MITSUBISHI ELECTRIC Coin Type Lithium Manganese Dioxide Battery Instructions

MITSUBISHI ELECTRIC HOME APPLIANCE

SAFETY DATA SHEET

The batteries are exempt articles and are not subject to the OSHA Hazard Communication Standard Requirement. This sheet is provided as technical information only.
The information and recommendations set forth are made in good faith and believed to be accurate as of the date of preparation. However, Mitsubishi makes no warranty expressed or Implied.

Section 1 —Product and Company Identification

Product Name:
Coin Type Lithium Manganese Dioxide Battery.
(Made in CHINA )| Size: ALL*| Effective Date From:
January 1,2022
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Company:
Mitsubishi Electric Home Appliance Co., Ltd.| Telephone Numbers: 81- (0)47-712-7500
Address (Number, Street, City, State, and ZIP Code):
3-12,Shiohama, Ichikawa-shi,Chiba,272-0127 Japan| Fax Numbers: 81- (0)47-307-6010

*: CRI216E,CR1220E,CR1620E,CR2016E,CR2025E,CR2032E,CR2032E+,CR2430E,CR2450E

Section 2 — Composition/Information on Ingredients

※ Heavy metal such as Mercury, Cadmium and Lead are not added in the battery.

Lithium content for each cell

Section 3 — Hazards Identification

This contains lithium, organic solvent, and other combustible materials. For this reason, Improper handling of the battery could lead to distortion, leakage, overheating, explosion of fire and cause human injury or equipment trouble. Please strictly observe safety instructions.
(Leakage is defined as an unintended escape of liquid from a battery.)

Section 4 — First Aid Measures

None unless internal materials exposure. If contents are leaked out, observe following Instructions.
Inhalation: Fumes can cause respiratory irritation. Remove to fresh air and consult a physician.
Skin: Immediately flush skin with plenty of water. If itch or irritation by chemical burn persists, consult a physician.
Eyes: Immediately flush eye with plenty of water for at least 15 minutes.
Consult a physician immediately
Ingestion: If swallowing a battery, consult a physician immediately. If contents come into mouth, immediately rinse by plenty of water and consult a physician.

Section 5 —Fire Fighting Measures

Extinguishing Media: Extinguisher of alkaline metal fire is effective.
Plenty of cold water is also effective to cool the surrounding area and control the spread fire. But hydrogen gas may be evolved by the reaction of water and lithium and it can form an explosive mixture.
Therefore in the case that lots of lithium batteries are burning in a confined space, use a smothering agent.
Fire fighting procedure: Use self-contained breathing apparatus and full protective gear not to inhale harmful gas.

Section 6 — Accidental Release Measures

Accidental Releases: Do not breathe vapors or touch liquid with bare hands (see section 4).
Waste Disposal Methods: Evacuate area. If possible, a trained person should attempt to stop or contain the leak by neutralizing spill with soda lime or baking soda. A NIOSH Approved Acid Gas Filter Mask or Self-Contained Breathing Apparatus should be worn. Seal leaking battery and soda lime or baking soda in a plastic bag and dispose of as hazardous waste.
Other: Follow North American Emergency Response Guide (NAERG) #138 for cells involved in an accident, cells that have vented, or have exploded.

Section 7—Handling and Storage

1. Handling
   Never swallow. Never reverse the positive and negative terminals when mounting.
   Never short-circuit the battery. Never heat. Never expose to open flame. Never disassemble.
   Never weld the terminal or wire to the body of the battery directly. Never touch the liquid leaked out of battery. Never bring fire close to battery liquid. Never keep in touch with battery.

2. Storage
   Never let the battery contact with water. Never store the battery in hot and high humid place.
   Don’t push the battery excessively and destroy the battery packaging, often wet and ventilating the dry place to keep in the normal atmospheric temperature, find the unusual battery is dealt with in time

Section 8 — Exposure Controls, Personal Protection

Section 9 — Physical/Chemical Characteristics

State of matter: Solid state
Form: Button type
Color: True quality of stainless steel
Smell: Tasteless (At the time of the fullness)
Resolve temperature: NA
Spontaneous combustion temperature: NA
Explosion demarcation line: Higher than 170 degrees Centigrade of batteries will be burnt
To the density (Water =1): NA
Dissolving: NA

odor.

