HACH AT1000 Series Titration Bundle User Manual
- June 14, 2024
- HACH
Table of Contents
- AT1000 Series Titration Bundle
- Product Specifications
- Dimensions
- Weight
- Power Requirements
- Main Supply Voltage Fluctuation
- Operating Temperature
- Storage Temperature
- Pollution Degree
- Protection Class
- Environmental Conditions
- Certifications
- Warranty
- Product Usage Instructions
- Safety Information
- Precautionary Labels
- Compliance and Certification
- FAQ
- Q: Can this product be used outdoors?
- Q: What is the warranty period for this product?
- References
- Read User Manual Online (PDF format)
- Download This Manual (PDF format)
AT1000 Series Titration Bundle
Product Specifications
Dimensions
Width: 22 cm (8.7 in)
Depth: 40 cm (15.7 in)
Height: 36 cm (14.2 in)
Weight
4 kg (8.8 lb)
Power Requirements
Input: 24 VDC, 2.5 A
Main Supply Voltage Fluctuation
Altitude: 2,000 m (6,562 ft) maximum
Operating Temperature
20 to 80% relative humidity, non-condensing
Storage Temperature
Overvoltage Category: II
Pollution Degree
2
Protection Class
II
Environmental Conditions
Indoor use only
Certifications
Safety: IEC/EN 61010-1, UL/CSA C22.2 61010-1
EMC: IEC/EN 61326-1
Warranty
1 year (EU: 2 years)
Product Usage Instructions
Safety Information
DANGER: Indicates a potentially or imminently
hazardous situation which, if not avoided, will result in death or
serious injury.
WARNING: Indicates a potentially or imminently
hazardous situation which, if not avoided, could result in death or
serious injury.
CAUTION: Indicates a potentially hazardous
situation that may result in minor or moderate injury.
NOTICE: Indicates a situation which, if not
avoided, may cause damage to the instrument. Information that
requires special emphasis.
Precautionary Labels
Read all labels and tags attached to the instrument. Personal
injury or damage to the instrument could occur if not observed. A
symbol on the instrument is referenced in the manual with a
precautionary statement. This symbol, if noted on the instrument,
references the instruction manual for operation and/or safety
information.
This symbol indicates that a risk of electrical shock and/or
electrocution exists.
This symbol indicates the presence of devices sensitive to
Electro-static Discharge (ESD) and indicates that care must be
taken to prevent damage with the equipment.
Electrical equipment marked with this symbol may not be disposed
of in European domestic or public disposal systems. Return old or
end-of-life equipment to the manufacturer for disposal at no charge
to the user.
Compliance and Certification
CAUTION: This equipment is not intended for use
in residential environments and may not provide adequate protection
to radio reception in such environments.
1. The equipment may not cause harmful interference.
2. The equipment must accept any interference received,
including interference that
FAQ
Q: Can this product be used outdoors?
A: No, this product is designed for indoor use only.
Q: What is the warranty period for this product?
A: The warranty period is 1 year, with an extended warranty of 2
years for customers in the European Union.
