GREISINGER GE xxx Penetration pH Electrodes Instruction Manual

GREISINGER GE xxx Penetration pH Electrodes

General Note

Read this document carefully and get used to the operation of the product before you use it. Keep this document within easy reach near the product for consulting in case of doubt.

Safety

Intended Use

• The pH electrodes must be used only according to their intended purpose and under suitable conditions.
• The electrodes must be operated with suitable measuring devices and be calibrated before first use and afterward in regular intervals.
• The safety requirements (see below) have to be observed.
• The lifetime and accuracy of the electrodes depend on adequate selection as well as on proper handling.
• Please consider therefore the chapters “Choose the right electrode”, “Measuring and storing” and “Maintenance”.
• Use the device carefully and according to its technical data (do not throw it, strike it, etc.). Protect the device from dirt.
• To be sure that there´s no risk arising due to misinterpretation of measured values, the operator must have further knowledge in case of doubt – the user is liable for any harm/damage resulting from misinterpretation due to insufficient knowledge.
• The manufacturer will assume no liability or warranty in case of usage for other purpose than the intended one, ignoring this manual, operating by unqualified staff as well as unauthorized modifications to the device.

Safety guidelines

• This device has been designed and tested in accordance with the safety regulations for electronic devices.
• However, its trouble-free operation and reliability cannot be guaranteed unless the standard safety measures and special safety advises given in this manual will be adhered to when using the device.

Safety signs and symbols

The following signs in this document highlight warnings:

• Caution! This symbol warns of imminent danger, death, serious injuries and significant damage to property at non-observance.
• This symbol indicates danger for living tissue as well as a variety of materials, which can be damaged or destroyed when coming into contact with this chemical. The caustic effect, protective equipment required!
• This Symbol indicates dangers to all living beings that may result in death or acute or chronic health hazards when inhaled, swallowed, or absorbed through the skin of this chemical.
• This Symbol indicates irritant substances that can cause inflammation on short-term, prolonged or repeated contact with the skin or mucous membranes.
• Attention! This symbol warns of possible dangers or dangerous situations that can provoke damage to the device or environment at non-observance.
• Note! This symbol point out processes which can indirectly influence operation, possibly cause incorrect measurement or provoke unforeseen reactions at non-observance.
• This symbol instructs the use of eye protection which protects the eyes from harmful influences when working with powerful light, UV radiation, laser, chemicals, dust, splinters or weather influences.
• This symbol instructs the use of protective gloves which offer protection from mechanical, thermal, chemical, biological or electrical hazards.

Foreseeable misuse
The fault-free function and operational safety of the product can only be guaranteed if generally applicable safety precautions and the device-specific safety instructions for this document are observed. If these notices are disregarded, personal injury or death, as well as property damage can occur.

• This device must not at all be used in a potentially explosive environment! The usage of this device in potentially explosive areas increases the danger of deflagration, explosion, or fire due to sparking.
• This device is not suitable for medical applications.
• The device is not suitable for direct contact with food products. Take samples and dispose of them correctly after the measurement.

Safety instructions

This device has been designed and tested in accordance with the safety regulations for electronic devices. However, its trouble-free operation and reliability cannot be guaranteed unless the standard safety measures and special safety advice given in this manual will be adhered to when using the device.

The electrodes contain 3 molar KCL (GE103: 1mol/l KNO3), which is acidic.

First-Aid-provisions:

• Contact with eyes: rinse the opened eye with sufficient water, contact the oculist
• Contact with skin: clean with sufficient water
• Swallowing: drink a lot of water. If feeling sick, contact doctor

The electrodes contain glass parts that can cause injuries when broken. There is an elevated risk of injury in conjunction with measurements in food.

• Inspect the electrode before and after measurement!
• Always measures in samples for measurements in foods. Discard these samples after the measurement!

If there is a risk whatsoever involved in running it, the device has to be switched off immediately and to be marked accordingly to avoid restarting. Operator safety may be a risk if:

• there is visible damage to the device
• the device is not working as specified
• the device has been stored under unsuitable conditions for a longer time.

In case of doubt, please return the device to the manufacturer for repair or maintenance.

Do not use this product as a safety or emergency stop device or in any other application where failure of the product could result in personal injury or material damage. Failure to comply with these instructions could result in death or serious injury and material damage

When interacting with chemicals at least the following points must be ensured:

1. Obey all notes on the container of chemicals.
2. Obey all notes in the safety specification sheet of chemicals.
3. Consider any statutory provisions guidelines and guidelines of chemicals when disposing! This is also for accidentally spilled chemicals, dried residues, soiled rags or similar.
4. Always wear suitable protective clothing (e.g. protection goggles, safety gloves, face mask, etc.)!
5. Never eat, drink or smoke in the operational area of chemicals!
6. In case of problems instantly consult skilled personnel.

