RUST-OLEUM 299743 RockSolid Metallic Garage Floor Coating Kit Instructions

RUST-OLEUM 299743 RockSolid Metallic Garage Floor Coating Kit

Product Information

Specifications

• Product Name: Rust-Oleum Multi Component Product
• Product Identifier: 299743 RKSOLID KIT METALLIC GAR COATGUNMETAL
• Components: 299743B, 299743A, 60169
• Recommended Use: Floor Coating
• Manufacturer: Rust-Oleum ROCKSOLID
• Address: 11 Hawthorn Parkway Vernon Hills, IL 60061 USA

Product Usage Instructions

1. Step 1: Preparing the Surface
2. Clean the surface thoroughly to remove any dirt, grease, or contaminants.
3. If the surface has any loose or peeling paint, scrape it off and sand the area to create a smooth surface.
4. Repair any cracks or holes in the surface using an appropriate filler.
5. Step 2: Mixing the Components
6. Ensure that you have all the necessary components: 299743B, 299743A, and 60169.
7. Follow the recommended mixing ratio provided on the product packaging.
8. Use a clean container to mix the components together thoroughly. Stir well to achieve a homogenous mixture.
9. Step 3: Application
10. Use a brush or roller to apply the mixed product onto the prepared surface.
11. Apply an even coat, working in small sections to ensure proper coverage.
12. Allow the first coat to dry according to the recommended drying time.
13. If a second coat is desired, repeat the application process after the first coat has dried.
14. Step 4: Curing and Drying
15. After the final coat, allow the product to cure for the recommended curing time before subjecting it to heavy use.
16. Ensure proper ventilation during the drying and curing process.

FAQ (Frequently Asked Questions)

1. Q: Can this product be used on outdoor surfaces?
   A: Yes, this product can be used both indoors and outdoors.

2. Q: What is the recommended temperature range for application?
   A: The recommended temperature range for application is between 50°F and 90°F (10°C and 32°C).

3. Q: How long does it take for the product to dry?
   A: The drying time may vary depending on environmental conditions, but typically it takes around 4-6 hours.

4. Q: Can I apply this product over existing coatings?
   A: Yes, you can apply this product over existing coatings as long as they are clean, dry, and in good condition.

• Revision Date: 9/23/2022
• Rust-Oleum Multi Component Product Information Sheet

299743 RKSOLID KIT METALLIC GAR COATGUNMETAL is a multi component product composed of the following individual chemical components:

• 299743B
  • RKSOLID ACTIVATOR PART B
• 299743A
  • RKSOLID KIT GUN METAL
• 60169
  • CITRIC ETCH WITH WARNING LABELS

SDSs for each component follow this cover sheet.

Transportation Information

UN Number:

| Domestic (USDOT)

N.A.

| International (IMDG)

3066

| Air (IATA)

3066

| TDG (Canada)

N.A.

---|---|---|---|---

Proper Shipping Name: Paint Products in              Paint and Paint Related            Paint and Paint                Paint Products in

| Limited Quantities| Material| Related Material| Limited Quantities
Hazard Class:| N.A.| 8| 8| N.A.
Packing Group:| N.A.| II| II| N.A.
Limited Quantity:| Yes| Yes| No| Yes

Identification

• Product Name:
  • RKSOLID ACTIVATOR PART B Revision Date: 9/23/2022
• Product Identifier:
  • 299743B Supersedes Date: 4/27/2020
• Recommended Use:
  • Floor Coating Part B
• Supplier:
  • Rust-Oleum ROCKSOLID
  • 11 Hawthorn Parkway
  • Vernon Hills, IL 60061 USA
• Manufacturer:
  • Rust-Oleum ROCKSOLID
  • 11 Hawthorn Parkway
  • Vernon Hills, IL 60061 USA
• Preparer:
  • Regulatory Department
• Emergency Telephone:
  • 24 Hour Hotline: 847-367-7700

Hazards Identification

• Classification
• Symbol(s) of Product
• Signal Word
  • Danger
• Possible Hazards
  • 15% of the mixture consists of ingredient(s) of unknown acute toxicity.

GHS HAZARD STATEMENTS

• Acute Toxicity, Oral, category 4
  • H302 Harmful if swallowed.
• Skin Sensitizer, category 1
  • H317 May cause an allergic skin reaction.
• Acute Toxicity, Inhalation, category 4
  • H332 Harmful if inhaled.
• Reproductive Toxicity, category 1B
  • H360 May damage fertility or the unborn child.
• Skin Corrosion, category 1B
  • H314 Causes severe skin burns and eye damage.

GHS LABEL PRECAUTIONARY STATEMENTS

• P201
  • Obtain special instructions before use.
• P260
  • Do not breathe dust/fume/gas/mist/vapors/spray.
• P264
  • Wash hands thoroughly after handling.
• P271
  • Use only outdoors or in a well-ventilated area.
• P272
  • Contaminated work clothing should not be allowed out of the workplace.
• P280
  • Wear protective gloves/protective clothing/eye protection/face protection.
• P310
  • If exposed immediately call a POISON CENTER or doctor/physician.
• P321
  • For specific treatment see label.
• P405
  • Store locked up.
• P501
  • Dispose of contents/container in accordance with local, regional and national regulations.