DOC022.52.93074
TitraLab® AT1000 series workstations
User Manual 12/2022, Edition 10
Table of Contents
Section 1 Specifications…………………………………………………………………………………………………….. 3
Section 2 General information…………………………………………………………………………………………… 5 2.1 Safety
information………………………………………………………………………………………………………… 5 2.1.1 Use of hazard
information……………………………………………………………………………………… 5 2.1.2 Precautionary
labels……………………………………………………………………………………………… 5 2.1.3 Compliance and
certification………………………………………………………………………………….. 6 2.1.4 Restriction of
hazardous substances (RoHS)…………………………………………………………… 6 2.2 Product
overview………………………………………………………………………………………………………….. 7 2.3 Instrument
connections…………………………………………………………………………………………………. 8 2.4 Product
components…………………………………………………………………………………………………….. 9
Section 3 Installation………………………………………………………………………………………………………… 11 3.1
Installation guidelines………………………………………………………………………………………………….. 11 3.2 Connect
to AC power………………………………………………………………………………………………….. 11 3.3 Install the
syringe……………………………………………………………………………………………………….. 12 3.4 Install the sensor
storage tubes……………………………………………………………………………………. 13 3.5 Install the stir bar and
the beaker………………………………………………………………………………….. 13 3.6 Prepare the
tubes……………………………………………………………………………………………………….. 13 3.7 Connect the
tubes………………………………………………………………………………………………………. 14 3.8 Install the
sensor………………………………………………………………………………………………………… 14 3.8.1 Install the legacy
adapter…………………………………………………………………………………….. 14 3.8.1.1 Set the legacy adapter
settings…………………………………………………………………….. 15 3.8.2 Connect the
sensor…………………………………………………………………………………………….. 15 3.9 Install the titrant and the
reagent…………………………………………………………………………………… 16 3.10 Tidy the work
area…………………………………………………………………………………………………….. 18
Section 4 Install accessories……………………………………………………………………………………………. 19 4.1
Install an external pump………………………………………………………………………………………………. 19 4.2 Install
an external propeller………………………………………………………………………………………….. 21 4.3 Install a
balance…………………………………………………………………………………………………………. 21 4.4 Install PC
software……………………………………………………………………………………………………… 22 4.5 Install the syringe
verification kit…………………………………………………………………………………… 22
Section 5 User interface and navigation…………………………………………………………………………..25 5.1
Keypad……………………………………………………………………………………………………………………… 25 5.2 Home
screen……………………………………………………………………………………………………………… 25 5.3 Menu
structure…………………………………………………………………………………………………………… 26
Section 6 Startup………………………………………………………………………………………………………………. 29 6.1 Configure
the instrument……………………………………………………………………………………………… 29 6.2 Install the
applications…………………………………………………………………………………………………. 30 6.3 Prepare the
instrument for measurement………………………………………………………………………. 30
Section 7 Standard operations………………………………………………………………………………………… 33 7.1
Calibration…………………………………………………………………………………………………………………. 33 7.1.1 Calibrate the
sensor……………………………………………………………………………………………. 33 7.1.2 Calibrate the
titrant……………………………………………………………………………………………… 34 7.1.3 Auto leveling
calibration………………………………………………………………………………………. 35 7.2 Sample
preparation…………………………………………………………………………………………………….. 36 7.3 Get a sample
measurement…………………………………………………………………………………………. 36 7.4 Change the application
settings……………………………………………………………………………………. 38 7.4.1 Sample
name…………………………………………………………………………………………………….. 38 7.5 Manage the data
log…………………………………………………………………………………………………… 39 7.6
Purge………………………………………………………………………………………………………………………… 39
1
Table of Contents Section 8 Maintenance………………………………………………………………………………………………………
41
8.1 Maintenance schedule………………………………………………………………………………………………… 41 8.2 Clean the
instrument…………………………………………………………………………………………………… 41 8.3 Clean the
sensor………………………………………………………………………………………………………… 41 8.4 Replace the
tubes………………………………………………………………………………………………………. 42 8.5 Replace desiccant
cartridge contents……………………………………………………………………………. 42 8.6 Replace the syringe
electro-valve block…………………………………………………………………………. 42 8.7 Maintenance
menu……………………………………………………………………………………………………… 42
8.7.1 Syringe activation……………………………………………………………………………………………….. 43 8.7.2 Pump
activation………………………………………………………………………………………………….. 43 8.7.3 Syringe
management………………………………………………………………………………………….. 43 8.7.4 Syringe
verification……………………………………………………………………………………………… 43 8.7.5 Pump cassette
replacement…………………………………………………………………………………. 44 8.7.6 Other maintenance
options………………………………………………………………………………….. 45 8.8 Storage and
transportation…………………………………………………………………………………………… 46 8.8.1 Prepare the
instrument for storage…………………………………………………………………………46 8.8.2 Prepare the
instrument for short-term storage………………………………………………………… 47 8.8.3 Prepare the
instrument for shipment……………………………………………………………………… 47 Section 9
Troubleshooting………………………………………………………………………………………………..49 Section 10 Replacement
parts and accessories………………………………………………………………57 Appendix A Change application
parameters…………………………………………………………………… 63 Appendix B Frequently asked
questions………………………………………………………………………… 73 Section 13 Configure the
instrument………………………………………………………………………………. 75
2
Section 1 Specifications
Specifications are subject to change without notice.
