EnerSys 7439-92-1 Motive Power Lead Acid Battery Instructions

EnerSys 7439-92-1 Motive Power Lead Acid Battery

INTRODUCTION

Batteries are considered as articles under REACH regulation 1907/2006/EC and, as such, do not require the publication of a safety data sheet. However, there is a requirement to provide safety information on products. This document, which fulfils this requirement, is commonly called an SDS, but, in Europe, is more correctly referred to as ‘Information for the Safe Handling of Lead-Acid Batteries’. This leaflet was prepared by the Committee of Environmental Affairs of EUROBAT (May 2003), reviewed by EUROBAT TC members (September 2003) and CEM (October – November 2003). Revision: July 2021.

Identification of Product and Company

• Product: Motive Power Lead Acid Battery
• Trade name: EnerSys, Hawker, Ironclad, NexSys, Fiamm Motive Power, Energia, Oerlikon, Oldham
• Manufacturer: EH Europe GmbH
• Address: Baarerstrasse 18, 6300 Zug, Switzerland
• Phone: Emergency tel. no. +1 703 527 3887

Hazards Identification

No hazards occur during the normal operation of a Lead Acid Battery as it is described in the INFORMATION FOR USE that is provided with the Battery. However, Lead-Acid Batteries have three significant characteristics:

• They contain an electrolyte which contains diluted sulphuric acid. Sulphuric acid may cause severe chemical burns.
• During the charging process or during operation they might develop hydrogen gas and oxygen, which under certain circumstances may result in an explosive mixture.
•  They can contain a considerable amount of energy, which may be a source of high electrical current and a severe electrical shock in the event of a short circuit.
  The Batteries have to be marked with the symbols listed under section 15.

Composition and Information on the main Ingredients

CAS no.| Index Numbers| Description| Content 1)

[% of weight]

| Hazards Category and Statement Code, GHS pictograms
---|---|---|---|---
7439-92-1| 082-014-00- 7| Lead Grid

(Lead massive*, lead alloys)

| ~ 32|
 |  |  |  | Repr. 1A – H360FD
 |  |  |  | Lact– H362
 |  |  |  | STOT RE 1 – H372
7439-92-1| 082-001-00- 6| Active Mass

(Lead dioxide, inorganic lead compounds, with possible traces of additives)

| ~ 32| Repr. 1A – H360Df
 |  |  |  | Acute Tox. 4 – H332. Acute Tox. 4 – H302
 |  |  |  | STOT RE 1 – H372
 |  |  |  | Lact – H362
 |  |  |  | Carc.2 – H351
 |  |  |  | Aquatic Acute 1 – H400, Aquatic Chronic 1 H410
7664-93-9| 016-020-00- 8| Electrolyte 2) (diluted sulphuric acid with additives)| ~ 29|
 |  |  |  | SkinCorr.1A – H 314
 |  | Plastic Container / Plastic Parts 3)| ~ 7|

1. Contents may vary due to performance data and/or application of the Battery
2. Density of the electrolyte varies in accordance to the state of charge
3. Composition of the plastic may vary due to different customer requirements

First Aid measures

This information is of relevance only if the Battery is broken and this results in a direct contact with the ingredients.

General

• Electrolyte (diluted sulphuric acid): sulphuric acid acts corrosively and damages skin
• Lead compounds: lead compounds are classified as toxic for reproduction

Electrolyte (Sulphuric acid)

• After skin contact: rinse with water, remove and wash wet clothing
• After inhalation of acid mist: inhale fresh air, seek advice of a medical doctor
• After contact with the eyes: rinse under running water for several minutes, seek advice of a medical doctor
• After swallowing: drink a lot of water immediately, swallow activated carbon, do not induce vomiting, seek advice of a medical doctor

Lead compounds

• After skin contact: clean with water and soap
• After inhalation: inhale fresh air, seek advice of a medical doctor
• After contact with the eyes: rinse under running water for several minutes, seek advice of a medical doctor
• After swallowing: wash mouth with water, seek advice of a medical doctor

Fire fighting measures

Suitable fire extinguishing agents:
CO2, dry powder extinguishing agents or Water
Unsuitable fire extinguishing agents:
Water, if the battery voltage is above 120 V
Special protective equipment:
Protective goggles, respiratory protective equipment, acid protective equipment, and acid-proof clothing in case of larger stationary battery plants or where larger quantities are stored.

Measures to be taken in case of accidental release

This information is of relevance only if the battery is broken and the ingredients are released. In the case of spillage, use a bonding agent, such as sand, to absorb spilt acid; use lime/sodium carbonate for neutralisation; dispose of with due regard to the official local regulations; do not allow penetration into the sewage system, into earth or water bodies.

