HACH DOC343.97.80077 Analog Combination pH ORP Sensors User Manual
- June 14, 2024
- HACH
Table of Contents
DOC343.97.80077
Analog Combination pH/ORP
Sensors
01/2023, Edition 3
User Manual
Section 1 Specifications
Specifications are subject to change without notice.
Specification|
Details
---|---
Dimensions (length/diameter)| Convertible: 150 mm (5.9 in.)/33 mm (1.3 in.),
¾-in. NPT; Insertion: 150 mm
(5.9 in.)/22 mm (0.875 in.); Sanitary: 187 mm (7.4 in.)/22 mm (0.875 in.)
Pollution degree| 2
Overvoltage category| I
Protection class| III
Altitude| 2000 m (6562 ft) maximum
Operating temperature| 0 to 105 °C (32 to 221 °F)
Wetted materials| Convertible style (pH and ORP sensors): PPS body (glass
filled) Insertion style (pH and ORP sensors): PVDF body Sanitary style (pH
sensor): 316 stainless steel sleeved PVDF body
Common materials for all sensor styles include PTFE double junction, glass
process electrode, and FPM/FKM O-rings
Measuring range| pH sensor: 0 to 14 pH1 (or 2.00 to 14.00)
ORP sensor: -2000 to +2000 mV
Sensor cable| 4.5 m (15 ft)
Components| Corrosion-resistant materials, fully-submersible
Maximum flow rate| 2 m/s (6.6 ft/s) maximum
Immersion depth/pressure| 107 m (350 ft), 1050 kPa (100 psi) maximum
Pressure limit| 6.9 bar at 100 °C (100 psi at 212 °F)
Transmission distance| 100 m (328 ft) maximum when used with an sc digital
gateway
1000 m (3280 ft) maximum when used with an sc digital gateway and a termination box
Temperature element| PT100, PT1000 (default), NTC300 or none depending on the
analog sensor
Calibration methods| 1- or 2-point automatic or manual
Sensor interface| Modbus RTU from sc digital gateway or pH/ORP module
Certifications| Listed by ETL (US/Canada) for use in Class 1, Division 2,
Groups A, B, C, D, Temperature Code T4 – Hazardous Locations with Hach SC
Controller. Conforms to: CE, UKCA, FCC, ISED, ACMA, KC, CMIM, NM
1 Most pH applications are in the 2.5 to 12.5 pH range. Some industrial applications require accurate measurement and control below 2 or above 12 pH. In these special cases, please contact the manufacturer for further details.
Section 2 General information
In no event will the manufacturer be liable for damages resulting from any
improper use of product or failure to comply with the instructions in the
manual. The manufacturer reserves the right to make changes in this manual and
the products it describes at any time, without notice or obligation. Revised
editions are found on the manufacturer’s website.
2.1 Safety information
The manufacturer is not responsible for any damages due to misapplication or
misuse of this product including, without limitation, direct, incidental and
consequential damages, and disclaims such damages to the full extent permitted
under applicable law. The user is soley responsible to identify critical
application risks and install appropriate mechanisms to protect processes
during a possible equipment malfunction.
Please read this entire manual before unpacking, setting up or operating this
equipment. Pay attention to all danger and caution statements. Failure to do
so could result in serious injury to the operator or damage to the equipment.
Make sure that the protection provided by this equipment is not impaired. Do
not use or install this equipment in any manner other than that specified in
this manual.
2.1.1 Use of hazard information
DANGER
Indicates a potentially or imminently hazardous situation which, if not
avoided, will result in death or serious injury.
WARNING
Indicates a potentially or imminently hazardous situation which, if not
avoided, could result in death or serious injury.
CAUTION
Indicates a potentially hazardous situation that may result in minor or
moderate injury.
NOTICE
Indicates a situation which, if not avoided, may cause damage to the
instrument. Information that requires special emphasis.
2.1.2 Precautionary labels
Read all labels and tags attached to the instrument. Personal injury or damage
to the instrument could occur if not observed. A symbol on the instrument is
referenced in the manual with a precautionary statement.
This symbol, if noted on the instrument, references the instruction manual for
operation and/or safety information.
Electrical equipment marked with this symbol may not be disposed of in
European domestic or public disposal systems. Return old or end-of-life
equipment to the manufacturer for disposal at no charge to the user.
2.2 Product overview
This sensor is designed to work with a controller for data collection and
operation. Different controllers can be used with this sensor. This document
assumes sensor installation and use with an SC4500 Controller. To use the
sensor with other controllers, refer to the user manual for the controller
that is used.
Optional equipment, such as mounting hardware for the sensor, is supplied with
installation instructions. Several mounting options are available, allowing
the sensor to be adapted for use in many different applications.
