JELMAR Material Safety Data Sheet

MATERIAL SAFETY DATA SHEET CLR CALCIUM, LIME & RUST REMOVER

1 – PRODUCT AND COMPANY IDENTIFICATION

SDS ID: 521012 Product Name Product Use_ CLR Calcium, Lime & Rust Remover Aqueous Acidic Cleaner for Removal of Calcium, Lime, and Rust from  Hard Surfaces Retail Package: [28 fl. oz., 42 fl. oz., and 128 fl. oz. (one gallon)}
CAS# Proprietary Mixture
Restrictions on Use__ Incompatible with strong oxidizing agents, metals (except stainless steel, chrome), acids, bases, and bleach.

Manufacturer: Jelmar, LLC
Address: 5550 W. Touhy Ave. Skokie, IL 60077
Emergency Phone Number: 1(800) 323-5497 (USA) Monday – Friday 8:30 A.M. – 4:30 P.M. CST
Emergency 24 hour Contact: Chemtrec 1(800) 424-9300

2 – HAZARDS IDENTIFICATION
Emergency Overview: WARNING : EYE IRRITANT. GHS Toxicity Category 2A Causes eye irritation and possible SKIN IRRITANT GHS Category 3 – on sensitive skin. DO NOT get in eyes, on the skin, or clothing. DO NOT mix with bleach or other household chemicals as harmful fumes may result. DO NOT  ingest. DO NOT breathe vapor or mist. Use in well-ventilated areas. Keep container closed when not in use.
KEEP OUT OF REACH OF CHILDREN

Potential Short Term Health Effects
Routes of Exposure Eyes, Skin, Inhalation, Ingestion.
Eyes- Irritant Avoid eye contact Effects may vary depending on the length of exposure, solution concentration
Skin —Irritant. Prolonged contact may cause dermatitis and itching.
Inhalation- No adverse effects expected under typical use conditions.
Ingestion- – Oral burns, vomiting, and gastrointestinal disturbance.
Target organs – Eyes. Skin.

SECTION 3 – COMPOSITION /INFORMATION ON INGREDIENTS

Component                      CAS#                      OSHA HAZARD % by Weight
1. Lactic Acid                    79-33-4                         YES 12.00-18.00
2. Gluconic Acid                526-95-4                      YES 2.50-3.75
3. Lauramine Oxide          1643-20-5                       YES 1.50-3.25

SECTION 4 – FIRST AID MEASURES
EYE CONTACT: In case of eye contact, immediately rinse the eye thoroughly with plenty of water. Remove contact lenses, and continue rinsing for at least 15 minutes. If irritation persists, get medical attention.
SKIN CONTACT: Can be irritating to the skin, prolonged contact can be more severe, no adverse effects during normal usage. In case of skin contact, rinse the area for at least 15 minutes. Remove contaminated clothing and shoes, wash thoroughly before reuse. If irritation persists get medical attention.
INHALATION : Not a significant route of exposure. Remove to fresh air. If breathing is difficult, GET MEDICAL ATTENTION IMMEDIATELY.
INGESTION: DO NOT induce vomiting. If fully conscious, drink 16 ounces of water. CALL A PHYSICIAN OR POISON CONTROL CENTER  IMMEDIATELY. NEVER give an unconscious person anything to ingest.

SECTION 5 – FIRE FIGHTING MEASURES
FLAMMABILITY: Not flammable
FLASHPOINT : None; Method: ASTM D-56
EXPLOSIVE LIMITS IN AIR : Not available
EXTINGUISHING MEDIA : Not flammable. Use appropriate media for the area. Use water spray, dry chemical, alcohol foam, or carbon dioxide.
FIRE FIGHTING METHODS : Evacuate area of personnel. Wear protective NIOSH-approved self-contained breathing apparatus. Remain upwind of fire to avoid hazardous vapors and decomposition products. Use water spray to cool fire-exposed containers. Run-off of large quantities of product from fire control may cause pollution. Contact appropriate agencies.
HAZARDOUS COMBUSTION PRODUCTS: Carbon Monoxide. Thermal decomposition can lead to irritating gases and vapors.
FIRE AND EXPLOSION HAZARDS : None knew.