Rock Solid Activator Part B

Date Printed: 9/23/2022

• P301+P312
  • IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
• P301+P330+P331
  • IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
• P302+P352
  • IF ON SKIN: Wash with plenty of soap and water.
• P303+P361+P353
  • IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower.
• P304+P340
  • IF INHALED: Remove person to fresh air and keep comfortable for breathing.
• P305+P351+P338
  • IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
• P308+P313
  • IF exposed or concerned: Get medical advice/attention.
• P333+P313
  • If skin irritation or rash occurs: Get medical advice/attention.

GHS SDS PRECAUTIONARY STATEMENTS

• P270 Do not eat, drink or smoke when using this product.
• P363 Wash contaminated clothing before reuse.

Composition / Information on Ingredients

• HAZARDOUS SUBSTANCES Chemical Name CAS-No. Wt.% Range GHS Symbols GHS Statements
• Polyoxypropylenediamine
  • 9046-10-0 25-50 GHS05 H314
• Benzyl Alcohol
  • 100-51-6 25-50 GHS07 H302-312-320-332
• 4,4′-(1-Methylethylidene)
  • Bisphenol 80-05-7 10-25 GHS05-GHS07-
  • GHS08 H317-318-335-360
• Isophorone Diamine
  • 2855-13-2 10-25 GHS05-GHS07 H302-314-317

First-Aid Measures

• FIRST AID – EYE CONTACT: Immediately flush eyes with plenty of water for at least 15 minutes holding eyelids open. Get medical attention. Do NOT allow rubbing of eyes or keeping eyes closed. Remove contact lenses, if present and easy to do. Continue rinsing.
• FIRST AID – SKIN CONTACT : Wash skin with soap and water. Remove contaminated clothing. Get medical attention if irritation develops or persists.
• FIRST AID – INHALATION: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get immediate medical attention. Do NOT use mouth-to-mouth resuscitation. If you experience difficulty in breathing, leave the area to obtain fresh air. If continued difficulty is experienced, get medical assistance immediately.
• FIRST AID – INGESTION : Swallowing less than an ounce will not cause significant harm. For larger amounts, do not induce vomiting, but give one or two glasses of water to drink and get medical attention. If swallowed, do not induce vomiting. If victim is conscious and alert, give 2 to 4 cupfuls of water or milk. Call a physician or poison control center immediately. Never give anything by mouth to an unconscious person. Treat symptomatically and supportively. If swallowed, rinse mouth with water. If feeling unwell, get medical attention.

Fire-Fighting Measures

• EXTINGUISHING MEDIA:
  • Alcohol Film Forming Foam, Carbon Dioxide, Dry Chemical, Dry Sand, Water Fog
• UNUSUAL FIRE AND EXPLOSION HAZARDS: Keep containers tightly closed. FLASH POINT IS TESTED TO BE GREATER THAN 200 DEGREES F. No unusual fire or explosion hazards noted.
• SPECIAL FIREFIGHTING PROCEDURES: Water may be used to cool closed containers to prevent buildup of steam. If water is used, fog nozzles are preferred.
• Special Fire and Explosion Hazard (Combustible Dust): No Information

Accidental Release Measures

STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: If spilled, contain spilled material and remove with inert absorbent. Dispose of contaminated absorbent, container, and unused contents in accordance with local, state, and federal regulations. Do not incinerate closed containers

Handling and Storage

• HANDLING: Wash thoroughly after handling. Wash hands before eating. Remove contaminated clothing and launder before reuse. Use only with adequate ventilation. Follow all SDS and label precautions even after container is emptied because it may retain product residues. Avoid breathing fumes, vapors, or mist. Avoid contact with eyes, skin and clothing.
• STORAGE :Store in a dry, well ventilated place. Keep container tightly closed when not in use. Advice on Safe Handling of Combustible
• Dust: No Information

Exposure Controls / Personal Protection

Chemical Name

|

CAS- No.

| Weight % Less Than| ACGIH TLV- TWA| ACGIH TLV- STEL|

OSHA PEL-TWA

| OSHA PEL- CEILING
---|---|---|---|---|---|---
Polyoxypropylenediamine| 9046-10-0| 50.0| N.E.| N.E.| N.E.| N.E.
Benzyl Alcohol| 100-51-6| 35.0| N.E.| N.E.| N.E.| N.E.
4,4′-(1-Methylethylidene)

Bisphenol

| 80-05-7| 20.0| N.E.| N.E.| N.E.| N.E.
Isophorone Diamine| 2855-13-2| 15.0| N.E.| N.E.| N.E.| N.E.