Specification Dimensions (W x D x H)
Details 22 x 40 x 36 cm (8.7 x 15.7 x 14.2 in.)
Weight
4 kg (8.8 lb)
Power requirements
Instrument: Input 24 VDC, 2.5 A
External power supply: Input 100240 VAC, 5060 Hz, 1.5 A, Class I; output 24
VDC, 2.5 A 60 VA
Main supply voltage fluctuation
±10% of nominal voltage
Altitude
2,000 m (6,562 ft) maximum
Operating temperature
15 to 35 °C (59 to 95 °F)
Relative humidity
20 to 80%, non-condensing
Storage temperature
5 to 40 °C (23 to 104 °F)
Overvoltage category
II
Pollution degree
2
Protection class
II
Environmental conditions
Indoor use
Certifications EMC requirements
Safety: IEC/EN 61010-1, UL/CSA C22.2 61010-1 EMC: IEC/EN 61326-1
This product is intended to be used in a domestic or basic electromagnetic
environment.
Warranty
1 year (EU: 2 years)
3
Specifications
4
Section 2 General information
In no event will the manufacturer be liable for damages resulting from any
improper use of product or failure to comply with the instructions in the
manual. The manufacturer reserves the right to make changes in this manual and
the products it describes at any time, without notice or obligation. Revised
editions are found on the manufacturer’s website.
2.1 Safety information
The manufacturer is not responsible for any damages due to misapplication or
misuse of this product including, without limitation, direct, incidental and
consequential damages, and disclaims such damages to the full extent permitted
under applicable law. The user is soley responsible to identify critical
application risks and install appropriate mechanisms to protect processes
during a possible equipment malfunction. Please read this entire manual before
unpacking, setting up or operating this equipment. Pay attention to all danger
and caution statements. Failure to do so could result in serious injury to the
operator or damage to the equipment. Make sure that the protection provided by
this equipment is not impaired. Do not use or install this equipment in any
manner other than that specified in this manual.
2.1.1 Use of hazard information
DANGER
Indicates a potentially or imminently hazardous situation which, if not
avoided, will result in death or serious injury.
WARNING
Indicates a potentially or imminently hazardous situation which, if not
avoided, could result in death or serious injury.
CAUTION
Indicates a potentially hazardous situation that may result in minor or
moderate injury.
NOTICE
Indicates a situation which, if not avoided, may cause damage to the
instrument. Information that requires special emphasis.
2.1.2 Precautionary labels
Read all labels and tags attached to the instrument. Personal injury or damage
to the instrument could occur if not observed. A symbol on the instrument is
referenced in the manual with a precautionary statement. This symbol, if noted
on the instrument, references the instruction manual for operation and/or
safety information.
This symbol indicates that a risk of electrical shock and/or electrocution
exists.
5
General information
This symbol indicates the presence of devices sensitive to Electro-static
Discharge (ESD) and indicates that care must be taken to prevent damage with
the equipment.
Electrical equipment marked with this symbol may not be disposed of in
European domestic or public disposal systems. Return old or end-of-life
equipment to the manufacturer for disposal at no charge to the user.
2.1.3 Compliance and certification
CAUTION
This equipment is not intended for use in residential environments and may not
provide adequate protection to radio reception in such environments.
Canadian Radio Interference-Causing Equipment Regulation, ICES-003, Class A:
Supporting test records reside with the manufacturer. This Class A digital
apparatus meets all requirements of the Canadian InterferenceCausing Equipment
Regulations. Cet appareil numérique de classe A répond à toutes les exigences
de la réglementation canadienne sur les équipements provoquant des
interférences. FCC Part 15, Class “A” Limits Supporting test records reside
with the manufacturer. The device complies with Part 15 of the FCC Rules.