2.3 Sensor styles
The sensor is available in different styles. Refer to Figure 1.
Figure 1 Sensor styles
- Convertible, flat electrode—for a pipe tee or an open vessel
- Convertible, dome electrode—for a pipe tee or an open vessel
- Insertion—allows removal without stopping the process flow
- Sanitary—for install in a 2-inch sanitary tee
Section 3 Installation
3.1 Mounting
WARNING
Explosion hazard. For installation in hazardous (classified) locations, refer
to the instructions and control drawings in the controller Class 1, Division 2
documentation. Install the sensor according to local, regional and national
codes. Do not connect or disconnect the instrument unless the environment is
known to be non-hazardous.
WARNING
Explosion hazard. Make sure that the mounting hardware for the sensor has a
temperature and pressure rating sufficient for the mounting location.
CAUTION
Personal injury hazard. Broken glass can cause cuts. Use tools and personal
protective equipment to remove broken glass.
NOTICE
The process electrode at the pH sensor tip has a glass bulb, which can break.
Do not hit or push on the glass bulb.
NOTICE
The gold or platinum process electrode at the tip of the ORP sensor has a
glass shank (hidden by the salt bridge), which can break. Do not hit or push
on the glass shank.
- Install the sensor where the sample that comes into contact with the sensor is representative of the entire process.
- Refer to Replacement parts and accessories on page 20 for the available mounting hardware.
- Refer to the instructions supplied with the mounting hardware for installation information.
- Install the sensor at least 15° above horizontal.
- For immersion installations, put the sensor at least 508 mm (20 inches) from the aeration basin wall and immerse the sensor at least 508 mm (20 inches) into the process.
- Remove the protective cap before the sensor is put into the process water. Keep the protective cap for future use.
- Calibrate the sensor before use.
For examples of sensors in different applications, refer to Figure 2.
Figure 2 Mounting examples
- Sanitary mount
- End of pipe immersion
- Flow-through mount
- Ball valve insertion
3.2 Connect the sensor to an SC Controller
Use one of the options that follows to connect the sensor to an SC Controller:
- Connect the sensor to an sc digital gateway, then connect the sc digital gateway to the SC Controller. The digital gateway converts the analog signal from the sensor to a digital signal.
- Install a sensor module in the SC Controller. Then, connect the sensor to the sensor module. The sensor module converts the analog signal from the sensor to a digital signal.
Refer to the instructions supplied with the sensor module or sc digital gateway. Refer to Replacement parts and accessories on page 20 for ordering information.
Section 4 Operation
4.1 User navigation
Refer to the controller documentation for the touchscreen description and
navigation information.
4.2 Configure the sensor
Use the Settings menu to enter identification information for the sensor and
to change options for data handling and storage.
- Select the main menu icon, then select Devices. A list of all of the available devices shows.
- Select the sensor and select Device menu > Settings.
- Select an option.
- For sensors connected to a pH/ORP module, refer to Table 1.
- For sensors connected to an sc digital gateway, refer to Table 2.
Table 1 Sensors connected to pH/ORP module
Option
|
Description
---|---
Name| Changes the name that corresponds to the sensor on the top of the
measurement screen. The name is limited to 16 characters in any combination of
letters, numbers, spaces or punctuation.
Sensor S/N| Lets the user enter the serial number of the sensor. The
serial number is limited to 16 characters in any combination of letters,
numbers, spaces or punctuation.
Format| For pH sensors only—Changes the number of decimal places that
are shown on the measurement screen to XX.XX (default) or XX.X
Temperature| Sets the temperature units to °C (default) or °F.
Temperature element| pH sensors —Sets the temperature element
for automatic temperature compensation to PT100, PT1000 (default) or NTC300.
If no element is used, the type can be set to Manual and a value for
temperature compensation can be entered (default: 25 °C).
ORP sensors —Temperature compensation is not used. A temperature element can be connected to the controller to measure temperature.
Filter| Sets a time constant to increase signal stability. The time
constant calculates the average value during a specified time—0 (no effect,
default) to 60 seconds (average of signal value for 60 seconds). The filter
increases the time for the sensor signal to respond to actual changes in the
process.
Pure H2O compensation| For pH sensors only—Adds a temperature-dependent
correction to the measured pH value for pure water with additives. Options:
None (default), Ammonia, Morpholine or User defined.
For process temperatures above 50 °C, the correction at 50 °C is used. For user-defined applications, a linear slope (default: 0 pH/°C) can be entered.
Data logger interval| Sets the time interval for sensor and temperature
measurement storage in the data log—5, 30 seconds, 1, 2, 5, 10, 15 (default),
30, 60 minutes.
