Tresemme Keratin Hairspray Smooth Flexible Hold Owner’s Manual
- June 1, 2024
- TRESemme
Table of Contents
- Section 1. Identification
- Section 2. Hazards identification
- Section 3. Composition/information on ingredients
- Section 5. Fire-fighting measures
- Section 6. Accidental release measures
- Section 7. Handling and storage
- Section 8. Exposure controls/personal protection
- Section 9. Physical and chemical properties
- Section 10. Stability and reactivity
- Section 11. Toxicological information
- Section 12. Ecological information
- Section 13. Disposal considerations
- Section 14. Transport information
- Section 15. Regulatory information
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Tresemme Keratin Hairspray Smooth Flexible Hold Owner's Manual
Section 1. Identification
Product name : TRESemme Keratin Hairspray Smooth Flexible Hold (Aerosol)
Product description : Hair Styling Product
Product code : 200000271904
Product code : 69789628_C, 69776756
Relevant identified uses of the substance or mixture and uses advised against
Supplier’s details : UNILEVER
700 Sylvan Avenue
Englewood Cliffs NJ 07632
USA
Emergency telephone number (with hours of operation) :
Phone #: 800-761-3683 Monday thru
Friday (8:30 AM – 5:00 PM EST)
Emergency #: 800-745-9269 (24 hours)
Poison Control #: 800-949-7866 (24
hours)
CHEMTREC #: 800-424-9300(24 hours,
Transportation Emergencies)
Consumer Information:
For information regarding the use of this product by a consumer, please refer
directly to the product label. This
industrial MSDS is provided for workplace employees, per US OSHA regulations.
It contains recommendations for handling of this product in an occupational,
or workplace, setting.
Any first aid or warnings that are applicable to consumer use are stated directly on the product label, in accordance with all applicable government regulations.
Section 2. Hazards identification
OSHA/HCS status : This material is considered hazardous by the OSHA
Hazard Communication Standard (29 CFR 1910.1200).
Classification of the substance or mixture : FLAMMABLE AEROSOLS –
Category 2
GASES UNDER PRESSURE – Compressed gas
GHS label elements
Hazard pictograms :
Signal word : Warning
Hazard statements : Flammable aerosol.
Contains gas under pressure; may explode if heated.
Precautionary statements
General : Not applicable.
Prevention : Keep away from heat, hot surfaces, sparks, open flames and
other ignition sources. No smoking. Do not spray on an open flame or other
ignition source. Pressurized container: Do not pierce or burn, even after use.
Response : Not applicable.
Storage : Protect from sunlight. Store in a well-ventilated place. Do not
expose to temperatures exceeding 50 °C/122 °F.
Disposal : Not applicable.
Supplemental label elements : None known.
Hazards not otherwise classified : None known.
Section 3. Composition/information on ingredients
Substance/mixture : Mixture
CAS number/other identifiers
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
There are no additional ingredients present which, within the current
knowledge of the supplier and in the concentrations applicable, are classified
as hazardous to health or the environment and hence require reporting in this
section.
Occupational exposure limits, if available, are listed in Section 8.
Section 4. First aid measures
Description of necessary first aid measures
Eye contact : Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention if irritation occurs. Inhalation : Remove victim to fresh air and keep at rest in a position comfortable for breathing. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention if adverse health effects persist or are severe. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Skin contact : Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Get medical attention if symptoms occur. Wash clothing before reuse. Clean shoes thoroughly before reuse.
Ingestion : Wash out mouth with water. Remove dentures if any. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get medical attention if adverse health effects persist or are severe. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Most important symptoms/effects, acute and delayed
Potential acute health effects
Eye contac t : No known significant effects or critical hazards.
Inhalation : No known significant effects or critical hazards.
Skin contact : No known significant effects or critical hazards.
Ingestion : No known significant effects or critical hazards.
Over-exposure signs/symptoms
Eye contact : Adverse symptoms may include the following: irritation
redness
Inhalation : Adverse symptoms may include the following: respiratory
tract irritation coughing
Skin contact : No specific data.
Ingestion : None known.
Indication of immediate medical attention and special treatment needed, if necessary
Notes to physician : Treat symptomatically. Contact poison treatment
specialist immediately if large quantities have been ingested or inhaled.
Specific treatments : No specific treatment.
Protection of first-aiders : No action shall be taken involving any
personal risk or without suitable training. It may be dangerous to the person
providing aid to give mouth-to-mouth resuscitation.