Operation is subject to the following conditions:
1. The equipment may not cause harmful interference. 2. The equipment must
accept any interference received, including interference that
may cause undesired operation.
Changes or modifications to this equipment not expressly approved by the party
responsible for compliance could void the user’s authority to operate the
equipment. This equipment has been tested and found to comply with the limits
for a Class A digital device, pursuant to Part 15 of the FCC rules. These
limits are designed to provide reasonable protection against harmful
interference when the equipment is operated in a commercial environment. This
equipment generates, uses and can radiate radio frequency energy and, if not
installed and used in accordance with the instruction manual, may cause
harmful interference to radio communications. Operation of this equipment in a
residential area is likely to cause harmful interference, in which case the
user will be required to correct the interference at their expense. The
following techniques can be used to reduce interference problems:
1. Disconnect the equipment from its power source to verify that it is or is
not the source of the interference.
2. If the equipment is connected to the same outlet as the device
experiencing interference, connect the equipment to a different outlet.
3. Move the equipment away from the device receiving the interference. 4.
Reposition the receiving antenna for the device receiving the interference. 5.
Try combinations of the above.
2.1.4 Restriction of hazardous substances (RoHS)
Dieses Informationsblatt enthält Angaben, die ausschließlich für den Export
dieses Gerätes in die Volksrepublik China erforderlich sind. This document
contains information which is only required for the export of this instrument
into the People’s Republic of China. Type: AT1xxx
6
(Parts) (Resistor) ( Diode)
General information
Name: TitraLab AT1000 Table 1 (Hazardous Substance)
(Pb) (Hg) (Cd) (Cr6+)
(PBB)
X
O
O
O
O
X
O
O
O
O
(PBDE) O O
SJ/T11363-2006 O: Indicates that the concentration of the hazardous substance
in all homogeneous materials in the parts is below the
relevant threshold of the SJ/T11363-2006 standard.
SJ/T11363-2006 X: Indicates that the concentration of the hazardous substance
of at least one of all homogeneous materials in the parts
is above the threshold of the SJ/T11363-2006 standard.
, , : This table shows where these substances may be found in the supply chain
of “Company” electronic information products, as of the date of sale of the
enclosed product. Note that some of the component types listed above may or
may not be a part of the enclosed product.
, . ( , ) . . The Environmentally Friendly Use Period (EFUP) for all enclosed products and their parts are per the symbol shown here, unless otherwise marked. Certain field-replaceable parts have a different EFUP (for example, battery modules) and so are marked to reflect such. The Environmentally Friendly Use Period is valid only when the product is operated under the conditions defined in the product manual.
2.2 Product overview
The instrument operates with digital and analog sensors to do potentiometric
(AT1000 series) and volumetric (KF1000 series) titration. Measurement
applications are installed on the instrument to automate the measurement
process. Instructions show on the display when user intervention is required.
7
General information
1 Keypad
6 Beaker
11 Sensor holder
2 Display
7 Syringe protection cover
12 Pump 2 input/output
3 Sensor storage tubes 4 USB port1
8 Syringe input/output 9 Tube clips
13 Pump 1 input/output 14 Pump access cover
5 Tube holder
10 Syringe Note: Depending on the model, there will be 1 or 2 syringes and syringe input/output ports, and 0, 1 or 2 pumps. Refer to Table 2.
Table 2 Instrument configurations
Model
Syringes
Pumps
AT1102
1
0
AT1112
1
1
AT1122
1
2
AT1222
2
2
2.3 Instrument connections
DANGER
ElectricaI shock hazard. Externally connected equipment must comply with an
applicable country safety standard (e.g., IEC 60950-1 or IEC 62368-1 for IT
equipment) and the circuit intended to be connected to the equipment shall not
exceed the SELV (safety extra low voltage) safe level.
1 A second USB port is found on the rear of the instrument, but the instrument
recognizes only one USB storage device connection at a time.