Reset to default values| Sets the Settings menu to the factory default
settings and resets the counters. All sensor information is lost.
Table 2 Sensors connected to sc digital gateway
Option
|
Description
---|---
Name| Changes the name that corresponds to the sensor on the top of the
measurement screen. The name is limited to 12 characters in any combination of
letters, numbers, spaces or punctuation.
Select sensor| Selects the type of sensor (pH or ORP).
Format| Refer to Table 1.
Temperature| Refer to Table 1.
Data logger interval| Sets the time interval for sensor and temperature
measurement storage in the data log—5, 10, 15, 30 seconds, 1, 5, 10, 15
(default), 30 minutes, 1, 2, 6, 12 hours.
Alternating current frequency| Selects the power line frequency to get
the best noise rejection. Options: 50 or 60 Hz (default).
Filter| Refer to Table 1.
Temperature element| Refer to Table 1.
Select standard buffer| For pH sensors only—Sets the pH buffers used for
auto correction calibration. Options: 4.00, 7.00, 10.00 (default set) or DIN
19267 (pH 1.09, 4.65, 6.79, 9.23, 12.75)
Note: Other buffers can be used if the 1-or 2-point manual correction
is selected for calibration.
Pure H2O compensation| Refer to Table 1.
1-,2-,3- or 4-point matrix correction can also be selected. The 1-,2-,3- or
4-point matrix correction are compensation methods pre-programmed in the
firmware.
Last calibration| Sets a reminder for the next calibration (default:60
day
s). A reminder to calibrate the sensor shows on the display after the selected
interval from the date of the last calibration.
For example, if the date of the last calibration was June 15 and Last
calibration is set to 60 days, a calibration reminder shows on the display on
August 14. If the sensor is calibrated before August 14, on July 15, a
calibration reminder shows on the display on September 13.
Sensor days| Sets a reminder for sensor replacement (default:
365 days). A reminder to replace the sensor shows on the display after the
selected interval.
The Sensor days counter shows on the Diagnostics/Test > Counter menu.
When the sensor is replaced, reset the Sensor days counter on the
Diagnostics/Test > Counter menu.
Reset setup| Sets the Settings menu to the factory default settings and
resets the counters. All sensor information is lost.
4.3 Calibrate the sensor
WARNING
** Fluid pressure hazard. Removal of a sensor from a pressurized vessel can
be dangerous. Reduce the process pressure to below 7.25 psi (50 kPa) before
removal. If this is not possible, use extreme caution. Refer to the
documentation supplied with the mounting hardware for more information.
WARNING
** Chemical exposure hazard. Obey laboratory safety procedures and wear all
of the personal protective equipment appropriate to the chemicals that are
handled. Refer to the current safety data sheets (MSDS/SDS) for safety
protocols.
CAUTION
Chemical exposure hazard. Dispose of chemicals and wastes in accordance with
local, regional and national regulations.
4.3.1 About sensor calibration
Calibration adjusts the sensor reading to match the value of one or more
reference solutions. The sensor characteristics slowly shift over time and
cause the sensor to lose accuracy. The sensor must be calibrated regularly to
maintain accuracy. The calibration frequency varies with the application and
is best determined by experience.
A temperature element is used to provide pH readings that are automatically
adjusted to 25 °C for temperature changes that affect the active and reference
electrode. This adjustment can be manually set by the customer if the process
temperature is constant.
During calibration, data is not sent to the datalog. Thus, the datalog can
have areas where the data is intermittent.
4.3.2 Change calibration options
For sensors connected to a pH/ORP module, the user can set a reminder or
include an operator ID with calibration data from the Calibration options
menu.
Note: This procedure is not applicable to sensors connected to an sc
digital gateway.
- Select the main menu icon, then select Devices. A list of all of the available devices shows.
- Select the sensor and select Device menu > Calibration.
- Select Calibration options.
- Select an option.**
Option| Description**
---|---
Select standard buffer| For pH sensors only—Sets the pH buffers used for auto correction calibration. Options: 4.00, 7.00, 10.00 (default set), DIN 19267 (pH 1.09, 4.65, 6.79, 9.23, 12.75) or NIST 4.00, 6.00, 9.00
Note: Other buffers can be used if the 1-or 2-point value calibration is selected for calibration.
Calibration reminder| Sets a reminder for the next calibration (default: Off). A reminder to calibrate the sensor shows on the display after the selected interval from the date of the last calibration. For example, if the date of the last calibration was June 15 and Last calibration is set to 60 days, a calibration reminder shows on the display on August 14. If the sensor is
calibrated before August 14, on July 15, a calibration reminder shows on the display on September 13.