Suitable clean-up possibilities (eye wash, etc.) must exist within spitting distance!

• Trouble-free operation and reliability of the device can only be guaranteed if the device is not subjected to any other climatic conditions than those stated under the specification.

Basics

pH measurement
The pH value describes the acidic or alkaline behavior of an aqueous solution. pH values below 7 are acidic (smaller values indicate higher acidity), and values above 7 are alkaline; pH 7 = neutral. The pH measurement is very precise but also sensitive. The measured signals are very weak (high ohmic), especially when measured in weak or low-ion media. Therefore, always take measures to determine the pH value of a solution, it should always be recorded together with the measuring temperature, the reason is that most liquids change their pH value with the temperature.

• avoid interference (electrostatic charges, etc.)
• keep plug contacts clean and dry
• prevent electrodes (except special waterproof versions) from extended immersion above the shaft
• calibrate the electrode at sufficient intervals (see below). The frequency of calibration can range from every hour to several weeks, depending on the electrode and the application.
• use a suitable electrode.

Design of electrode
In most cases, so-called combination electrodes are used. That means that all needed elements are integrated into a single electrode (including the reference electrode). Sometimes even a temperature sensor is integrated. (The picture shows an electrode without a temperature sensor)

1. Coaxial cable
2. Reference electrode
3. Measuring electrode
4. Refill opening
5. Electrolyte
6. Internal buffer
7. Diaphragm
8. Glass membrane / source layer

The diaphragm, which establishes a connection between the electrolyte and the liquid to be measured, can be designed in different ways. Clogging or soiling of the diaphragm is a frequent cause of a malfunctioning or sluggish electrode. Always handle the glass membrane with extreme care. The so-called source layer forms there. This is crucial for the measurement and must always be kept moist.

Further information

A pH electrode is a wear part. If the signal is very slow or the required values are no longer observed after careful cleaning and possible regeneration, the electrode must be replaced. When using the electrodes, be aware that various substances in aqueous solutions can corrode glass and that chemicals can produce a chemical reaction with the KCl solution in the electrode, which can result in blockage of the diaphragm.

Examples:

• In solutions that contain proteins, such as for measurements in medical and biological applications, KCl can cause denaturation of the protein.
• Coagulated paints
• Solutions that contain high concentrations of silver ions

Substances that accumulate on the glass membrane or the diaphragm affect the measurement and must be removed regularly. This can be achieved for example with automatic cleaning systems.

Service life

• The service life of electrodes is normally at least 8 to 10 months.
• When cared for properly, this can usually increase to more than 2 years.
• The actual life will vary depending on the particular application.
• Extreme pH values and high temperatures accelerate the aging process.

Operating and Maintenance

Measuring and storing
The pH-electrodes have been tested and have been subordinated to strict quality controls in all manufacturing steps To keep the optimum efficiency and accuracy for a long time take care of the following points:

• Remove the storing protection cap and rinse the shaft and pH-glass-diaphragm with distilled water.
• Important! The pH-glass-diaphragm has to be kept wet. When not in use the electrode must be stored in 3 mol/l KCl solution. (GE 103 in 1 mol/l KNO3). If the pH-glass-diaphragm dried out, the performance and the responsiveness are affected. To re-moisten the electrode store it in 3 mol/l KCl solution for 24 hours (GE 103 1 mol/l KNO3). Longer storage of a combination electrode or a reference electrode in distilled water will deplete them of KCl. Please refill KCl-electrolyte (saturated or 3 mol) in time
• Do not touch the glass diaphragm! Damages on the surface and attrition affect the performance negatively and might even destroy the electrode.
• Before usage perform a visual check of the pH-electrode. If there are air bubbles in the pH-glass-diaphragm or the outer reference electrode you can get them out by shaking the electrode downward.
• For electrodes with liquid electrolytes: For continuous flow of electrolyte the cap sleeve made of rubber, that covers the refill opening, has to be removed before measurements. The opening has to be closed for storage in order to prevent running down.
• The level of the electrolyte should be over the level of the measured medium. This ensures stable measuring values and reduces pollution of the diaphragm and reference electrolyte.
• Take care that the diaphragm fully contacts the media you want to measure. Minimum depth for e.g. GE 100 20 mm, maximum 80 mm
• Keep the cable and plug of the electrode always clean and dry. Otherwise, the electric insulation will be lost and consequently measuring errors or other subsequent errors might occur.
• The calibration (adjustment) of the measurement chain (single rod or measurement and reference electrode) has to be performed according to the device manufacturer. The “asymmetry” is adjusted with the help of a buffer solution with a value at the chain’s zero point (e.g. pH 7.0). The “slope” is adjusted with the help of a second buffer solution, whose pH value should match the expected measuring range (e.g. pH 4.0; pH 10.0; pH 12.0), but at least 2 pH units different from the first value.
• The electrode has to be stored in dry rooms at temperatures between 10°C to 30°C. Below –5°C the electrode might be damaged because of freezing of the electrolyte. We recommend storing the electrode vertically with the cable to the upper side.
• The pH-electrode should be arranged vertically upwards with the connecting cable. A slight angle of inclination does not impair the measurement