PERSONAL PROTECTION

• ENGINEERING CONTROLS:
  • Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels below recommended exposure limits. Prevent build-up of vapors by opening all doors and windows to achieve cross-ventilation.
• RESPIRATORY PROTECTION:
  • A respiratory protection program that meets OSHA 1910.134 and ANSI Z88.2 requirements must be followed whenever workplace conditions warrant a respirator’s use.
• SKIN PROTECTION:
  • Use gloves to prevent prolonged skin contact. Nitrile or Neoprene gloves may afford adequate skin protection.
• EYE PROTECTION:
  • Use safety eyewear designed to protect against splash of liquids.
• OTHER PROTECTIVE EQUIPMENT:
  • Refer to safety supervisor or industrial hygienist for further guidance regarding types of personal protective equipment and their applications.
• HYGIENIC PRACTICES:
  • Wash thoroughly with soap and water before eating, drinking or smoking. Remove contaminated clothing immediately and launder before reuse. Engineering Measures for
• Combustible Dust:
  • No Information

Physical and Chemical Properties

• Appearance: Liquid
• Physical   State: Liquid
• Odor: Solvent Like
• Odor Threshold: N.E.
• Specific Gravity: 0.991
• pH: N.A.
• Freeze Point, °C: N.D.
• Viscosity: N.D.
• Solubility in Water: Slight Partition Coefficient, n-octanol/
• Decomposition Temp.,
• °C: N.D. water: N.D.
• Boiling Range, °C: 205 – 220
• Explosive   Limits, vol%: N.A. – N.A.
• Flammability: Does not Support
• Combustion Flash Point, °C: 94
• Evaporation Rate: Slower than Ether
• Auto-Ignition Temp., °C: N.D.
• Vapor Density: Heavier than Air
• Vapor Pressure: N.D

(See “Other information” Section for abbreviation legend)

Stability and Reactivity

• Conditions to Avoid: Avoid excess heat. Keep from freezing.
• Incompatibility: Incompatible with strong oxidizing agents, strong acids and strong alkalies.
• Hazardous Decomposition: When heated to decomposition, it emits acrid smoke and
• irritating fumes. Hazardous Polymerization: Will not occur under normal conditions.
• Stability: This product is stable under normal storage conditions.
• Rock Solid Activator Part B

Toxicological Information

• EFFECTS OF OVEREXPOSURE -EYE CONTACT : Irritating, and may injure eye tissue if not removed promptly.
• EFFECTS OF OVEREXPOSURE -SKIN CONTACT: Low hazard for usual industrial handling or commercial handling by trained personnel.
• EFFECTS OF OVEREXPOSURE -INHALATION : High gas, vapor, mist or dust concentrations may be harmful if inhaled. Avoid breathing fumes, spray, vapors, or mist.
• EFFECTS OF OVEREXPOSURE -INGESTION : Substance may be harmful if swallowed.
• EFFECTS OF OVEREXPOSURE -CHRONIC HAZARDS: No Information
• PRIMARY ROUTE(S) OF ENTRY: Eye Contact, Ingestion, Inhalation, Skin Absorption, Skin Contact

ACUTE TOXICITY VALUES
The acute effects of this product have not been tested. Data on individual components are tabulated below:

• CAS-No. Chemical Name Oral LD50 Dermal LD50 Vapor LC50
• 9046-10-0
  • Polyoxypropylenediamine 2885 mg/kg Rat 2979 mg/kg Rabbit 25 mg/L
• 100-51-6
  • Benzyl Alcohol 1230 mg/kg Rat 2000 mg/kg Rabbit 11 mg/L Rat
• 80-05-7
  • 4,4′-(1-Methylethylidene) Bisphenol 3300 mg/kg Rat 3000 mg/kg Rabbit 2100 mg/L
• 2855-13-2
  • Isophorone Diamine 1030 mg/kg Rat > 2,000 mg/kg Rat 25 mg/L

N.E. – Not Established

• Ecological Information
  • ECOLOGICAL INFORMATION: Product is a mixture of listed components. No ecotoxicity data was found for this product.
• Disposal Information
  • DISPOSAL: Dispose of material in accordance to local, state, and federal regulations and ordinances.

Transport Information

• Domestic (USDOT) International (IMDG) Air (IATA) TDG (Canada)
• UN Number: N.A. 3066 3066 N.A.
• Proper Shipping Name: Paint Products in
• Limited Quantities
• Paint and Paint Related
• Material
• Paint and Paint
• Related Material
• Paint Products in
• Limited Quantities
• Hazard Class: N.A. 8 8 N.A.
• Packing Group: N.A. II II N.A.
• Limited Quantity: Yes Yes No Yes

Regulatory Information

U.S. Federal Regulations:
CERCLA – SARA Hazard Category

• This product has been reviewed according to the EPA ‘Hazard Categories’ promulgated under Sections 311 and 312 of the Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, to meet the following categories:
• Acute Toxicity (any route of exposure), Reproductive toxicity, Skin Corrosion or Irritation, Respiratory or Skin Sensitization

SARA Section 313
This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372:

• Chemical Name
• Rock Solid Activator Part B
• Date   Printed: 9/23/2022
  • 4,4′-(1-Methylethylidene) Bisphenol
  • 80-05-7
• Toxic Substances Control Act
  • This product contains the following chemical substances subject to the reporting requirements of TSCA 12(b) if exported from the United States:
  • No TSCA 12(b) components exist in this product.

U.S. State Regulations:

California Proposition 65

• WARNING:
  • Reproductive Harm – www.P65Warnings.ca.gov.