Operator ID for calibration| Includes an operator ID with calibration data—Yes or No (default). The ID is entered during the calibration.
4.3.3 pH calibration procedure
Calibrate the pH sensor with one or two reference solutions (1-point or
2-point calibration). Standard buffers are automatically recognized.
-
Put the sensor in the first reference solution (a buffer or sample of known value). Make sure that the sensor portion of the probe is fully immersed in the liquid (Figure 3).
Figure 3 Sensor in reference solution
-
Wait for the sensor and solution temperature to equalize. This can take 30 minutes or more if the temperature difference between the process and reference solution is significant.
-
Select the main menu icon, then select Devices. A list of all of the available devices shows.
-
Select the sensor and select Device menu > Calibration.
-
Select the type of calibration:
Option| Description
---|---
1-point buffer calibration
(or 1-point auto correction)| Use one buffer for calibration (e.g., pH 7). The sensor automatically identifies the buffer during calibration.
Note: Make sure to select the buffer set in the Calibration > Calibration options > Select standard buffer menu (or Settings > Select standard buffer menu).
2-point buffer calibration (or 2-point auto correction)| Use two buffers for calibration (e.g., pH 7 and pH 4). The sensor automatically identifies the buffers during calibration.
Note: Make sure to select the buffer set in the Calibration > Calibration options > Select standard buffer menu (or Settings > Select standard buffer menu).
1-point value calibration (or 1-point manual correction)| Use one sample of a known value (or one buffer) for calibration. Determine the pH value of the sample with a different instrument. Enter the pH value during calibration.
2-point value calibration (or 2-point manual correction)| Use two samples of known value (or two buffers) for calibration. Determine the pH value of the samples with a different instrument. Enter the pH values during calibration. -
Select the option for the output signal during calibration:
Option| Description
---|---
Active| The instrument sends the current measured output value during the calibration procedure.
Hold| The sensor output value is held at the current measured value during the calibration procedure.
Transfer| A preset output value is sent during calibration. Refer to the controller user manual to change the preset value. -
ith the sensor in the first reference solution, push OK.
The measured value is shown. -
Wait for the value to stabilize and push OK.
Note: The screen may advance to the next step automatically. -
If applicable, enter the pH value and push OK.
Note: If the reference solution is a buffer, find the pH value on the buffer bottle for the temperature of the buffer.
If the reference solution is a sample, determine the pH value of the sample with a different instrument. -
For a 2-point calibration, measure the second reference solution as follows:
a. Remove the sensor from the first solution and rinse with clean water.
b. Put the sensor in the next reference solution, then push OK.
c. Wait for the value to stabilize and push OK.
Note: The screen may advance to the next step automatically.
d. If applicable, enter the pH value and p ush OK. -
Review the calibration result:
• “The calibration was successfully completed.”—The sensor is calibrated and ready to measure samples. The slope and/or offset values are shown.
• “The calibration failed.” —The calibration slope or offset is outside of accepted limits. Repeat the calibration with fresh reference solutions. Clean the sensor if necessary. -
Push OK.
-
Return the sensor to the process and push OK.
The output signal returns to the active state and the measured sample value is shown on the measurement screen.
4.3.4 ORP calibration procedure
Calibrate the ORP sensor with one reference solution (1-point calibration).
-
Put the sensor in the reference solution (a reference solution or sample of known value). Make sure that the sensor portion of the probe is fully immersed in the solution (Figure 4).
Figure 4 Sensor in reference solution -
Select the main menu icon, then select Devices. A list of all of the available devices shows.
-
Select the sensor and select Device menu > Calibration.
-
Select 1-point value calibration (or 1-point manual correction).
-
Select the option for the output signal during calibration:
Option| Description
---|---
Active| The instrument sends the current measured output value during the calibration procedure.
Hold| The sensor output value is held at the current measured value during the calibration procedure.
Transfer| A preset output value is sent during calibration. Refer to the controller user manual to change the preset value. -
With the sensor in the reference solution or sample, push OK.
The measured value is shown. -
Wait for the value to stabilize and push OK.
Note: The screen may advance to the next step automatically. -
If a sample is used for calibration, measure the ORP value of the sample with a secondary mverification instrument. Enter the measured value, then push OK.
-
If a reference solution is used for calibration, enter the ORP value marked on the bottle. Push OK.
-
Review the calibration result:
• “The calibration was successfully completed.”—The sensor is calibrated and ready to measure samples. The slope and/or offset values are shown.
• “The calibration failed.” —The calibration slope or offset is outside of accepted limits. Repeat the calibration with fresh reference solutions. Clean the sensor if necessary. -
Push OK.
-
Return the sensor to the process and push OK.
The output signal returns to the active state and the measured sample value is shown on the measurement screen.