Calibration
The electrodes have to be calibrated (adjusted) in regular intervals. The length of the intervals depends on the accuracy requirements, the application, and the electrode. If asymmetry or slope cannot be adjusted any longer, it’s a sign that

• a) the electrode is exhausted and has to be exchanged,
• b) the electrode is polluted and has to be cleansed (see below), or
• c) the buffer solution is exhausted (prepare new solution). A prepared buffer solution has a limited lifetime (about 1 month) when using/calibrating it thoroughly (no procrastination of buffer solution residua from one solution to another one through cleaning and drying the electrode not enough)

Buffer capsules have no lifetime limitations, we recommend keeping a sufficient number of them in stock. pH 12 buffer capsules (white) have to be stored in an exsiccator or stored together with a drying agent. As an alternative to the buffer capsules, the PHL buffer solutions are available. They are stored in practical 250 ml dosage bottles and are ready to use (keep the best-before-the-buffer solutions in mind). The electrolyte (mostly 3 mol/l KCl) should be always available for refilling, too. (e.g. contained in working and calibration set GAK 1400).

Care and maintenance

• For electrodes with liquid electrolyte: Check the level of reference electrolyte and, if necessary, refill 3 mol/l KCl solution with the help of a syringe or pipette.
• Normal cleaning takes place with the GRL 100 pepsin cleaning solution into which the electrode is immersed for 5 – 10 minutes before being rinsed off with clean water. Crystallization of the 3 mol/l KCL solution is unavoidable. Crystallized potassium chloride on the protective cap and shaft can easily be removed with a fingernail or cloth and is therefore not a defect or grounds for complaint.
• Dirty electrodes must be cleaned. The suitable cleaning agents for the pH glass membrane are listed in the table below.
• Mechanical cleansing should be avoided as this might damage the electrode permanently. Therefore a chemical cleansing is preferable.

solution
Biological coatings with protein| Acetone
Extremely resistant residues| Hydrogen peroxide or sodium hypochlorite

The material of the pH probe must always be protected. Plastic shafts must not be cleaned in solvents, etc. If in doubt, contact the manufacturer to inquire about suitable cleaners for the existing electrode. This is also important in the case of aggressive substances or other substances that are not primarily water-based! The GAK 1400 working and calibration set includes all necessary products for calibration, care and maintenance of the electrode.

Choose the right electrode

| GE 014| GE 100| GE 101| GE 103| GE 104| GE 106| GE 107| GE 108| GE 109| GE 114| GE 117| GE 120| GE 125| GE 126| GE 135| GE 151| GE 170| GE 171| GE 173
---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---
Sewage| | | | | | | | | | | | | | X| | | | | X
Aquarium water| X| X| | | X| X| X| X| X| X| X| | | X| | X| | | X
Soil testings| | | X| | | | | | | | | | | | | | | |
Emulsions| | | X| | X| | | | | | | | | | | | | | X
On-site measurements| | | | | | | X| X| X| X| X| | X| | X| | | |
Fish farming| X| X| | | X| X| X| X| X| X| X| | X| X| X| X| | |
Photo laboratory| | | | X| | | | | | | | | | | | | | |
Galvanic baths| | | | X| | | | | | | | | | | | X| | | X
Beverages| | | | | | | | | | | | | X| | X| X| | | X
Low-ion media
(Rainwater, some aquariums, VE water)| | | | | ****

X

| ****

X

| | | | | | | | | | | | | ****

X

Cosmetics| | | | | X| | | | | | | | | | | | | |
Food sample| | | X| | | | | | | | | X| | | | | | |
Sea water| X| X| X| X| | X| X| X| X| X| X| | X| X| X| X| X| X| X
Process chemistry| | | | | | | | | | | | | | | | X| X| X| X
Online measurements| | | | | | | | | | | | | | | | | X| X| X
Swimming pool water| X| X| | | | X| | X| | X| X| | X| X| X| X| | | X
Suspensions| | | X| | X| | | | | | | | | | | | | | X
Drinking water| X| X| | | X| X| | X| | X| X| | X| X| X| X| | X| X
Water-based lacquers| | | | | X| | | | | | | | | | | | | | X

For most applications, the GE 114 or the GE 100 can be used. Some different applications require a special electrode.