See toxicological information (Section 11)
Section 5. Fire-fighting measures
Extinguishing media
Suitable extinguishing media : Use an extinguishing agent suitable for
the surrounding fire.
Unsuitable extinguishing media : None known.
NFPA 30B Classification : Aerosol Level 1
Specific hazards arising from the chemical : Flammable aerosol. Runoff to
sewer may create fire or explosion hazard. In a fire or if heated, a pressure
increase will occur and the container may burst, with the risk of a subsequent
explosion. Gas may accumulate in low or confined areas or travel a
considerable distance to a source of ignition and flash back, causing fire or
explosion. Bursting aerosol containers may be propelled from a fire
at high speed.
Hazardous thermal decomposition products : No specific data.
Special protective actions for fire- fighters :
Promptly isolate the scene by removing all persons from the vicinity of the
incident if there is a fire. No action shall be taken involving any personal
risk or without suitable training. Move containers from fire area if this can
be done without risk. Use water spray to keep fire-exposed containers cool.
Special protective equipment for fire-fighters : Fire-fighters should wear appropriate protective equipment and self- contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Section 6. Accidental release measures
Personal precautions, protective equipment and emergency procedures
For non-emergency personnel :
No action shall be taken involving any personal risk or without suitable
training. Evacuate surrounding areas. Keep unnecessary and unprotected
personnel from entering. In the case of aerosols being ruptured, care should
be taken due to the rapid escape of the pressurized contents and propellant.
If a large number of containers are ruptured, treat as a bulk material
spillage according to the instructions in the clean-up section. Do not touch
or walk through spilled material. Shut off all ignition sources. No flares,
smoking or flames in hazard area. Avoid breathing vapor or mist. Provide
adequate ventilation. Wear appropriate respirator when ventilation is
inadequate. Put on appropriate personal protective equipment.
For emergency responders : If specialized clothing is required to deal
with the spillage, take note of any information in Section 8 on suitable and
unsuitable materials.
See also the information in “For non-emergency personnel”.
Environmental precautions : Avoid dispersal of spilled material and
runoff and contact with soil, waterways, drains and sewers. Inform the
relevant authorities if the product has caused environmental pollution
(sewers, waterways, soil or air).
Methods and materials for containment and cleaning up
Small spill : Stop leak if without risk. Move containers from spill area.
Use spark-proof tools and explosion-proof equipment. Dilute with water and mop
up if water-soluble. Alternatively, or if water-insoluble, absorb with an
inert dry material and place in an appropriate waste disposal container.
Dispose of via a licensed waste disposal contractor.
Large spill : Stop leak if without risk. Move containers from spill area.
Use spark-proof tools and explosion-proof equipment. Approach release from
upwind. Prevent entry into sewers, water courses, basements or confined areas.
Wash spillages into an effluent treatment plant or proceed as follows. Contain
and collect spillage with non- combustible, absorbent material e.g. sand,
earth, vermiculite or diatomaceous earth and place in container for disposal
according to local regulations (see Section 13). Dispose of via a licensed
waste disposal contractor. Contaminated absorbent material may pose the same
hazard as the spilled product. Note: see Section 1 for emergency contact
information and Section 13 for waste disposal.
Section 7. Handling and storage
Precautions for safe handling
Protective measures : Put on appropriate personal protective equipment
(see Section 8).
Pressurized container: protect from sunlight and do not expose to
temperatures exceeding 50°C. Do not pierce or burn, even after use.
Do not ingest. Avoid contact with eyes, skin and clothing. Avoid breathing
gas. Avoid breathing vapor or mist. Use only with adequate ventilation. Wear
appropriate respirator when ventilation is inadequate. Store and use away from
heat, sparks, open flame or any other ignition source. Use explosion-proof
electrical (ventilating, lighting and material handling) equipment. Use only
non-sparking tools. Empty containers retain product residue and can be
hazardous.
Advice on general occupational hygiene : Eating, drinking and smoking
should be prohibited in areas where
this material is handled, stored and processed. Workers should wash hands and
face before eating, drinking and smoking. Remove contaminated clothing and
protective equipment before entering eating areas. See also Section 8 for
additional information on hygiene measures.
Conditions for safe storage, including any incompatibilities : Store in
accordance with local regulations. Store away from direct sunlight in a dry,
cool and well-ventilated area, away from incompatible materials (see Section
10) and food and drink. Protect from sunlight. Eliminate all ignition sources.
Use appropriate containment to avoid environmental contamination. See Section
10 for incompatible materials before handling or use.