Other Information

• HMIS RATINGS
• Health:
  • 2* Flammability: 1 Physical Hazard: 0 Personal Protection: X
• NFPA RATINGS
• Health:
  • 2 Flammability: 1 Instability: 0
• Volatile Organic Compounds:
  • 0 g/L
• SDS REVISION DATE:
  • 9/23/2022
• REASON FOR REVISION:
  • Revision Description Changed
• Product Composition Changed
• Substance and/or Product Properties Changed in
• Section(s):
  • 01 – Identification
  • 02 – Hazard Identification
  • 09 – Physical & Chemical Properties
  • 14 – Transport Information
  • 15 – Regulatory Information
  • 16 – Other Information
  • Revision Statement(s) Changed
• Legend: N.A. – Not Applicable, N.D. – Not Determined, N.E. – Not Established

The manufacturer believes, to the best of its knowledge, information and belief, the information contained herein to be accurate and reliable as of the date of this safety data sheet. However, because the conditions of handling, use, and storage of these materials are beyond our control, we assume no responsibility or liability for personal injury or property damage incurred by the use of these materials. The manufacturer makes no warranty, expressed or implied, regarding the accuracy or reliability of the data or results obtained from their use. All materials may present unknown hazards and should be used with caution. The information and recommendations in this material safety data sheet are offered for the users’ consideration and examination. It is the responsibility of the user to determine the final suitability of this information and to comply with all applicable international, federal, state, and local laws and regulations.

Identification

• Product Name: RKSOLID KIT GUN METAL Revision Date: 9/23/2022
• Product Identifier: 299743A Supercedes Date: 4/27/2020
• Recommended Use: Epoxy Floor Coating
• Supplier: Rust-Oleum ROCKSOLID
  • 11 Hawthorn Parkway Vernon Hills, IL 6006 USA
• Manufacturer: Rust-Oleum ROCKSOLID 11 Hawthorn Parkway Vernon Hills, IL 60061 USA
• Preparer: Regulatory Department
• Emergency Telephone: 24 Hour Hotline: 847-367-7700

Hazards Identification

Classification
Symbol(s) of Product

• Signal Word
  • Warning

Possible Hazards
24% of the mixture consists of ingredient(s) of unknown acute toxicity.

GHS HAZARD STATEMENTS

• Flammable liquid, category 4
  • H227 Combustible liquid.
• Skin Irritation, category 2
  • H315 Causes skin irritation.
• Skin Sensitizer, category 1
  • H317 May cause an allergic skin reaction.
• Eye Irritation, category 2A
  • H319 Causes serious eye irritation.
• STOT, Single Exposure, category 3,
  • RTI H335 May cause respiratory irritation.
• Carcinogenicity, category 2
  • H351 Suspected of causing cancer.

GHS LABEL PRECAUTIONARY STATEMENTS

• P201
  • Obtain special instructions before use.
• P210
  • Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. NO SMOKING.
• P261
  • Avoid breathing dust/fume/gas/mist/vapors/spray.
• P264
  • Wash hands thoroughly after handling.
• P271
  • Use only outdoors or in a well-ventilated area.
• P272
  • Contaminated work clothing should not be allowed out of the workplace.
• P280
  • Wear protective gloves/protective clothing/eye protection/face protection.
• P312
  • Call a POISON CENTER or doctor/physician if you feel unwell.

Date Printed: 9/23/2022

• P321 For specific treatment see label.
• P405 Store locked up.
• P501 Dispose of contents/container in accordance with local, regional and national regulations.
• P302+P352 IF ON SKIN: Wash with plenty of soap and water.
• P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
• P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present
• and easy to do. Continue rinsing.
• P308+P313 IF exposed or concerned: Get medical advice/attention.
• P332+P313 If skin irritation occurs: Get medical advice/attention.
• P333+P313 If skin irritation or rash occurs: Get medical advice/attention.
• P337+P313 If eye irritation persists: Get medical advice/attention.
• P370+P378 In case of fire: Use alcohol film forming foam, carbon dioxide, dry chemical, dry sand to extinguish.
• P403+P233 Store in a well-ventilated place. Keep container tightly closed.
• P403+P235 Store in a well-ventilated place. Keep cool.
• P362+P364 Take off contaminated clothing and wash it before reuse

GHS SDS PRECAUTIONARY STATEMENTS
P363 Wash contaminated clothing before reuse

Composition / Information on Ingredients

HAZARDOUS SUBSTANCES

• Chemical Name CAS-No. Wt.% Range GHS Symbols GHS Statements
• Bisphenol A Epoxy Resin 25085-99-8 50-75 GHS07 H315-317-319-335
• 1-Chloro-4-(Trifluoromethyl)Benzene 98-56-6 10-25 GHS07 H315-319-332-335
• Neopentyl Glycol Diglyceryl Ether 17557-23-2 2.5-10 GHS07 H315-317
• Mica 12001-26-2 2.5-10 Not Available Not Available
• Titanium Dioxide 13463-67-7 1.0-2.5 Not Available Not Available
• Xylenes (o-, m-, p- Isomers) 1330-20-7 0.1-1.0 GHS02-GHS07 H226-315-319-332
• Ethylbenzene 100-41-4 0.1-1.0 GHS02-GHS07-
• GHS08 H225-304-332-351-373

First-Aid Measures

• FIRST AID -EYE CONTACT: Immediately flush eyes with plenty of water for at least 15 minutes holding eyelids open. Get medical attention. Do NOT allow rubbing of eyes or keeping eyes closed.
• FIRST AID -SKIN CONTACT : Wash skin with soap and water. Remove contaminated clothing. Get medical attention if irritation develops or persists.
• FIRST AID -INHALATIO N: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get immediate medical attention. Do NOT use  mouth-to-mouth resuscitation. If you experience difficulty in breathing, leave the area to obtain fresh air. If continued difficulty is experienced, get medical assistance immediately.
• FIRST AID -INGESTION: If swallowed, get medical attention.