Handling and Storage
Store under a roof in cool ambiance – charged lead-acid batteries do not freeze up to -50°C; prevent short circuits. Seek agreement with local water authorities in case of larger quantities of batteries to be stored. If batteries have to be stored, it is imperative that the instructions for use are observed.

Exposure limits and personal protective equipment
Lead and Lead compounds
No exposure to lead and lead compounds during normal conditions of use.

Electrolyte (Sulphuric Acid)
Exposure to sulphuric acid and acid mist might occur during filling and charging.

• Threshold value in workplace: occupational exposure limits for sulphuric acid mist are regulated on a national basis.

• Hazard corrosive
  Personal protective equipment: Protective goggles, rubber or PVC gloves, acid- resistant clothing, safety boots.

• CAS-No: 7664-93-9

• Hazard statements: H314 Causes severe burns and eye damage.

• Precautionary Statements:

  • P102 Keep out of reach of children.
  • P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking

• P305+P351+315 IF in eyes. Rinse cautiously with water for several minutes. Get immediate medical advice/attention.

• P309+315 IF exposed or if you feel unwell. Get immediate medical advice/attention.

Physical and Chemical properties

| Lead and Lead compounds| Electrolyte (diluted sulphuric acid, 30 to 38.5%)
---|---|---
Appearance| **** solid grey

odourless

| **** liquid colourless

odourless

form : colour :

odour :

Safety-related data| **** 327°C

1740°C

very low (0.15 mg/l) 11.35g/cm³

N.A.

| **** -35 to -60°C

approx. 108 to 114°C complete

1.2 to 1.3g/cm³

N.A.

solidification point :

boiling point : solubility in water : density (20°C) :

vapour pressure (20°C) :

Lead and Lead compounds used in Lead-Acid batteries are poorly soluble in water, Lead can be dissolved in an acidic or alkaline environment only.

Stability and Reactivity (sulphuric acid, 30 – 38.5 %)

• Corrosive, non-flammable liquid
• Thermal decomposition at 338° C.
• Destroys organic materials such as cardboard, wood, textiles.
• Reacts with metals, producing hydrogen
• Vigorous reactions on contact with sodium hydroxide and alkalis.

Toxicological Information
This information does not apply to the finished product “Lead-Acid Battery”. This information only applies to its compounds in case of a broken product. Different exposure limits exist on a national level.

Electrolyte (diluted sulphuric acid):
Sulphuric Acid is intensely corrosive to skin and mucous membranes; the inhalation of mists may cause damage to the respiratory tract.
Acute toxicity data:

• LD50 (oral, rat) = 2140 mg/kg
• LC50 (inhalation, rat) = 510 mg/m³/2h

Lead and Lead compounds
Lead and its compounds used in a Lead Acid Battery may cause damage to the blood, nerves and kidneys when ingested. The lead contained in the active material is classified as toxic for reproduction.

Ecological Information
This information is of relevance if the battery is broken and the ingredients are released to the environment.

Electrolyte (diluted sulphuric acid)
In order to avoid damage to the sewage system, the acid has to be neutralised by means of lime or sodium carbonate before disposal. Ecological damage is possible by change of pH. The electrolyte solution reacts with water and organic substances, causing damage to flora and fauna. The electrolyte may also contain soluble components of lead that can be toxic to aquatic environments

Lead and Lead compounds
Chemical and physical treatment is required for the elimination from water. Waste water containing lead must not be disposed of in an untreated condition.
Lead metal grids are not classified as eco-toxic.

Disposal Considerations

Spent lead-acid batteries (EWC 160601) are subject to regulation of the EU Battery Directive and its adoptions into national legislation on the composition and end-of-life management of batteries. Spent Lead-Acid batteries are recycled in lead refineries (secondary lead smelters). The components of a spent Lead-Acid Battery are recycled or re-processed.
At the points of sale, the manufacturers and importers of batteries, respectively the metal dealers take back spent batteries, and render them to the secondary lead smelters for processing. To simplify the collection and recycling or re-processing procedure, spent Lead-Acid Batteries must not be mixed with other batteries. By no means may the electrolyte (diluted sulphuric acid) be emptied in an inexpert manner. This process is to be carried out by the processing companies only. 200133 EWC may be used for municipal collected batteries.

Transport Regulation

Flooded Lead-Acid Batteries:
Transport Regulations, other than listed below, are based on UN Recommendations on the Transport of Dangerous Goods – Model Regulations as well. Nevertheless, every time all Special Provisions are considered to ensure and check when material is shipped to non-European regions (e.g. USA, APAC or Africa etc.).