4.3.5 Temperature calibration
The instrument is calibrated at the factory for accurate temperature
measurement. The temperature can be calibrated to increase accuracy.
-
Put the sensor in a container of water.
-
Measure the temperature of the water with an accurate thermometer or independent instrument.
-
Select the main menu icon, then select Devices. A list of all of the available devices shows.
-
Select the sensor and select Device menu > Calibration.
-
For sensors connected to a pH/ORP module, do the steps that follow:
a. Select 1-point temperature calibration.
b. Wait for the value to stabilize, then push OK.
c. Enter the exact value and push OK. -
For sensors connected to an sc digital gateway, do the steps that follow:
a. Select Temperature adjustment.
b. Wait for the value to stabilize, then push OK.
c. Select Edit Temperature.
d. Enter the exact value and push OK. -
Return the sensor to the process and push the home icon.
4.3.6 Exit calibration procedure
- To exit a calibration, push the back icon.
- Select an option, then push OK.
| Option | Description |
|---|---|
| Quit calibration (or Cancel) | Stop the calibration. A new calibration must |
start from the beginning.
Return to calibration| Return to the calibration.
Leave calibration (or Exit)| Exit the calibration temporarily. Access to other
menus is allowed. A calibration for a second sensor (if present) can be
started.
4.3.7 Reset the calibration
The calibration can be reset to the factory default settings. All sensor
information is lost.
- Select the main menu icon, then select Devices. A list of all of the available devices shows.
- Select the sensor and select Device menu > Calibration.
- Select Reset to default calibration values (or Reset setup), then push OK.
- Push OK again.
4.4 Impedance measurements
To increase the reliability of the pH measurement system, the controller
determines the impedance of the glass electrodes. This measurement is taken
every minute. During diagnostics, the pH measurement reading will be on hold
for five seconds. If an error message appears, refer to Error list on page 17
for more details.
Note: This procedure does not apply to sensors connected to an sc digital
gateway.
To enable or disable the sensor impedance measurement:
- Select the main menu icon, then select Devices. A list of all of the available devices shows.
- Select the device and select Device menu > Diagnostics/Test.
- For sensors connected to a pH/ORP module, select Impedance status.
- Select Enabled or Disabled and push OK.
4.5 Modbus registers
A list of Modbus registers is available for network communication. Refer to
the manufacturer’s website for more information.
Section 5 Maintenance
WARNING
** Multiple hazards. Only qualified personnel must conduct the tasks
described in this section of the document.
WARNING
** Explosion hazard. Do not connect or disconnect the instrument unless the
environment is known to be non-hazardous. Refer to the controller Class 1,
Division 2 documentation for hazardous location instructions.
WARNING
** Fluid pressure hazard. Removal of a sensor from a pressurized vessel can
be dangerous. Reduce the process pressure to below 7.25 psi (50 kPa) before
removal. If this is not possible, use extreme caution. Refer to the
documentation supplied with the mounting hardware for more information.
WARNING
** Chemical exposure hazard. Obey laboratory safety procedures and wear all
of the personal protective equipment appropriate to the chemicals that are
handled. Refer to the current safety data sheets (MSDS/SDS) for safety
protocols.
CAUTION
**** Chemical exposure hazard. Dispose of chemicals and wastes in accordance
with local, regional and national regulations.
5.1 Maintenance schedule
Table 3 shows the recommended schedule of maintenance tasks. Facility
requirements and operating conditions may increase the frequency of some
tasks.
Table 3 Maintenance schedule
| Maintenance task | 1 year | As necessary |
|---|---|---|
| Clean the sensor on page 15 | X | |
| Set by regulatory agencies or experience |
5.2 Clean the sensor
Pre-requisite: Prepare a mild soap solution with a non-abrasive dishwashing
detergent that does not contain lanolin. Lanolin leaves a film on the
electrode surface that can degrade the sensor performance.
Examine the sensor periodically for debris and deposits. Clean the sensor when
there is a buildup of deposits or when performance has degraded.
- Use a clean, soft cloth to remove loose debris from the end of the sensor. Rinse the sensor with clean, warm water.
- Soak the sensor for 2 to 3 minutes in the soap solution.
- Use a soft bristle brush to scrub the entire measuring end of the sensor.
- If debris remains, soak the measuring end of the sensor in a dilute acid solution such as < 5% HCl for a maximum of 5 minutes.
- Rinse the sensor with water and then return to the soap solution for 2 to 3 minutes.
- inse the sensor with clean water.
Note: Sensors with antimony electrodes for HF applications may require additional cleaning. Contact technical support.
Always calibrate the sensor after maintenance procedures are done.