SECTION 6 – ACCIDENTAL RELEASES MEASURES
Steps to be Taken in Case Material is Released or Spilled: Avoid contact with skin and eyes Small Spill: No special clean-up procedure is necessary for small  (less than 1 gallon) spills. Flush spill area with water. Wear rubber gloves.
Large Spill : Use personal protection recommended in Section 8. Isolate area, and deny entry to unnecessary and unprotected personnel. Dam spill, and absorb with earth, sand, or similar material. Place in non-leaking containers. Dispose of collected material according to local, state, and federal regulations. Flush residue with a large amount of water. Avoid direct discharge to sewers and surface waters.

SECTION 7- HANDLING AND STORAGE
STORAGE: Store in a cool, well-ventilated area, away from heat. Keep containers tightly closed. Avoid contact with combustible materials, wood, and organic materials. Store in original container in a secure area away from children and pets.
HANDLING : Avoid contact with eyes, skin, or clothing. It May be harmful or if swallowed. Use with adequate ventilation. Avoid breathing vapors or mist. Do not eat, drink, or smoke in the work area. Wash hand thoroughly after use. Consumer size containers (28, and 42 fluid ounces and gallon containers), should be rinsed and recycled. DO NOT PRESSURIZE, CUT OR EXPOSE THESE CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION. THEY MAY EXPLODE AND CAUSE INJURY. DO NOT MIX WITH BLEACH, OR ANY OTHER PRODUCTS AS TOXIC FUMES MAY RESULT. KEEP OUT OF REACH OF CHILDREN.

SECTION 8 – EXPOSURE CONTROLS / PERSONAL PROTECTION
VENTILATION REQUIREMENT : Avoid prolonged breathing mists or dust of this product. Use with adequate ventilation. Do not use in closed or confined spaces.
RESPIRATORY PROTECTION : None required during normal household use.
EYE PROTECTION : Not required during normal household usage. Do not wear contact lenses. Emergency responders should wear full eye and face protection.
SKIN PROTECTION : Rubber gloves with protective cuff. Emergency responders should wear impermeable gloves.
OTHER PROTECTION : Emergency responders should wear chemical type (impermeable) protective clothing and footwear where direct contact with chemicals in this product is possible.
WORK/HYGIENIC PRACTICES : Wash thoroughly with soap and water after use or handling.

EXPOSURE GUIDELINES:            OSHA            ACGIH
COMPONENT                                 PEL                 STEL/C TWA              STEL/C
1. Lactic Acid                                     N.E                  N.E. N.E.             N.E.
2. Gluconic Acid                                N.E.                 N.E. N.E.             N.E.
3. Lauramine Oxide                           N.E.                  N.E. N.E.            N.E.

SECTION 9 – PHYSICAL AND CHEMICAL PROPERTIES
Boiling point:                          99ºC / 210º F Specific Gravity @20ºC: 1.04 – 1.06
Vapor Pressure:                      N.D. Percent Volatiles: ~77.2% (Calculated)
Freezing Point:                       N.D. Evaporation Rate: N.D. (nBuAc=1)
Melting Point:                         N.D. Total VOC (wt. %): 0% – does not include any
Vapor Density (mm Hg):       N.D.                                    (Volatile Organic Compounds/ CARB applicable
pH: @20ºC                           2.10-2.30 California Air Resource Board) exemptions
Solubility in Water: 100%

SECTION 10 – STABILITY AND REACTIVITY
STABILITY: Stable under normal conditions.
CONDITIONS TO AVOID : Avoid elevated temperatures.
INCOMPATIBLE MATERIALS : Strong oxidizing agents, metals (except stainless steel and chrome), acids, and bases.
HAZARDOUS DECOMPOSITION PRODUCTS : Thermal decomposition can lead to release of irritating gases, vapors and carbon oxides.
POSSIBILITY OF HAZARDOUS REACTIONS : No data.