Road and Railway Transport (ADR/RID)| – UN Number: 2794

– Proper Shipping Name: BATTERIES, WET, FILLED WITH ACID

– Class: 8,

– Hazard label: 8

– Packing Group: not assigned

– Special provisions: 295, 598

–  Packing instructions (P) and Packing Provision (PP), if any: P801 (only for new batteries)

– Tunnel codes (ADR only): (E)

NOTE:

295 Batteries need not be individually marked and labelled if the pallet bears the appropriate mark and label.

598 The following are not subject to the requirements of ADR/RID:

(a) New storage batteries when:

– they are secured in such a way that they cannot slip, fall or be damaged;

– they are provided with carrying devices, unless they are suitably stacked, e.g. on pallets;

– there are no dangerous traces of alkalis or acids on the outside;

– they are protected against short circuits;

(b) Used storage batteries carried for recycling at the end of their normal service life when:

–  their cases are undamaged;

–  they are secured in such a way that they cannot leak, slip, fall or be damaged, e.g. by stacking on pallets;

–  there are no dangerous traces of alkalis or acids on the outside of the articles;

–  they are protected against short circuits.

---|---
Sea Transport (IMDG Code)| – UN Number: 2794

– Proper Shipping Name: BATTERIES, WET, FILLED WITH ACID

– Class: 8,

– Hazard label: 8

– Packing Group: not assigned

– Special provision: 295,

– Packing instruction: P801

– Emergency Schedule (EmS): F-A, S-B

NOTE:

295 Batteries need not be individually marked and labelled if the pallet bears the appropriate mark and label.

Air Transport (IATA DGR)| – UN Number: 2794

– Proper Shipping Name: BATTERIES, WET, FILLED WITH ACID

– Class: 8,

– Hazard label: corrosives (figure 7.3.V)

– Packing Group: not assigned

– Special provisions: A51, A164, A183, A802

– Packing instruction on passenger aircraft: 870

– Packing instruction on Cargo Aircraft Only: 870

NOTE:

A51 Aircraft batteries classified to UN2794 up to a limit of 100 kg net weight per package may be transported. Transport in accordance with this Special Provision must be noted on the Shipper’s Declaration for Dangerous Goods. Therefore, Shipper’s Declaration for Dangerous Goods must then include the text : “ Battery is considered to be Aircraft Battery in accordance with Special Provision number A51 ” or its equivalent.

A164 Any electrical battery or battery powered device, equipment or vehicle having the potential of a dangerous evolution of heat must be prepared for transport so as to prevent:

(a) a short circuit (e.g. in the case of batteries by the effective insulation of exposed terminals; or in the case of equipment, by disconnection of the battery and protection of exposed terminals); and

(b) unintentional activation.

A183 Waste batteries and batteries being shipped for recycling or disposal are forbidden from air transport unless approved by the appropriate national authority of the State of Origin and the State of the Operator.

A802 Articles assigned to these entries must be packed in UN Specification packagings that meet packing group II performance standards.

Valve Regulated Lead Acid (VRLA) Batteries:

Road and Railway Transport (ADR/RID)| – UN Number: 2800

– Proper Shipping Name: BATTERIES, WET, NON-SPILLABLE

– Class: 8

– Hazard label: 8

– Packing Group: not assigned

– Special provisions : 238, 295, 598

– Packing instructions (P) and Packing Provision (PP): P003, P801 (only for new batteries), PP16

– Tunnel codes (ADR only): (E)

NOTE:

238 a) Batteries can be considered as non-spillable provided that they are capable of withstanding the appropriate vibration and pressure differential tests, without leakage of batter fluid. The aforementioned tests are described in ADR/RID.

(b) Non-spillable batteries are not subject to the requirements of ADR/RID if, at a temperature of 55°C , the electrolyte will not flow from a ruptured or cracked case and there is no free liquid to flow and if, as packaged for carriage ,

the terminals are protected from short circuit.

295 Batteries need not be individually marked and labelled if the pallet bears the appropriate mark and label

598 The following are not subject to the requirements of ADR/RID:

(a) New storage batteries when:

– they are secured in such a way that they cannot slip, fall or be damaged;

– they are provided with carrying devices, unless they are suitably stacked, e.g. on pallets;

– there are no dangerous traces of alkalis or acids on the outside;

– they are protected against short circuits;

(b) Used storage batteries carried for recycling at the end of their normal service life when:

–  their cases are undamaged;

–  they are secured in such a way that they cannot leak, slip, fall or be damaged, e.g. by stacking on pallets;

–  there are no dangerous traces of alkalis or acids on the outside of the articles;

–  they are protected against short circuits.

---|---
Sea Transport (IMDG Code)| – UN Number: 2800

– Proper Shipping Name: BATTERIES, WET, NON-SPILLABLE

– Class: 8,

– Hazard label: 8

– Packing Group: not assigned

– Special provision: 238

– Packing instruction (P)) and Packing Provision (PP): P003, PP16

– Emergency Schedule (EmS): F-A, S-B

NOTE:

238 Non-spillable batteries are not subject to the provisions of IMDG Code if, at a temperature of 55°C , the electrolyte will not flow from a ruptured or cracked case and there is no free liquid to flow and if, when packaged for transport , the

terminals are protected from short circuit.