• GE 100 is a universal electrode with two ceramic diaphragms and liquid.
• GE 101 is preferably used for small sample amounts. It comprises a glass electrode with two ceramic diaphragms and a liquid electrolyte.
• GE 104 is preferably used for measurements in low-ionic media, such as rainwater, aquarium water, and deionized water.
• GE 114 is a universally applicable, durable, and low-maintenance gel electrode with a Pellon diaphragm. It can be used for measurements in drinking water, swimming pools, aquaria, and slightly contaminated wastewater.
• GE 117 is a temperature-compensated gel electrode with two ceramic diaphragms and PH 13.5 cable screw coupling.
• GE 120 is an insertion electrode and is preferably used for measurements in cheese, fruit, and meat. For measurements in products containing proteins, the electrode must be cleaned with a special cleaner. For this purpose, we recommend the GRL 100 pepsin cleaning solution.
• GE 125 is a waterproof, universally applicable, durable, and low-maintenance gel electrode with a ceramic diaphragm. It can be immersed above the shaft for an extended time.
• GE 126 is an extremely low-maintenance and long-term stable gel electrode with a ceramic diaphragm.
• GE 135 is a waterproof, universally applicable, durable, and low-maintenance gel electrode with a ceramic diaphragm. It can be immersed above the shaft for an extended time.
• GE 151 is a glass electrode and is preferably used in galvanic applications for paints and lacquers.
• GE 173 is an alkaline-resistant glass electrode with a ground diaphragm and gel electrolyte for chemical and wastewater applications.

Reshipment and disposal

Reshipment

• All devices returned to the manufacturer have to be free of any residual measuring media and other hazardous substances. Measuring residuals at housing or sensor may be a risk for persons or the environment
• Use an adequate transport package for reshipment, especially for fully functional devices. Please make sure that the device is protected in the package by enough packing materials.
• Add the completed reshipment form to the GHM website.

Disposal
The device must not be disposed of with household waste. Return it to us, freight prepaid. We will then arrange for the proper and environmentally friendly disposal. Private end users in Germany have the possibility of dropping off the product at the municipal collection center.

Manufacturer/distributor

• GHM GROUP – Greisinger
• GHM Messtechnik GmbH
• Hans-Sachs-Str. 26
• 93128 Regenstauf
• Germany
• +49 9402 9383-0
• info@greisinger.de.
• www.greisinger.de.
• WEEE-Reg.-Nr.: DE 93889386
• https://manual-hub.com/.

Specification

Type| Description| Operating range| Pressure| Reference electrolyte| Connection| Cable| Notes| Diaphragm type

/Membrane shape

| Tube
---|---|---|---|---|---|---|---|---|---
__**GE 014-Cinch** … )| low Cost pH-electrode| pH 2-12, 0..60°C

200 µS/cm

| pressureless| 3mol/l KCl| Cinch| 1 m| | 2x ceramic/sphere| plastic approx. Ø12×110 mm
GE 014-BNC … )| BNC
__**GE 100-Cinch**| standard pH-electrode| pH 0-14, 0..80°C

100 µS/cm

| pressureless| 3mol/l KCl| Cinch| 1 m| | 2x ceramic/sphere| tyril approx. Ø12×120 mm
GE 100-BNC| BNC-
__**GE 101-Cinch**| injection pH-electrode| pH 2-11, 0..60°C

100 µS/cm

| pressureless| 3mol/l KCl| Cinch| 1 m| | 2x ceramic/cone| glass approx. Ø12×120 mm
GE 101-BNC| BNC
__**GE 103-Cinch** … )| double chamber pH-electrode| pH 0-14, 0..80°C

200 µS/cm

| pressureless| 3mol/l KCl 1mol/l KNO3| Cinch| 1 m| | 2x ceramic/sphere| plastic approx. Ø12×120 mm
GE 103-BNC … )| BNC
__**GE 104-Cinch**| special grinding pH-electrode| pH 2-14, 0..80°C

20 µS/cm

| pressureless| 3mol/l KCl| Cinch| 1 m| moveable joint, easy-to-clean| grinding / cylinder| glass approx. Ø12×120 mm
GE 104-BNC| BNC
__**GE 106-Cinch**| pH-electrode for VE water| pH 0-14, 0..80°C