SECTION 11 – TOXICOLOGICAL INFORMATION
LD50 ACUTE EYE IRRITATION : OPPTS 8740.2400 Toxicity – Irritant; GHS Toxicity Category 2A – Irritant
LD50 ACUTE DERMAL IRRITATION – RABBITS: OPPTS 870.2500 Toxicity Category IV – Mild or Slight Skin Irritation; GHS Category 3 – Mild Skin Irritation.
LD50ACUTE ORAL TOXICIT Y – RATS: OPPTS 870.1100 Toxicity Category IV

5,000 mg/kg; GHS Category 5 >5,000 mg/kg – Not Toxic
LD50ACUTE DERMAL TOXICITY – RABBITTS: OPPTS 870-1200 Toxicity Category IV 5 g/kg; GHS Category 5 >5,000 mg/kg – Not Toxic
LD50 ACUTE INHALATION TOXICITY – RATS: OPPTS 870.1300 Toxicity Category IV – Not toxic by inhalation; GHS Category 5 – Not toxic by inhalation

SECTION 12- ECOLOGICAL INFORMATION

ECOTOXICOLOGICAL INFORMATION: LACTIC ACID:
Persistence / degradability
Readily biodegradable, according to appropriate OECD test.
Biochemical oxygen demand (BOD)5 = 0.45 mg O2 /mg
Biochemical oxygen demand (BOD)20= 0.60 mg O2/mg
Chemical oxygen demand (COD) =0.90 mg O2 /mg
Bioaccumulation
None.
Ecotoxicity
EC50/48h/Daphnia = 240mg/l LC50/48h/Fish = 320 mg/l
EC50/Algae = 3500 mg/l(neutral) No data available.

GLUCONIC ACID:
Fish 96-h LC50 > 1000.0 mg/L
Daphnid 48-h LC50 > 1000.0 mg/L
Green algal 96-h EC50 > 1000.0 mg/L
Fish Chronic Value (ChV) > 100.0 mg/L
Daphnid ChV > 100.0 mg/L
Algal ChV > 100.0 mg/L
Biological Fate: No bioconcentration in aquatic organisms and rapid
biodegradation/disappearance in the environment, i.e. 40% in 5 days.

LAURAMINE OXIDE : Acute Aquatic Toxicity
Reviewed Category ≤1 mg/L
Algae IC50 0.01 mg/L
Invertebrate EC50 1.01 mg/L
Fish LC50 2.6 mg/L
Biodegradation: % degraded in 28 days ≥60% ThOD/ThCO2 (≥70% DOC)

DOWANOL DPNB:
Movement & Partitioning
Bioconcentration potential is low (BCF less than 100 or log Pow less than 3). Potential for mobility in soil is very high (Koc between 0 and 50).

Henry’s Law Constant (H): 3.78E-07 atm*m3/mole; 25 °C Estimated.
Partition coefficient, n-octanol/water (log Pow): 1.13 Estimated.
Partition coefficient, soil organic carbon/water (Koc): 10 – 21 Estimated.
Persistence and Degradability
Material is readily biodegradable. Passes OECD test(s) for ready biodegradability. Material is ultimately biodegradable (reaches > 70% mineralization in OECD  test(s) for inherent biodegradability).
Indirect Photodegradation with OH Radicals
Rate Constant Atmospheric Half-life Method
4.97E-11 cm3/s 2.6 h Estimated.
OECD Biodegradation Tests:
Biodegradation Exposure Time Method
91 % 28 d OECD 301E Test
96 % 28 d OECD 302B Test
Theoretical Oxygen Demand: 2.35 mg/mg

ECOTOXICITY
Material is practically non-toxic to aquatic organisms on an acute basis (LC50/EC50/EL50/LL50 >100 mg/L in the most sensitive species tested).
Fish Acute & Prolonged Toxicity
LC50, guppy (Poecilia reticulate), static, 96 h: 841 mg/l
Aquatic Invertebrate Acute Toxicity
LC50, water flea Daphnia magna, static, 48 h, immobilization: > 1,000 mg/l
CLR CHEMICAL FATE INFORMATION: 28-day biodegradation. The matter is readily biodegradable. OECD 301D

SECTION 13 – DISPOSAL CONSIDERATIONS
DISPOSAL METHOD: Rinse empty bottles and recycle them. Dispose of unused product in a permitted hazardous waste management facility following all local, state, and federal regulations.