Air Transport (IATA DGR)| – UN Number: 2800

– Proper Shipping Name: BATTERIES, WET, NON SPILLABLE

– Class: 8,

– Hazard label: corrosives (figure 7.3.V)

– Packing Group: Not assigned

– Special provisions: A48, A67, A164, A183,

– Packing instruction on passenger aircraft: 872

– Packing instruction on Cargo Aircraft Only: 872

NOTE:

A48 Packaging tests are not considered necessary

A67 Wet cell batteries can be considered as non-spillable provided that they are capable of withstanding the appropriate vibration and pressure differential tests, without leakage of batter fluid. Aforementioned tests are described in IATA DGR.

Non-spillable type batteries which are an integral part of, and necessary for the operation of, mechanical or electronic equipment must be securely fastened in the battery holder on the equipment and protected in such a manner so as to prevent damage and short circuits.

Non-spillable batteries are not subject to Regulations of IATA DGR when carried

s cargo if, at a temperature of 55°C , the electrolyte will not flow from a ruptured or cracked case. The battery must not contain any free or unabsorbed liquid. Any electrical battery or battery powered device, equipment or vehicle having the potential of dangerous evolution of heat must be prepared for transport so as to prevent:

a) a short circuit (e.g. in the case of batteries, by the effective insulation of exposed terminals; or in the case of equipment, by disconnection of the battery and protection of exposed terminals); and

b) unintentional activation.

The words “ Not Restricted ” and the Special Provision number A67 must be

 | included in the description of the substance on the Air Waybill as required by IATA DGR 8.2.6, when an Air Waybill is issued. Therefore, the Air Waybill must then include the text : “ Battery successfully passed tests described in Special Provision number A67 and could be send as Not Restricted ” or its equivalent.

A164 Any electrical battery or battery powered device, equipment or vehicle having the potential of a dangerous evolution of heat must be prepared for transport so as to prevent:

(a) a short circuit (e.g. in the case of batteries by the effective insulation of exposed terminals; or in the case of equipment, by disconnection of the battery and protection of exposed terminals); and

(b) unintentional activation.

A183 Waste batteries and batteries being shipped for recycling or disposal are forbidden  from  air  transport  unless  approved  by  the appropriate

national authority of the State of Origin and the State of the Operator.

---|---

Regulatory Information
In accordance with EU Battery Directive and the respective national legislation, Lead-Acid batteries have to be marked by a crossed-out dust bin with the chemical symbol for lead shown below, together with the ISO return/recycling symbol.

In addition, Lead-Acid batteries may have to be labelled with the hazard symbols described below:

Labelling may vary due to application and dimension of the Battery. The manufacturer, respectively the importer of the batteries shall be responsible for placing the symbols (a minimum size is specified). In addition, consumer/user information on the significance of the symbols may be attached.

Substances of Very High Concern (SVHC)
The publications of the European Chemicals Agency on substances of very high concern are monitored by EnerSys. As defined by REACH, customers will receive the required information if an updated publication may add a substance relevant for our products to the list of SVHC’s. On 19 December 2012, four Lead compounds used in the process of battery manufacturing – Lead Monoxide, Lead Tetroxide, Tetralead Trioxide Sulphate and Pentalead Tetraoxide Sulphate – were added to the list of Substances of Very High Concern. As of June 27 2018, Lead Metal was added to the SVHC list as well.
Irrespective of the battery design (flooded, MHF, Gel, AGM) all lead based batteries contain Lead Metal (CAS Nr.: 7439-92-1). The content varies but exceeds the notification threshold of 0,1% w/w.
Batteries ready for use do not contain Oxides our Sulphates that are classified SVHC.
Dry Batteries/dry cells (dry charged plates, delivered without electrolyte) contain more than 0,1 % of Lead Monoxide. Lead Monoxide (CAS Nr.: 1317-36-8) is listed as a substance of very high concern. Once the batteries/cells are filled with electrolyte all Lead Monoxide is transformed and the presence of Lead Monoxide has ended.

Other Information

Products such as Batteries are not in the scope of regulation which require the publication of an EU Safety Data Sheet (Regulation (EC) 1907/2006, Article 31).
The information given above is provided in good faith based on existing knowledge and does not constitute an assurance of safety under all conditions. It is the user’s responsibility to observe all laws and regulations applicable for storage, use, maintenance or disposal of the product. If there are any queries, the supplier should be consulted.
However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship.

© 2021 EnerSys. All rights reserved. Trademarks and logos are the property of EnerSys and its affiliates unless otherwise noted.
Subject to revisions without prior notice. E.&O.E. EMEA-EN-ISH-0721

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