100 µS/cm

| pressureless| 3mol/l KCl| Cinch| 1 m| | 3x ceramic/sphere| Cyril approx. Ø12×120 mm
GE 106-BNC| BNC
__**GE 108-Cinch**| standard pH-electrode, pressure resistant| pH 0-14, 0..80°C

100 µS/cm

|

max 6 bar

| 3mol/l KCl (gel)| Cinch| 2 m| pressure resistant up to 6 bar with PG13.5 thread| 2x ceramic/cylinder|

PSU approx. Ø12×120 mm

__**GE 108-BNC| BNC| 2 m
GE 108-S7*| S7 connection| – )
GE 109-BNC| pH-electrode with int. Pt100 sensor| pH 0-14, 0..60°C

100 µS/cm

| max 6 bar| 3mol/l KCl (gel)| BNC und MiniDIN| 2 m| pressure resistant up to 6 bar| 2x ceramic/cylinder| PSU approx. Ø12×120 mm
GE 114-BNC| low-cost pH-electrode| pH 0-14, 0..60°C

200 µS/cm

| pressureless| 3mol/l KCl (gel)| BNC| 1 m| | 1x Pellon / sphere| epoxy approx. Ø12×120 mm
GE 117-BNC| pH-electrode with int. Pt1000 sensor| pH 0-14, 0..60°C

100 µS/cm

| max 6 bar| 3mol/l KCl (gel)| BNC and 4mm banana| 2 m| pressure resistant up to 6 bar with PG13.5 thread| 2x ceramic/cylinder| PSU approx. Ø12×120 mm
__**GE 120-Cinch**| injection pH-electrode| pH 0-14, 0..60°C

200 µS/cm

| pressureless| Ag/AgCl (gel)| Cinch| 1 m| incl. screwable cutting blade| 2x ceramic/cone| PVC approx. Ø22×110 mm injection tip approx. Ø13×60
GE 120-BNC| BNC
GE 125-BNC| pH-electrode with int. Pt1000 sensor| pH 0-14, 0..70°C

200 µS/cm

| pressureless| 3mol/l KCl (gel)| BNC and 4mm banana| 2 m| water-proof IP 67 incl. BNC plug| 1x ceramic / cylinder| epoxy approx. Ø12×120 mm
GE 126-BNC| extremely low- maintenance pH-electrode| pH 0-14, 0..80°C

100 µS/cm

| max 5.5 bar| Ag/AgCl (Gel)| BNC| 5 m| with ½“ NPT thread| 2x ceramic/sphere| ABS approx. Ø26.4×147 mm
GE 135-BNC| pH-electrode with int. Pt1000 sensor| pH 0-14, 0..80°C

150 µS/cm

| max 5 bar| Ag/AgCl (Gel)| BNC and 4mm banana| 1 m| water-proof IP 67 incl. BNC plug| 1x ceramic / cone| PC approx. Ø12×130 mm
__**GE 151-Cinch**| pH-electrode for difficult measurement conditions| pH 0-14, 0..80°C

100 µS/cm

| pressureless| 3mol/l KCl| Cinch| 1 m| chemically resistant glass tube| 1x ceramic / cylinder| glass approx.Ø12×120 mm
GE 151-BNC| BNC
GE 170-S7 )| pH-electrode for extreme conditions| pH 0-14, 0..130°C

100 µS/cm

| max 15 bar @ 25°C| 3mol/l KCl (gel)| S7 connection| – *)| up to 130°C / 15 bar with PG13.5 thread| 3x ceramic/sphere| glass approx. Ø12×120 mm
GE 171-S7| pH-electrode for extreme conditions| pH 0-14, 0..140°C

100 µS/cm

|

max 10 bar

| 3mol/l KCl (gel)|

S7 connection

|

– *)

| can be sterilized and autoclaved

with PG13.5 thread

| 2x ceramic/sphere| glass approx. Ø12×120 mm
__**GE 173-Cinch**| special grinding pH-electrode| pH 0-14, 0..80°C > 50 µS/cm| max 6 bar| 3mol/l KCl (gel)| Cinch| 2 m| alkali resistant, pressure- resistant up to

6 bar with PG13.5 thread

| grinding / cylinder| glass approx. Ø12×120 mm
__**GE 173-BNC| BNC
GE 173-S7*| S7 connection| – )

no longer available
Note: cable GEAK-2S7-BNC or GEAK-5S7-BNC is needed for connection S7 (additional adapter GAD 1 BNC is required for measurement devices with cinch plug)

References

• Senseca Germany GmbH - Business Unit Portable

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