. – Not Applicable, N.D. – Not Determined, N.E. – Not Established

Rust-Oleum Corporation believes, to the best of its knowledge, information and belief, the information contained herein to be accurate and reliable as of the date of this safety data sheet. However, because the conditions of handling, use, and storage of these materials are beyond our control, we assume no responsibility or liability for personal injury or property damage incurred by the use of these materials. Rust-Oleum Corporation makes no warranty, expressed or implied, regarding the accuracy or reliability of the data or results obtained from their use. All materials may present unknown hazards and should be used with caution. The information and recommendations in this material safety data sheet are offered for the users’ consideration and examination. It is the responsibility of the user to determine the final suitability of this information and to comply with all applicable international, federal, state, and local laws and regulations.

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