DO NOT PRESSURIZE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND OR EXPOSE CONTAINERS TO HEAT, FLAME, SPARKS, STATIC  ELECTRICITY, OR OTHER SOURCES OF IGNITION.
Follow label warnings, since containers may retain some residue of the product.
Processing, use, or contamination of this product may change the waste management options. It is the responsibility of the waste generator to determine the toxicity and physical properties of the material generated to determine the proper waste identification and disposal methods in compliance with applicable regulations. State and local disposal regulations may differ from federal disposal regulations.

SECTION 14 – TRANSPORTATION INFORMATION
DOT (Department of Transportation Proper Shipping Name): Not regulated by DOT.  Identification Number: N.A.Packaging Group: N.A.
UN Number: N.A.
TDG Classification: Not Regulated
IMDG Classification: Not Regulated
IATA Classification: Passenger – Not Regulated
WHIMS (Canada): This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by CPR.

SECTION 15 – REGULATORY INFORMATION
FEDERAL REGULATIONS: TSCA INVENTORY STATUS: All components of this product are listed on the TSCA Inventory or are exempt from TSCA Inventory requirements.

SARA TITLE III SECTION 311/312 CATEGORY:
IMMEDIATE (ACUTE) HEALTH HAZARD: YES
DELAYED (CHRONIC) HEALTH HAZARD: NO
FIRE HAZARD: NO
SUDDEN RELEASE OF PRESSURE: NO
REACTIVE HAZARD: NO
SARA SECTIONS 302/304/313/HAP: NO
INTERNATIONAL CHEMICAL INVENTORY STATUS:
EUROPEAN UNION (EINECS)-YES
JAPAN (METI)-YES
AUSTRALIA (ACIS)-YES
KOREA (KECL)-YES
CANADA (DSL)-YES
CANADA (NDSL)-NO
PHILIPPINES-YES

STATES RIGHT TO KNOW California, New Jersey, Pennsylvania, Minnesota, Massachusetts, and Wisconsin. Complies with listed States Right to Know Act.
The following statement is made in order to comply with the California State Drinking Water Act. California Proposition 65: This product does not contain any chemicals known to the State of California to cause cancer and/or to cause birth defects and other reproductive harm.

SECTION 16 – OTHER INFORMATION
Precautions to be taken in Handling and Storing: Avoid exposure to excess heat, and prevent freezing. Other Precautions: None required.
MSDS ABBREVIATIONS:
N. A.: Not Applicable
HAP: Hazardous Air Pollutant
VOC: Volatile Organic Compound
N. D.: Not Determined
N.E.: Not Established
C: Ceiling Limit
HAP: Hazardous Air Pollutant
VOC: Volatile Organic Compound

Revision: New Formula,             GHS Format                      October 2012                  R. A. Gaudreault

Although the information and recommendations set forth herein are presented in good faith and believed to be correct as of the date hereof, JELMAR offers no representations as to the completeness or accuracy thereof. Information is provided upon the condition that the persons receiving same will make their own determination as to its suitability for their purposes prior to use. In no event will JELMAR be responsible for damages of any nature whatsoever resulting from the use of or reliance upon said information.
NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESSED OR IMPLIED, OF MERCHANTABILITY, FITNESS FOR A PARTICULAR  PURPOSE, OR OF ANY OTHER NATURE ARE MADE HEREUNDER WITH RESPECT TO INFORMATION OR THE PRODUCT TO WHICH INFORMATION HEREIN REFERS.

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