5.3 Prepare for storage
For short-term storage (when the sensor is out of the process for more than
one hour), fill the protective cap with pH 4 buffer or distilled water and put
the cap back on the sensor. Keep the process electrode and reference junction
salt bridge moist to avoid slow response when the sensor is returned to
operation.
For extended storage, repeat the short-term storage procedure every 2 to 4
weeks, depending on the environmental conditions. Refer to Specifications on
page 3 for temperature storage limits.
Section 6 Troubleshooting
6.1 Intermittent data
During calibration, data is not sent to the datalog. Thus, the datalog can
have areas where the data is intermittent.
6.2 Test the pH sensor
Pre-requisites: Two pH buffers and a multimeter.
If a calibration fails, first complete the maintenance procedures in
Maintenance on page 15.
-
Put the sensor in a pH 7 buffer solution and wait for the temperature of the sensor and buffer to reach room temperature.
-
Disconnect the red (or green for 6-plug sensors) and white wires from the module or digital gateway.
-
Measure the resistance between the red (or green for 6-plug sensors) and white wires to verify the operation of the temperature element. The resistance should be between 1090 and 1105 ohms at approximately 25 ºC.
If the temperature element is good, reconnect the wires to the module. -
Push the main menu icon, then select Devices. A list of all of the available devices shows.
-
Select the device and select Device menu > Diagnostics/Test.
-
Select Sensor signals (or Signals). The reading should be between –50 and + 50 mV.
-
Rinse the sensor with water and put it in a pH 4 or pH 10 buffer solution. Wait for the temperature of the sensor and buffer to reach room temperature.
-
Compare the mV reading in the pH 4 or 10 buffer to the reading in the pH 7 buffer. The reading should differ by approximately 160 mV.
If the difference is less than 160 mV, call technical support.
6.3 Diagnostics/Test menu
The Diagnostics/Test menu shows current and historical information about the
sensor. Refer to Table 4. Push the main menu icon, then select Devices. Select
the device and select Device menu > Diagnostics/Test.
Table 4 Diagnostics/Test menu
Option
|
Description
---|---
Module information| For sensors connected to a pH/ORP module
only—Shows the version and the serial number for the sensor module.
Sensor information| For sensors connected to a pH/ORP module—Shows
the sensor name and the serial number entered by the user.
For sensors connected to an sc digital gateway—Shows the sensor model number,
and the sensor name entered by the user and the sensor serial number. Shows
the software version and driver version installed.
Last calibration| For sensors connected to a pH/ORP module only—Shows
the number of days since the last calibration was done.
Calibration history| For sensors connected to a pH/ORP module—Shows the
calibration slope and date of the previous calibrations.
For sensors connected to an sc digital gateway—Shows the calibration slope and
date of the last calibration.
Reset calibration history| For sensors connected to a pH/ORP module
only—For service use only
Impedance status| For pH sensors only—Refer to Impedance measurements on
page 14.
Note: Impedance status is not available for sensors connected to an
sc digital gateway.
Sensor signals (or Signals )| For pH sensors connected to a pH/ORP
module only—Shows the current reading in mV.
For pH sensors connected to an sc digital gateway—Shows the current reading in
mV and the analog to digital converter counters.
If Impedance status is set to Enabled, shows the Sensor diagnostics value
(mV).
Sensor days (or Counter )| For sensors connected to a pH/ORP
module—Shows the number of days that the sensor has been in operation.
For sensors connected to an sc digital gateway—Shows the number of days that
the sensor and electrode(s) have been in operation. The Electrode days counter
is reset to zero when the firmware identifies that a defective electrode has
been replaced with an electrode that operates correctly.
To reset the Sensor days counter to zero, select Reset. Reset the Sensor
days counter when the sensor is replaced.
6.4 Error list
When an error occurs, the reading on the measurement screen flashes and all
outputs are held when specified in the Controller > Outputs menu. The screen
changes to red. The diagnostics bar shows the error. Push on the diagnostic
bar to show the errors and warnings. As an alternative, push the main menu
icon, then select Notifications > Errors.
A list of possible errors is shown in Table 5.
Table 5 Error list
Error
| Description|
Resolution
---|---|---
pH value is too high!| The measured pH is > 14.| Calibrate or replace the
sensor.
ORP value is too high!| The measured ORP value is > 2100 mV.|
pH value is too low!| The measured pH is < 0.| Calibrate or replace the
sensor.
ORP value is too low!| The measured ORP value is < –2100 mV.
Offset value is too high.| The offset is > 9 (pH) or 200 mV (ORP).| Follow the
maintenance procedures for the sensor and then repeat the calibration, or
replace the sensor.
Offset value is too low.| The offset is < 5 (pH) or –200 mV (ORP).