8
General information
Use the USB port on the side of the instrument for the USB applications key
supplied with the instrument. Use the USB port on the rear of the instrument
to connect to a printer, mouse, keyboard or a USB hub.
1 24 V external power supply port 2 Sensor 1 port 3 Sensor 2 port
4 External pump port 5 External propeller port 6 Serial port
7 USB port 8 Ethernet port
2.4 Product components
Make sure that all components have been received. Refer to the packing list in
the box. If any items are missing or damaged, contact the manufacturer or a
sales representative immediately.
Figure 1 Contents of the instrument box
Note: For identification, the outlet tube from the syringe is fitted with a blue marker.
1 Instrument
2 Tube holder (1 for each syringe position on the instrument)
3 Sensor storage tubes (3x) 4 Power supply
5 Power cord
9
General information
Figure 2 Contents of the application box
1 Beakers (5 x 50 mL and 5 x 150 mL) 2 Tube with anti-diffusion tip (if
necessary for the
application) 3 Conical adapters (quantity depends on application) 4 Magnetic
stir bars 5 Legacy sensor adapter (not in all application kits) 6 Sensor (type
and quantity depends on application)
7 Syringe holding ring (1 for each syringe) 8 Syringe (refer to Table 2 on
page 8 for quantity)
9 USB applications key 10 Glass bottles (not in all application kits) 11
Bottle caps (type and quantity depends on application)
10
Section 3 Installation
CAUTION
Multiple hazards. Only qualified personnel must conduct the tasks described in
this section of the document.
NOTICE
This is a class A product. There may be potential difficulties in ensuring
electromagnetic compatibility in other environments, due to conducted as well
as radiated disturbances. In a domestic environment this product may cause
radio interference in which case the user may be required to take adequate
measures.
NOTICE
Network and access point security is the responsibility of the customer that
uses the wireless instrument. The manufacturer will not be liable for any
damages, inclusive however not limited to indirect, special, consequential or
incidental damages, that have been caused by a gap in, or breach of network
security.
The instrument is available in different configurations (refer to Table 2 on
page 8). This manual supplies instructions for the installation of an
instrument with one syringe and one pump. Adjust the installation procedure as
applicable to accommodate the number of syringes and pumps in the instrument.
3.1 Installation guidelines
· This instrument is for indoor use only. · The mains plug must be easily
accessible so the power can be disconnected quickly
in case of emergency. · Protective earth ground (PE) connection is required. ·
Keep the instrument away from temperature extremes, including heaters, direct
sunlight and other heat sources. · Put the instrument on a stable and level
surface in a well ventilated place. · Make sure that there is at least 15 cm
(6 in.) of space on all sides of the instrument to
prevent electrical parts from overheating. · Do not operate or keep the
instrument in dusty, damp or wet locations. · Always keep the surface of the
instrument and all accessories dry and clean.
3.2 Connect to AC power
CAUTION
Electrical shock and fire hazards. Make sure that the supplied cord and non-
locking plug meet the applicable country code requirements.
WARNING
Fire hazard. Use only the external power supply that is specified for this
instrument.
WARNING
Electrocution hazard. Protective Earth Ground (PE) connection is required.
11
Installation
1. Connect the power cord to the power supply. 2. Connect the power supply to
the instrument (refer to Instrument connections
on page 8). 3. Connect the power cord to an electrical outlet.
3.3 Install the syringe
Before syringe installation, set the instrument power to on. Push the power
button on the front of the instrument. Make sure that the startup sequence
shows on the display. The syringe holder lowers to its operating position.
Note: Ignore any warning messages related to missing applications that show on
the display. The sensor holder has two positions: one over the magnetic
stirrer and the second at 180° to the right. Move the sensor holder away from
the instrument to the second position. Refer to the illustrated steps that
follow.
CAUTION
In step 6, tighten the syringe using the metallic part at the top. Do not hold
the glass section of the syringe. Do not tighten too much. To install a second
syringe, do steps 5 through 7 again.
12
Installation
3.4 Install the sensor storage tubes
Put the three sensor storage tubes into the holder that is on the side of the
instrument (refer to Product overview on page 7). Keep the sensor in a storage
tube when not in use.