Section 8. Exposure controls/personal protection
Control parameters
Occupational exposure limits
Appropriate engineering controls : Use only with adequate ventilation. If
user operations generate dust,
fumes, gas, vapor or mist, use process enclosures, local exhaust ventilation
or other engineering controls to keep worker exposure to airborne contaminants
below any recommended or statutory limits.
The engineering controls also need to keep gas, vapor or dust concentrations
below any lower explosive limits. Use explosion- proof ventilation equipment.
Environmental exposure controls : Emissions from ventilation or work
process equipment should be checked to ensure they comply with the
requirements of environmental protection legislation. In some cases, fume
scrubbers, filters or engineering modifications to the process equipment will
be necessary to reduce emissions to acceptable levels.
Individual protection measures
Hygiene measures : Wash hands, forearms and face thoroughly after
handling chemical products, before eating, smoking and using the lavatory and
at the end of the working period. Appropriate techniques should be used to
remove potentially contaminated clothing. Wash contaminated clothing before
reusing. Ensure that eyewash stations and safety showers are close to the
workstation location.
Eye/face protection : Safety eyewear complying with an approved standard
should be used when a risk assessment indicates this is necessary to avoid
exposure to liquid splashes, mists, gases or dusts. If contact is possible,
the following protection should be worn, unless the assessment indicates a
higher degree of protection: safety glasses with side-shields.
Skin protection
Hand protection : Chemical-resistant, impervious gloves complying with an
approved standard should be worn at all times when handling chemical products
if a risk assessment indicates this is necessary. Considering the parameters
specified by the glove manufacturer, check during use that the gloves are
still retaining their protective properties. It should be noted that the time
to breakthrough for any glove material may be different for different glove
manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.
Body protection : Personal protective equipment for the body should be
selected based on the task being performed and the risks involved and should
be approved by a specialist before handling this product., When there is a
risk of ignition from static electricity, wear anti-static protective
clothing., For the greatest protection from static discharges, clothing
should include anti-static overalls, boots and gloves.
Other skin protection : Appropriate footwear and any additional skin
protection measures should be selected based on the task being performed and
the risks involved and should be approved by a specialist before handling this
product.
Respiratory protection : Based on the hazard and potential for exposure, select a respirator that meets the appropriate standard or certification. Respirators must be used according to a respiratory protection program to ensure proper fitting, training, and other important aspects of use.
Section 9. Physical and chemical properties
Appearance
Physical state : liquid [aerosol] Color : No results available.
Odor : Characteristic.
Odor threshold : Not available.
pH : Not available.
Melting point : Not applicable Under normal conditions, melting
point/freezing point will not be observed
Boiling point : Not available.
Flash point : not applicable
Evaporation rate : Not available.
Flammability (solid, gas) : Not available.
Lower and upper explosive (flammable) limits :
Lower : Not available.
Upper : Not available.
Vapor density : Not available.
Relative density : Not available.
Solubility : Not available.
Solubility in water : Not available.
Partition coefficient : noctanol/water : Not available.
Auto-ignition temperature : Not available.
Decomposition temperature : Not available.
Viscosity :
Dynamic : Not available.
Kinematic : Not available.
Aerosol product
Type of aerosol : Spray
Can pressure : 11,650 hPa at 54°C/130°F
Heat of combustion : < 20000000 J/kg
Ignition distance : 70 cm
Enclosed space ignition – Time equivalent : Not available.
Enclosed space ignition – Deflagration density : Not available.
Flame height : Not available.
Flame duration : Not available.
Section 10. Stability and reactivity
Reactivity : No specific test data related to reactivity available for
this product or its ingredients.
Chemical stability : The product is stable.
Possibility of hazardous reactions : Under normal conditions of storage
and use, hazardous reactions
will not occur.
Conditions to avoid : Avoid all possible sources of ignition (spark or
flame).
Incompatible materials : None known.
Hazardous decomposition products : Under normal conditions of storage and
use, hazardous decomposition products should not be produced.
Section 11. Toxicological information
Information on toxicological effects
Acute toxicity
Conclusion/Summary : Based on available data, the classification criteria
are not met.
Irritation/Corrosion
Conclusion/Summary
Skin : Non-irritant to skin.
Eyes : Non-irritating to the eyes.
Respiratory : Non-irritating to the respiratory system.
Sensitization
Conclusion/Summary
Skin : Not sensitizing
Respiratory : Not sensitizing
Mutagenicity
Conclusion/Summary : Based on available data, the classification criteria
are not met.
Carcinogenicity
Conclusion/Summary : Not classified or listed by IARC, NTP, OSHA, EU and
ACGIH.