Slope is too high.| The slope is > 62 (pH)/1.3 (ORP).| Repeat the calibration
with a fresh buffer or sample, or replace the sensor.
Slope is too low.| The slope is < 50 (pH)/0.7 (ORP).| Clean the sensor, then
repeat the calibration, or replace the sensor.
Temperature is too high!| The measured temperature is >130 °C.| Make sure that
the correct temperature element is selected.
Temperature is too low!| The measured temperature is< –10 °C.
ADC failure| The analog to digital conversion failed.| Power off and power on
the controller. Contact technical support.
The difference between the buffers is too small!| The buffers for 2-point auto
correction have the same value.| Complete the steps in Test the pH sensor on
page 16.
Sensor is missing.| The sensor is missing or disconnected.| Examine the wiring
and connections for the sensor and for the module (or digital gateway).
Temperature sensor is missing!| The temperature sensor is missing.| Examine
the wiring for the temperature sensor. Make sure that the correct temperature
element is selected.
Glass impedance is too low.| The glass bulb is broken or reached end of life.|
Replace the sensor. Contact technical support.
6.5 Warning list
A warning does not affect the operation of menus, relays and outputs. The
screen changes to an amber color. The diagnostics bar shows the warning. Push
on the diagnostic bar to show the errors and warnings. As an alternative, push
the main menu icon, then select Notifications > Warnings. A list of possible
warnings is shown in Table 6.
Table 6 Warning list
Warning| Description|
Resolution
---|---|---
pH is too high.| The measured pH is > 13.| Calibrate or replace the sensor.
ORP value is too high.| The measured ORP value is > 2100 mV.
pH is too low.| The measured pH is < 1.| Calibrate or replace the sensor.
ORP value is too low.| The measured ORP value is < –2100 mV.
Offset value is too high.| The offset is > 8 (pH) or 200 mV (ORP).| Follow the
maintenance procedures for the sensor and then repeat the calibration.
Offset value is too low.| The offset is < 6 (pH) or –200 mV (ORP).
Slope is too high.| The slope is > 60 (pH)/1.3 (ORP).| Repeat the calibration
with a fresh buffer or sample.
Slope is too low.| The slope is < 54 (pH)/0.7 (ORP).| Clean the sensor, then
repeat the calibration.
Temperature is too high.| The measured temperature is > 100 °C.| Make sure the
right temperature element is used.
Temperature is too low.| The measured temperature is < 0 °C.|
Temperature is out of range.| The measured temperature is > 100 °C or < 0 °C.|
Calibration is overdue.| The Cal Reminder time has expired.| Calibrate the
sensor.
The device is not calibrated.| The sensor has not been calibrated.| Calibrate
the sensor.
Flash failure| The external flash memory failed.| Contact technical support.
Replace a sensor.| The Sensor days counter is more than the interval selected
for sensor replacement. Refer to Configure the sensor on page 8.| Replace the
sensor. Reset the Sensor days counter on the Diagnostics/Test > Reset menu (or
Diagnostics/Test > Counter menu.
Calibration is in progress…| A calibration was started but not completed.|
Return to calibration.
Temperature is not calibrated.| The temperature sensor is not calibrated.| Do
a temperature calibration.
6.6 Event list
The diagnostic bar shows current activities such as configuration changes,
alarms, warning conditions, etc. A list of possible events is shown in Table
7. Previous events are recorded in the event log, which can be downloaded from
the controller. Refer to the controller documentation for data retrieval
options.
Table 7 Event list
Event
|
Description
---|---
Calibration ready| The sensor is ready for calibration.
The calibration is OK.| The current calibration is good.
The time has expired.| The stabilization time during calibration expired.
There is no buffer available.| No buffer is detected.
Slope is too high.| The calibration slope is above the upper limit.
Slope is too low.| The calibration slope is below the lower limit.
Offset value is too high.| The calibration offset value for the sensor is
above the upper limit.
Offset value is too low.| The calibration offset value for the sensor is below
the lower limit.
The calibration points are too close for a correct calibration.| The
calibration points are too similar in value for a 2-point calibration.
The calibration failed.| The calibration failed.
The calibration is high.| The calibration value is above the upper limit.
The reading is unstable.| The reading during calibration was unstable.
Change in configuration float value| The configuration was changed—floating
point type.
Change in configuration text value| The configuration was changed—text type.
Change in configuration| The configuration was reset to the default options.
Power is on.| The power was turned on.
ADC failure| The analog to digital conversion failed (hardware failure).
Flash erase| The flash memory was erased.
Temperature| The recorded temperature is too high or too low.