Fire-Fighting Measures

• EXTINGUISHING MEDIA: Alcohol Film Forming Foam, Carbon Dioxide, Dry Chemical, Dry Sand, Water Fog
• UNUSUAL FIRE AND EXPLOSION HAZARDS: Closed containers may explode when exposed to extreme heat due to buildup of steam. Keep containers tightly closed. Combustible liquid and vapor. No unusual fire or explosion hazards noted
• SPECIAL FIREFIGHTING PROCEDURES : Evacuate area and fight fire from a safe distance. Use water spray to keep fire-exposed containers cool. Containers may explode when heated.
• Special Fire and Explosion Hazard (Combustible Dust) : No Information

Accidental Release Measures

STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: Remove all sources of ignition, ventilate area and remove with inert absorbent and non-sparking tools. Dispose of according to local, state (provincial) and federal regulations. Do not incinerate closed containers.

Handling and Storage

• HANDLING: Wash thoroughly after handling. Wash hands before eating. Remove contaminated clothing and launder before reuse. Use only with adequate ventilation. Follow all SDS and label precautions even after container is emptied because it may retain product residues. Avoid breathing fumes, vapors, or mist. Avoid contact with eyes, skin and clothing.
• STORAGE: Keep containers tightly closed. Isolate from heat, electrical equipment, sparks and open flame. Avoid excess heat. Store in a dry, well ventilated place. Keep container tightly closed when not in use. Advice on Safe Handling of Combustible
• Dust: No Information

Exposure Controls / Personal Protection

Chemical Name

|

CAS- No.

| Weight % Less Than| ACGIH TLV- TWA| ACGIH TLV- STEL|

OSHA PEL-TWA

| OSHA PEL- CEILING
---|---|---|---|---|---|---
Polyoxypropylenediamine| 9046-10-0| 50.0| N.E.| N.E.| N.E.| N.E.
Benzyl Alcohol| 100-51-6| 35.0| N.E.| N.E.| N.E.| N.E.
4,4′-(1-Methylethylidene)

Bisphenol

| 80-05-7| 20.0| N.E.| N.E.| N.E.| N.E.
Isophorone Diamine| 2855-13-2| 15.0| N.E.| N.E.| N.E.| N.E.

PERSONAL PROTECTION

• ENGINEERING CONTROLS: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels below recommended exposure limits. Prevent build-up of vapors by opening all doors and windows to achieve cross-ventilation.
• RESPIRATORY PROTECTION: A respiratory protection program that meets OSHA 1910.134 and ANSI Z88.2 requirements must be followed whenever workplace conditions warrant a respirator’s use.
• SKIN PROTECTION:Use gloves to prevent prolonged skin contact. Nitrile or Neoprene gloves may afford adequate skin protection.
• EYE PROTECTION:Use safety eyewear designed to protect against splash of liquids.
• OTHER PROTECTIVE EQUIPMENT:Refer to safety supervisor or industrial hygienist for further guidance regarding types of personal protective equipment and their applications.
• HYGIENIC PRACTICES:Wash thoroughly with soap and water before eating, drinking or smoking. Remove contaminated clothing immediately and launder before reuse.
• Engineering Measures for Combustible Dust: No Information

Physical and Chemical Properties

• Appearance: Liquid
• Physical State: Liquid
• Odor: Solvent Like Odor
• Threshold: N.E.
• Specific Gravity: 1.204
• pH: N.A.
• Freeze Point, °C: N.D.
• Viscosity: N.D.
• Solubility in Water: Slight Partition Coefficient, n-octanol/
• Decomposition Temp., °C: N.D. water: N.D.
• Boiling Range, °C: 136 – 537
• Explosive Limits, vol%: 0.9 – 10.5
• Flammability: Supports
• Combustion Flash Point, °C: 70
• Evaporation Rate: Slower than Ether Auto-Ignition Temp., °C: N.D.
• Vapor Density: Heavier than Air
• Vapor Pressure: N.D.

(See “Other information” Section for abbreviation legend)

Stability and Reactivity

• Conditions to Avoid: No Information
• Incompatibility: Incompatible with strong oxidizing agents, strong acids and strong alkalies.
• Hazardous Decomposition: When heated to decomposition, it emits acrid smoke and irritating fumes. Contains solvents which may form carbon monoxide, carbon dioxide, and  formaldehyde.
• Hazardous Polymerization: Will not occur under normal conditions.
• Stability: This product is stable under normal storage conditions.