Section 10 — Stability and Reactivity

Stability
Incompatibility
Hazardous polymerization
Condition to avoid Hazardous Decomposition or Byproducts| Stable
Water
Will not occur.
See section 7.
Hydrogen
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Section 11 — Toxicological Information

Acute Toxicity:
1, 2-Dimethoxyethane:
LC50 (Inhalation): N/A
LD50 : N/A
Eye Effects: Corrosive
Skin Effects: Corrosive

Section 12 —Ecological Information

Aquatic Toxicity: Do not let internal components enter marine environments. Avoid releases into waterways, wastewater or groundwater.

Section 13 — Disposal condition

The battery may be regulated by national or local regulation. Please follow the instructions of Proper regulation. ~ As electric capacity is left in a discarded battery and it comes into contact With other metals, it could lead to distortion, leakage, overheating, or explosion, so make sure to cover the (+) and (-) terminals with friction tape or some other insulator before disposal

Section 14 — Transportation Information

Lithium battery model ALL is complied with IATA Dangerous Goods Regulations 63rd Edition 0f 2022 & Section IB of Packing Instruction PT 968.
( ALL#:CRI1216E,CR1220E,CR1620E,CR2016E,CR2025E.CR2032E,CR2032E+,CR2430E,CR2450E )

Shipping Name (UN Number)| Lithium metal batteries (UN3090)
Lithium metal batteries packed with equipment (UN3091)
Lithium metal batteries contained in equipment (UN3091)
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Hazard Classification| Class 9 (Miscellaneous)

Organizations governing the transport of lithium batteries

These regulations are based on the UN Recommendations. Each special provision provides specifications on exceptions and packaging for shipping lithium batteries. All the Lithium metal cells of Mitsubishi comply in all respects can be shipped in accordance with [ATA Dangerous Goods Regulations 63rd Edition & Section IB of Packing Instruction PI 968 If all of following 3 requirements are satisfied, lithium metal batteries can be transported as “Dangerous Goods” cargo.

1. Lithium weight or equivalent lithium content must be less than value in table.
   Contents| Lithium metal cells and/or batteries with a lithium content not more than 0.3 g| Lithium metal cells and/or batteries with a lithium content greater than 0.3 g but not more than 1 g| Lithium metal cells and/or batteries with a lithium content greater than 1 g but not more than 2 g
   ---|---|---|---
   Maximum number of
   cells / batteries per
   package| No limit| 8 pieces per carton| 2 pieces per carton
   Maximum net  quantity (mass) per package| 2.5 Kg| N/A| N/A

Equivalent lithium content (g) is calculated as 0.3 (g/Ah) times the rated capacity (Ah).

2. Each cell or battery is of the type proven to meet the requirements of each test in the UN Manual of Tests and Criteria, Part V, section 38.3 Cells
3. Section IB of Packing Instruction PI 968:
   a) Be marked to indicate that it contains lithium metal cells & batteries, and that special procedures be followed in the event that the package is damaged.
   b) Each package must be labeled with a lithium battery handling label.
   c) Be accompanied by a shipping paper explaining that the cells and batteries are excepted from regulations.
   d) Packaging requirement following to above 1) Lithium weight or equivalent lithium content must be less than value in table.
   e) Be capable of withstanding a 1.2m drop test in any orientation without shifting of the contents that would allow short-circuiting, and without release of package contents.

Because the consignor has to take the responsibility, the customer has to confirm the exception conditions when shipping.

Section 15— Regulatory Information

EC Labeling : None
Risk Phrases :None
Safety Phrases : None
Labeling is not required because batteries are classified as “articles” under the Dangerous Preparations Directive and as such are exempt from the requirements of the Directive.

Section 16 — Other Information

If you want further information, please contact Mitsubishi sales representative.

MITSUBISHI ELECTRIC HOME APPLIANCE

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