Start of 1-point manual calibration| Start of 1-point sample calibration
Start of 1-point auto calibration| Start of 1-point buffer calibration for pH
Start of 1-point temperature calibration| Start of 1-point temperature
calibration
Start of 2-point manual calibration| Start of 2-point sample calibration for
pH
Start of 2-point auto calibration| Start of 2-point buffer calibration for pH
End of 1-point manual calibration| End of 1-point sample calibration
End of 1-point auto calibration| End of 1-point buffer calibration for pH
End of 1-point temperature calibration| End of 1-point temperature calibration
End of 2-point manual calibration| End of 2-point sample calibration for pH
End of 2-point auto calibration| End of 2-point buffer calibration for pH
Section 7 Replacement parts and accessories
WARNING
** Personal injury hazard. Use of non-approved parts may cause personal
injury, damage to the instrument or equipment malfunction. The replacement
parts in this section are approved by the manufacturer.
Note: Product and Article numbers may vary for some selling regions. Contact
the appropriate distributor or refer to the company website for contact
information.
Consumables**
Description
| Quantity|
Item no.
---|---|---
Buffer Solution, pH 4, red| 500 mL| 2283449
Buffer Solution, pH 7, yellow| 500 mL| 2283549
Buffer Solution, pH 10, blue| 500 mL| 2283649
ORP Reference Solution, 200 mV| 500 mL| 25M2A1001-115
ORP Reference Solution, 600 mV| 500 mL| 25M2A1002-115
Accessories
Description|
Item no.
---|---
pH/ORP module| LXZ525.99.D0003
sc digital gateway for combination pH/ORP sensor| 6120600
Sanitary mount hardware, 316 stainless steel, includes 2-inch sanitary tee and
heavy- duty clamp
Note: Cap and EPDM compound gasket are supplied with the sensor.|
MH018S8SZ
Union mount hardware, CPVC (chlorinated polyvinyl chloride), includes 1½-inch
standard tee, union pipe with adapter, sealing hub, lock ring and FPM/FKM
O-ring| 6131300
Union mount hardware, 316 stainless steel, includes 1½-inch standard tee,
union pipe with adapter, sealing hub, lock ring and FPM/FKM O-ring| 6131400
Flow-through mount hardware, CPVC, includes 1-inch standard tee| MH334N4NZ
Flow-through mount hardware, 316 stainless steel, includes 1-inch standard
tee| MH314N4MZ
Insertion mount hardware, CPVC, includes 1½-inch ball valve, 1½-inch NPT close
nipple, sensor adapter with two FPM/FKM O-rings and wiper, extension pipe,
pipe adapter, back tube and lock ring| 5646400
Insertion mount hardware, 316 stainless steel, includes 1½-inch ball valve,
1½-inch NPT close nipple, sensor adapter with two FPM/FKM O-rings and wiper,
extension pipe, pipe adapter, back tube and lock ring| ** 5646450
Immersion mount hardware, standard, CPVC, includes 1-inch by 4 ft pipe and
1-inch x 1-inch NPT coupling| MH434A00B
Immersion mount hardware, standard, 316 stainless steel, includes 1-inch by 4
ft pipe and 1-inch x 1-inch NPT coupling| MH414A00B
Immersion mount hardware, handrail, includes 1½ inch by 7.5 ft CPVC pipe and
pipe clamp assembly| MH236B00Z
Immersion mount hardware, chain, 316 stainless steel, includes stainless steel
bail, nuts and washers
Note: For stainless steel sensor use only. Does not include chain.|
** 2881900
Immersion mount hardware, ball float, includes 1½ inch by 7.5 ft CPVC pipe,
ball float assembly and pipe clamp assembly| 6131000
Safety lock for quick-connect fitting, Class 1 Div 2 installations| 6139900
Sensor guard, convertible style sensor, PEEK| 1000F3374-002
Sensor guard, convertible style sensor, PPS| 1000F3374-003
HACH COMPANY World Headquarters
P.O. Box 389, Loveland, CO 80539-0389 U.S.A.
Tel. 970-669-3050
800-227-4224 (U.S.A. only)
Fax 970-669-2932
orders@hach.com
www.hach.com
©Hach Company/Hach Lange GmbH, 2010, 2022.
All rights reserved. Printed in U.S.A.
Documents / Resources
| HACH
DOC343.97.80077 Analog Combination pH ORP
Sensors
[pdf] User Manual
DOC343.97.80077, DOC343.97.80077 Analog Combination pH ORP Sensors,
DOC343.97.80077, Analog Combination pH ORP Sensors, Combination pH ORP
Sensors, pH ORP Sensors, ORP Sensors, Sensors
---|---
Read User Manual Online (PDF format)
Read User Manual Online (PDF format) >>