3.5 Install the stir bar and the beaker
Add the stir bar to the beaker, and then attach the beaker to the sensor
holder.
3.6 Prepare the tubes
Remove any bends in the end of the tubes. 13
Installation
3.7 Connect the tubes
Arrow symbols identify the inlet and outlet ports for the syringe and the pump
connections. The “up” arrow is the outlet port. The “down” arrow is the inlet
port. Turn the tube connectors on the inlet and outlet ports of the syringe
and pump until they click. The syringe outlet tube has a blue ring on it. If
anti-diffusion tips are necessary, remove the pre-installed outlet tube from
the syringe and install the tube from the application kit with the pre-
installed anti-diffusion tip. Push the outlet tubes into the tube holder slots
so that they are correctly attached.
3.8 Install the sensor
3.8.1 Install the legacy adapter
Go to Connect the sensor on page 15 if no legacy adapter is included in the
application kit. 1. Connect the measuring, reference and temperature sensors
to the legacy adapter. 2. Make sure that the instrument display shows the Home
screen. Connect the legacy
adapter cable to a sensor socket on the rear panel of the instrument.
14
Installation
1 Temperature sensor
2 Reference sensor
3 Measuring sensor
3. The legacy adapter commissioning wizard automatically starts. Follow the instructions that show on the display. Select the parameter based on the connected sensor.
Option
Description
pH
Select this parameter if the connected sensor is a pH analogic sensor.
Metal/RedOX/Color Select this parameter if the connected sensor is a Pt-Pt (metallic) analogic sensor or PTM450/OPT300 sensor.
ISE
Select this parameter if the connected sensor is an ion selective
sensor.
Refer to the application documentation to enter the related information for the selected parameter.
3.8.1.1 Set the legacy adapter settings Do the steps that follow to set a
sensor name in the legacy adapter settings or set the
legacy adapter settings.
1. Make sure that the legacy adapter is connected to the instrument.
2. From the home screen, select Settings>Legacy settings and then push
Select.
3. If more than one legacy adapter is connected, select the legacy adapter to
change the settings.
4. Select an option2. Refer to the application notes for additional
information.
Option Input sensor name
Input manual temperature Input pHIso Reset settings
Description
Enters the name of the sensor used. If specified, follow the recommendations
on the application notes for the sensor name.
Sets the temperature used in the titration if no temperature sensor is
connected.
(pH parameter only) Sets the pH ISO value (default=7).
Sets the legacy adapter settings to the default configuration. Starts the
legacy adapter commissioning wizard.
3.8.2 Connect the sensor
Use a conical adapter to hold the sensor tightly in the sensor holder.
2 The options shown are based on the parameter selected on the legacy adapter commisioning wizard. 15
Installation
Connect the sensor to an available sensor port on the rear of the instrument.
After the sensor is connected, make sure that the sensor icon shows in the
banner at the top of the display.
NOTICE
Make sure that the sensor tip is 5 to 10 mm above the top of the magnetic stir
bar to prevent any contact with the bar during operation.
Refer to the illustrated steps that follow.
3.9 Install the titrant and the reagent
CAUTION
Chemical exposure hazard. Obey laboratory safety procedures and wear all of
the personal protective equipment appropriate to the chemicals that are
handled. Refer to the current safety data sheets (MSDS/SDS) for safety
protocols.
16
Installation
CAUTION
Chemical exposure hazard. Dispose of chemicals and wastes in accordance with
local, regional and national regulations.
NOTICE
This is only applicable to instruments with two syringes installed. It is
recommended to install the applications (refer to Install the applications on
page 30) before installing the titrant. Applications using titrant from
syringe 1 are loaded on line 1 of the home screen (refer to Home screen on
page 25) and applications using titrant from syringe 2 are loaded on line 2.