Toxicological Information

• EFFECTS OF OVEREXPOSURE -EYE CONTACT: Substance causes moderate eye irritation.

• EFFECTS OF OVEREXPOSURE -SKIN CONTACT: Substance may cause slight skin irritation.

• EFFECTS OF OVEREXPOSURE -INHALATION : High gas, vapor, mist or dust concentrations may be harmful if inhaled. Avoid breathing fumes, spray, vapors, or mist. High vapor concentrations are irritating to the eyes, nose, throat and lungs. Prolonged or excessive inhalation may cause respiratory tract irritation.

• EFFECTS OF OVEREXPOSURE -INGESTION : Irritating to the nose, throat and respiratory tract. Harmful if swallowed.

• EFFECTS OF OVEREXPOSURE -CHRONIC HAZARDS: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Overexposure to xylene in laboratory animals has been associated with liver abnormalities, kidney, lung, spleen, eye and blood damage as well as reproductive disorders. Effects in humans, due to chronic overexposure, have included liver, cardiac abnormalities and nervous system damage. IARC lists Ethylbenzene as a possible human carcinogen (group 2B). Contains Titanium Dioxide. Titanium Dioxide is listed as a Group
  2B-“Possibly carcinogenic to humans” by IARC. No significant exposure to Titanium Dioxide is thought to occur during the use of products in which Titanium Dioxide is bound to other materials, such as in paints during brush application or drying. Risk of overexposure depends on duration and level of exposure to dust from repeated sanding of surfaces or  spray mist and the actual concentration of Titanium Dioxide in the formula. (Ref: IARC Monograph, Vol. 93, 2010)

• PRIMARY ROUTE(S) OF ENTRY: Eye Contact, Ingestion, Inhalation, Skin Absorption, Skin Contact

ACUTE TOXICITY VALUES
The acute effects of this product have not been tested. Data on individual components are tabulated below:

• CAS-No. Chemical Name Oral LD50 Dermal LD50 Vapor LC50
• 25085-99-8
  • Bisphenol A Epoxy Resin >5000 >20000 >20
• 98-56-6
  • 1-Chloro-4-(Trifluoromethyl)Benzene 13000 mg/kg Rat >3300 mg/kg Rabbit 33 mg/L Rat
• 17557-23-2
  • Neopentyl Glycol Diglycidyl Ether 4500 mg/kg Rat >2000 mg/kg Rat N.E.
• 12001-26-2
  • Mica N.E. N.E. 25000
• 13463-67-7
  • Titanium Dioxide >10000 mg/kg Rat 6000 N.E.
• 1330-20-7
  • Xylenes (o-, m-, p- Isomers) 3500 mg/kg Rat >4350 mg/kg Rabbit 29.08 mg/L Rat
• 100-41-4
  • Ethylbenzene 3500 mg/kg Rat 15400 mg/kg Rabbit 17.4 mg/L Rat

Disposal Information
DISPOSAL: Dispose of material in accordance to local, state, and federal regulations and ordinances. Do not incinerate closed containers.

Transport Information

• Domestic (USDOT) International (IMDG) Air (IATA) TDG (Canada)
• UN Number: N.A. N.A. N.A. N.A.
• Proper Shipping Name: Not Regulated Not Regulated Not Regulated Not Regulated
• Hazard Class: N.A. N.A. N.A. N.A.
• Packing Group: N.A. N.A. N.A. N.A.
• Limited Quantity: No No No No

Regulatory Information

U.S. Federal Regulations:
CERCLA – SARA Hazard Category

• This product has been reviewed according to the EPA ‘Hazard Categories’ promulgated under Sections 311 and 312 of the Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, to meet the following categories:
• Flammable (gases, aerosols, liquids, or solids), Carcinogenicity, Skin Corrosion or Irritation, Respiratory or Skin Sensitization, Serious eye damage or eye irritation, Specific target organ toxicity (single or repeated exposure)

SARA Section 313
This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372:

• Chemical Name CAS-No.
  • Xylenes (o-, m-, p- Isomers)1330-20-7
• Ethylbenzene 100-41-4

Toxic Substances Control Act

• This product contains the following chemical substances subject to the reporting requirements of TSCA 12(b) if exported from the United States:
• No TSCA 12(b) components exist in this product.

U.S. State Regulations:
California Proposition 65

• WARNING:
  • Cancer and Reproductive Harm – www.P65Warnings.ca.gov.

Other Information

• HMIS RATINGS
• Health: 2* Flammability: 2 Physical Hazard: 0 Personal Protection: X
• NFPA RATINGS
• Health: 2 Flammability: 2 Instability: 0
• Volatile Organic Compounds: 1 g/L
• SDS REVISION DATE: 9/23/2022
• REASON FOR REVISION: Substance Chemical Name Changed
• Substance Hazardous Flag Changed
• Substance Hazard Threshold % Changed
• Substance and/or Product Properties Changed in Section(s):
  • 02 – Hazard Identification
  • 03 – Composition / Information on Ingredients
  • 08 – Exposure Controls / Personal Protection
  • 11 – Toxicological Information
  • 15 – Regulatory Information
  • Product Composition Changed
  • Revision Statement(s) Changed

Legend: N.A. – Not Applicable, N.D. – Not Determined, N.E. – Not Established

The manufacturer believes, to the best of its knowledge, information and belief, the information contained herein to be accurate and reliable as of the date of this safety data sheet. However, because the conditions of handling, use, and storage of these materials are beyond our control, we assume no responsibility or liability for personal injury or property damage incurred by the use of these materials. The manufacturer makes no warranty, expressed or implied, regarding the accuracy or reliability of the data or results obtained from their use. All materials may present unknown hazards and should be used with caution. The information and recommendations in this material safety data sheet are offered for the users’ consideration and examination. It is the responsibility of the user to determine the final suitability of this information and to comply with all applicable international, federal, state, and local laws and regulations.