Reproductive toxicity
Conclusion/Summary : Based on available data, the classification criteria are not met.
Teratogenicity
Conclusion/Summary : Based on available data, the classification criteria
are not met.
Specific target organ toxicity (single exposure)
Not available.
Specific target organ toxicity (repeated exposure)
Not available.
Aspiration hazard
Not available.
Information on the likely routes of exposure : Not available.
Potential acute health effects
Eye contact : No known significant effects or critical hazards.
Inhalation : No known significant effects or critical hazards.
Skin contact : No known significant effects or critical hazards.
Ingestion : No known significant effects or critical hazards.
Symptoms related to the physical, chemical and toxicological characteristics
Eye contact : Adverse symptoms may include the following: irritation
redness
Inhalation : Adverse symptoms may include the following: respiratory
tract irritation coughing
Skin contact : No specific data.
Ingestion : None known.
Delayed and immediate effects and also chronic effects from short and long term exposure
Short term exposure
Potential immediate effects : No known significant effects or critical
hazards.
Potential delayed effects : No known significant effects or critical
hazards.
Long term exposure
Potential immediate effects : No known significant effects or critical
hazards.
Potential delayed effects : No known significant effects or critical
hazards.
Potential chronic health effects
Conclusion/Summary : Based on available data, the classification criteria
are not met.
General : No known significant effects or critical hazards.
Carcinogenicity : No known significant effects or critical hazards.
Mutagenicity : No known significant effects or critical hazards.
Fertility effects : No known significant effects or critical hazards.
Numerical measures of toxicity
Acute toxicity estimates
Section 12. Ecological information
Toxicity
Conclusion/Summary : No known significant effects or critical hazards.
Persistence and degradability
Conclusion/Summary : No known significant effects or critical hazards.
Conclusion/Summary : No known significant effects or critical hazards.
Mobility in soil
Soil/water partition coefficient (KOC) : Not available.
Other adverse effects : No known significant effects or critical hazards.
Section 13. Disposal considerations
Disposal methods : The generation of waste should be avoided or minimized
wherever possible. Disposal of this product, solutions and any by-products
should at all times comply with the requirements of environmental protection
and waste disposal legislation and any regional local authority requirements.
Dispose of surplus and non-recyclable products via a licensed waste disposal
contractor. Waste should not be disposed of untreated to the sewer unless
fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be
considered when recycling is not feasible. This material and its container
must be disposed of in a safe way. Empty containers or liners may retain some
product residues. Do not puncture or incinerate container.
RCRA classification : D001 (Ignitable)
United States – RCRA Acute hazardous waste “P” List: Not listed
United States – RCRA Toxic hazardous waste “U” List: Not listed
Section 14. Transport information
Special precautions for user : Transport within user’s premises: always
transport in closed containers that are upright and secure. Ensure that
persons transporting the product know what to do in the event of an accident
or spillage.
Maritime transport in bulk according to IMO instruments
Section 15. Regulatory information
U.S. Federal regulations :
United States – TSCA 12(b) – Chemical export notification:
None of the components are listed.
United States – TSCA 4(a) – Final Test Rules: Not listed
United States – TSCA 4(a) – ITC Priority list: Not listed
United States – TSCA 4(a) – Proposed test rules: Not listed
United States – TSCA 4(f) – Priority risk review: Not listed
United States – TSCA 5(a)2 – Final significant new use rules: Not listed
United States – TSCA 5(a)2 – Proposed significant new use rules: Not
listed
United States – TSCA 5(e) – Substances consent order: Not listed
United States – TSCA 6 – Final risk management: Not listed
United States – TSCA 6 – Proposed risk management: Not listed
United States – TSCA 8(a) – Chemical risk rules: Not listed
United States – TSCA 8(a) – Dioxin/Furane precusor: Not listed
United States – TSCA 8(a) – Chemical Data Reporting (CDR): Not determined
United States – TSCA 8(a) – Preliminary assessment report (PAIR): Listed
United States – TSCA 8(c) – Significant adverse reaction (SAR): Not
listed
United States – TSCA 8(d) – Health and safety studies: Not listed
United States – EPA Clean water act (CWA) section 307 – Priority
pollutants: Not listed
United States – EPA Clean water act (CWA) section 311 – Hazardous
substances: Not listed
United States – EPA Clean air act (CAA) section 112 – Accidental release
prevention – Flammable substances: Listed
United States – EPA Clean air act (CAA) section 112 – Accidental release
prevention – Toxic substances: Not listed
United States – Department of commerce – Precursor chemical: Not listed
Clean Air Act Section 112(b) Hazardous Air Pollutants (HAPs) : Not listed
Clean Air Act Section 602 Class I Substances : Not listed
Clean Air Act Section 602 Class II Substances : Not listed
DEA List I Chemicals (Precursor Chemicals) : Not listed
DEA List II Chemicals (Essential Chemicals) : Not listed
SARA 302/304 : Not applicable
Composition/information on ingredients
SARA 304 RQ : 222.2 lbs
SARA 311/312
Classification : Fire hazard Sudden release of pressure
Composition/information on ingredients
State regulations Massachusetts : The following components are
listed: Dimethyl Ether Alcohol
New York : None of the components are listed.
New Jersey : The following components are listed: Dimethyl Ether Alcohol
Pennsylvania : The following components are listed: Dimethyl Ether Alcohol
US California 22CCR Appendix X Substances
Not Listed
United States inventory (TSCA 8b) : Not determined.
Canada inventory : Not determined.
International regulations
International lists : China inventory (IECSC): Not determined.
Korea inventory: Not determined.
New Zealand Inventory of Chemicals (NZIoC): Not determined.
Philippines inventory (PICCS): Not determined.
Taiwan Chemical Substances Inventory (TCSI): Not determined.
Chemical Weapons Convention
List Schedule I Chemicals
Chemical Weapons Convention: Not listed
List Schedule II Chemicals
Chemical Weapons Convention : Not listed
List Schedule III Chemicals
Section 16. Other information
History
Date of printing : 07.25.2023
Date of issue/Date of revision : 07.25.2023
Date of previous issue : 00.00.0000
Version : 1.0
Prepared by : Global Product Compliance
Unilever Regulatory Affairs
40 Merritt Blvd
Trumbull, CT 06611
USA
Key to abbreviations :
ATE = Acute Toxicity Estimate
ACGIH = American Conference of Governmental & Industrial Hygienists
AH = Acute Hazard
BCF = Bioconcentration Factor
CAA = Clean Air Act
CARB = California Air Resources Board
CCR = California Code of Regulations
CERCLA = Comprehensive Environmental Response, Compensation &
Liability Act
CFR = Code of Federal Regulations
CH = Chronic Hazard
CWA = Clean Water Act
DEA = Drug Enforcement Administration
DOT = Department of Transportation
EC = European Commission
EPCRA = Emergency Planning and Community Right‑To‑Know Act
EST = Eastern Standard Time
F = Fire
HAPS = Hazardous Air Pollutants
HCS = Hazard Communication Standard
HMIS = Hazardous Materials Information System
HVOC = High Volatile Organic Compound
GHS = Globally Harmonized System of Classification and Labelling of
Chemicals
IARC = International Agency for the Research of Cancer
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
ICAO = International Civil Aviation Organization
IMDG = International Maritime Dangerous Goods
IMO = International Maritime Organization
ITC = Interagency Testing Committee (TSCA)
KOC = Organic Carbon/Water Partition Constant
LogPow = logarithm of the octanol/water partition coefficient
LVOC = Low Volatile Organic Compound
MARPOL = International Convention for the Prevention of Pollution From
Ships, 1973 as modified by the Protocol of 1978. (“Marpol” = marine
pollution)
MPPCF = Million Particles Per Cubic Foot
N/A = Not Applicable
NFPA = National Fire Protection Association
NOEC = No Observable Effect Concentration
NTP = National Toxicology Program
OSHA = Occupation Safety & Health Administration
PEL = Permissible Exposure Limit
RCRA = Resource Conservation & Recovery Act
RQ = Reportable Quantity
RTK = Right-To-Know
SARA = Superfund Amendments & Reauthorization Act
STEL = Short-Term Exposure Limit
TBD = To Be Determined
TCC = Tagliabue Closed Cup
TCLP = Toxicity Characteristic Leaching Procedure
TDG = Transport of Dangerous Goods
TLV = Threshold Limit Value
TSCA = Toxic Substances Control Act
TWA = Time Weighted Average
UN = United Nations
References : Evaluation method used for mixture classification: Calculation method.
Notice to reader
To the best of our knowledge, the information contained herein is accurate.
However, neither the above- named supplier, nor any of its subsidiaries,
assumes any liability whatsoever for the accuracy or completeness of the
information contained herein. Final determination of suitability of any
material is the sole responsibility of the user. All materials may present
unknown hazards and should be used with caution. Although certain hazards are
described herein, we cannot guarantee that these are the only hazards that
exist.
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