Identification

• Product Name: CITRIC ETCH WITH WARNING LABELS Revision Date: 5/10/2021
• Product Identifier: 60169 Supercedes Date: 4/6/2021
• Recommended Use: Concrete Etch/ Citric Acid
• Supplier: Rust-Oleum Corporation
• 11 Hawthorn Parkway Vernon Hills, IL 60061 USA
• Manufacturer: Rust-Oleum Corporation
• 11 Hawthorn Parkway Vernon Hills, IL 60061= USA
• Preparer: Regulatory Department
• Emergency Telephone: 24 Hour Hotline: 847-367-7700

Hazards Identification

• Classification
• Symbol(s) of Product
• Signal Word
• Warning

Possible Hazards

• 100% of the mixture consists of ingredient(s) of unknown acute toxicity.
• GHS HAZARD STATEMENTS
• Eye Irritation, category 2A H319 Causes serious eye irritation.
• GHS LABEL PRECAUTIONARY STATEMENTS
• P264 Wash hands thoroughly after handling.
• P280 Wear protective gloves/protective clothing/eye protection/face protection.
• P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
• P337+P313 If eye irritation persists: Get medical advice/attention.

Composition / Information on Ingredients

HAZARDOUS SUBSTANCES

• Chemical Name CAS-No. Wt.% Range GHS Symbols GHS Statements
  • Citric Acid, Anhydrous 77-92-9 75-100 GHS07 H319

First-Aid Measures

• FIRST AID -EYE CONTACT : Immediately flush eyes with plenty of water for at least 15 minutes holding eyelids open. Get medical attention. Do NOT allow rubbing of eyes or keeping eyes closed.
• FIRST AID -SKIN CONTAC T: Wash skin with soap and water. Remove contaminated clothing. Get medical attention if irritation develops or persists.
• FIRST AID -INHALATION : Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get immediate medical attention. Do NOT use mouth-to-mouth resuscitation. If you experience difficulty in breathing, leave the area to obtain fresh air. If continued difficulty is experienced, get medical assistance immediately.
• FIRSTAID-INGESTION: If swallowed, rinse mouth with water. If feeling unwell, get medical attention.

Fire-Fighting Measures

• EXTINGUISHING MEDIA:
  • Alcohol Film Forming Foam, Carbon Dioxide, Dry Chemical, Dry Sand, Water Fog
• UNUSUAL FIRE AND EXPLOSION HAZARDS: Keep containers tightly closed. FLASH POINT IS TESTED TO BE GREATER THAN 200 DEGREES F. No unusual fire or explosion  hazards noted.
• SPECIAL FIREFIGHTING PROCEDURES: Water may be used to cool closed containers to prevent buildup of steam.
• Special Fire and Explosion Hazard (Combustible Dust):No Information

Accidental Release Measures
STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED : Dispose of according to local, state (provincial) and federal regulations. Do not incinerate closed containers. Sweep up gently to avoid dust cloud formation.

Handling and Storage

• HANDLING: Wash thoroughly after handling. Wash hands before eating. Remove contaminated clothing and launder before reuse. Use only with adequate ventilation. Follow all
• SDS and label precautions even after container is emptied because it may retain product residues. Avoid breathing fumes, vapors, or mist. Avoid contact with eyes, skin and clothing.
• STORAGE: Store in a dry, well ventilated place. Keep container tightly closed when not in use.
• Advice on Safe Handling of Combustible Dust: No Information

Exposure Controls / Personal Protection

Chemical Name

|

CAS- No.

| Weight % Less Than| ACGIH TLV- TWA| ACGIH TLV- STEL|

OSHA PEL-TWA

| OSHA PEL- CEILING
---|---|---|---|---|---|---
Citric Acid, Anhydrous| 77-92-9| 100.0| N.E.| N.E.| N.E.| N.E.

PERSONAL PROTECTION

• ENGINEERING CONTROLS: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels below recommended exposure limits.
• Prevent build-up of vapors by opening all doors and windows to achieve cross-ventilation.
• RESPIRATORY PROTECTION: A respiratory protection program that meets OSHA 1910.134 and ANSI Z88.2 requirements must be followed whenever workplace conditions  warrant a respirator’s use.
• SKIN PROTECTION : Use gloves to prevent prolonged skin contact. Nitrile or Neoprene gloves may afford adequate skin protection.
• EYE PROTECTION: Use safety eyewear designed to protect against splash of liquids.
• OTHER PROTECTIVE EQUIPMENT : Refer to safety supervisor or industrial hygienist for further guidance regarding types of personal protective equipment and their applications.
• HYGIENIC PRACTICES Wash thoroughly with soap and water before eating, drinking or smoking. Remove contaminated clothing immediately and launder before reuse.
• Engineering Measures for Combustible Dus t: No Information
• Citric Acid

Physical and Chemical Properties

• Appearance: Particulate Solid
• Physical State: Solid
• Odor: Solvent Like
• Odor Threshold: N.E.
• Specific Gravity: 1.665
• pH: N.A.
• Freeze Point, °C: N.D.
• Viscosity: N.D.
• Solubility in Water: Soluble Partition Coefficient, n-octanol/
• Decomposition Temp., °C:
• N.D. water: N.D.
• Boiling Range, °C: 175 – 537
• Explosive Limits, vol%: N.A. – N.A.
• Flammability: Does not Support
• Combustion Flash Point, °C: 94
• Evaporation Rate: Slower than Ether
• Auto-Ignition Temp., °C: N.D.
• Vapor Density: Heavier than Air
• Vapor Pressure: N.D.

(See “Other information” Section for abbreviation legend)

Stability and Reactivity

• Conditions to Avoid: No Information
• Incompatibility: Incompatible with strong oxidizing agents, strong acids and strong alkalies.
• Hazardous Decomposition: When heated to decomposition, it emits acrid smoke and  irritating fumes.
• Hazardous Polymerization: Will not occur under normal conditions.
• Stability: This product is stable under normal storage conditions.

Toxicological Information

• EFFECTS OF OVEREXPOSURE -EYE CONTACT: Can cause severe eye irritation. Irritating, and may injure eye tissue if not removed promptly.
• EFFECTS OF OVEREXPOSURE -SKIN CONTACT: Contact causes skin irritation. Low hazard for usual industrial handling or commercial handling by trained personnel.
• EFFECTS OF OVEREXPOSURE -INHALATION: High gas, vapor, mist or dust concentrations may be harmful if inhaled. Avoid breathing fumes, spray, vapors, or mist.
• EFFECTS OF OVEREXPOSURE -INGESTION : Expected to be a low ingestion hazard. May cause nausea.
• EFFECTS OF OVEREXPOSURE -CHRONIC HAZARDS : No Information
• PRIMARY ROUTE(S) OF ENTRY: Eye Contact, Ingestion, Inhalation, Skin Contact
• ACUTE TOXICITY VALUES

The acute effects of this product have not been tested. Data on individual components are tabulated below:

• CAS-No. Chemical Name Oral LD50 Dermal LD50 Vapor LC50

• 77-92-9 Citric Acid, Anhydrous 3000 mg/kg Rat >2000 mg/kg Rat N.E.

N.E. – Not Established

Ecological Information
ECOLOGICAL INFORMATIO N: Product is a mixture of listed components.

Disposal Information
DISPOSAL: Dispose of material in accordance to local, state, and federal regulations and ordinances.

Transport Information

• Domestic (USDOT) International (IMDG) Air (IATA) TDG (Canada)
• UN Number: N.A. N.A. N.A. N.A.
• Proper Shipping Name: Not Regulated Not Regulated Not Regulated Not Regulated
• Hazard Class: N.A. N.A. N.A. N.A.
• Packing Group: N.A. N.A. N.A. N.A.
• Limited Quantity: No No No No

Regulatory Information
U.S. Federal Regulations:

CERCLA – SARA Hazard Category

• This product has been reviewed according to the EPA ‘Hazard Categories’ promulgated under Sections 311 and 312 of the Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, to meet the following categories:
• Serious eye damage or eye irritation

SARA Section 313

• This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372:
• No Sara 313 components exist in this product.

Toxic Substances Control Act

• This product contains the following chemical substances subject to the reporting requirements of TSCA 12(b) if exported from the United States:
• No TSCA 12(b) components exist in this product.

U.S. State Regulations:
California Proposition 65

• WARNING:
  • No Prop. 65 warning is required.

Other Information

HMIS RATINGS

• Health: 2 Flammability: 1 Physical Hazard: 0 Personal Protection: X
• NFPA RATINGS
• Health: 2 Flammability: 1 Instability: 0
• Volatile Organic Compounds: 0 g/L
• SDS REVISION DATE: 5/10/2021
• REASON FOR REVISION: Substance and/or Product Properties Changed in Section(s):
• 15 – Regulatory Information
• Revision Statement(s) Changed
• Legend: N.A. – Not Applicable, N.D. – Not Determined, N.E. – Not Established

Rust-Oleum Corporation believes, to the best of its knowledge, information and belief, the information contained herein to be accurate and reliable as of the date of this safety data sheet. However, because the conditions of handling, use, and storage of these materials are beyond our control, we assume no responsibility or liability for personal injury or property damage incurred by the use of these materials. Rust-Oleum Corporation makes no warranty, expressed or implied, regarding the accuracy or reliability of the data or results obtained from their use. All materials may present unknown hazards and should be used with caution. The information and recommendations in this material safety data sheet are offered for the users’ consideration and examination. It is the responsibility of the user to determine the final suitability of this information and to comply with all applicable international, federal, state, and local laws and regulations

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