After the applications are installed, the correct titrant can be connected to
the applicable syringe. Optional: Fill a desiccant cartridge with an
applicable desiccant. Put the desiccant cartridge into the adapter on the
titrant bottle cap. Refer to the illustrated steps that follow, step 1. Loosen
the tube connector on the bottle cap. Push the inlet tube through the
connector. Make sure that the end of the tube is at the bottom of the bottle.
Tighten the connector on the bottle cap. Use the same procedure to connect the
second titrant bottle if a second syringe is installed on the instrument.
Refer to the “Application Note” on the USB applications key to identify the
correct pump to connect to the reagent bottle. Refer to the illustrated steps
that follow.
17
Installation
3.10 Tidy the work area
Attach the tubes to the instrument with the clips on the electrovalve and the
sensor holder. Refer to the illustrated steps that follow.
18
Section 4 Install accessories
4.1 Install an external pump
Table 3 External pump specifications (subject to change without notice)
Specification
Details
Dimensions (W x D x H)
11.4 x 11.4 x 10.0 cm (4.49 x 4.49 x 3.94 in.)
Weight
280 g (0.62 lb)
Power requirements
12 VDC, 0.40.54 A
Altitude
2,000 m (6,562 ft) maximum
Operating temperature
15 to 35 °C (59 to 95 °F)
Relative humidity
20 to 80%, non-condensing
Storage temperature
5 to 40 °C (23 to 104 °F)
Installation category
II
Pollution degree
2
Certifications
EMC IEC/EN 61326-1
Warranty
1 year (EU: 2 years)
NOTICE
The manufacturer is not responsible for any damages due to misapplication or
misuse of this product including, without limitation, direct, incidental and
consequential damages, and disclaims such damages to the full extent permitted
under applicable law. The user is solely responsible to identify critical
application risks and install appropriate mechanisms to protect processes
during a possible equipment malfunction.
Please read this entire section before unpacking, setting up or operating this
equipment. Pay attention to all danger and caution statements. Failure to do
so could result in serious injury to the operator or damage to the equipment.
Make sure that the protection provided by this equipment is not impaired. Do
not use or install this equipment in any manner other than that specified in
this manual.
Read all labels and tags attached to the equipment. Personal injury or damage
to the equipment could occur if not observed. A symbol on the equipment is
referenced in the manual with a precautionary statement.
Electrical equipment marked with this symbol may not be disposed of in
European domestic or public disposal systems. Return old or end-of-life
equipment to the manufacturer for disposal at no charge to the user.
Products marked with this symbol indicates that the product contains toxic or hazardous substances or elements. The number inside the symbol indicates the environmental protection use period in years.
This accessory (item no. LZE142) is used to remove any excess sample from the
beaker to control the volume of sample before titration. The inlet and outlet
tubes are preinstalled on the pump. Make sure that the tube from the outlet
port of the pump is installed in an applicable liquid waste container. A blue
tag is attached to the inlet tubes that extract the liquid from the beaker.
To install the pump, refer to the illustrated steps that follow. After
installation, check that the pump and tubes are correctly installed by
selecting Maintenance > Pump activation from the instrument home screen (refer
to Pump activation on page 43).
19
Install accessories
To adjust the height of the tube in the sample, unscrew the top of the fitting
and slide the metal tube up or down to the required height before retightening
the fitting. Refer to Figure 3. 20
Figure 3 Tube adjustment
Install accessories
4.2 Install an external propeller
This accessory (Item no. LZE143) is used as an alternative to the standard
magnetic stir bar, for more viscous samples.
1. Install the propeller into the slot in the middle of the sensor holder. 2.
Connect the propeller to the external propeller port on the rear of the
instrument (refer
to Instrument connections on page 8). 3. From the home screen, select
Settings>Options. Set the option Propeller Stirrer.
Note: Push the up and down arrow keys to highlight the option. Push the left
arrow to set the option ON/OFF then push Done to confirm.
4.3 Install a balance
This accessory is used to automatically send accurate weights to the
instrument. The balance is a laboratory type balance and uses the RS232
communication protocol with no flow control. When a balance is connected, the
window shown at the end of a titration that lets users enter a weight, shows
the value from the balance. The balance automatically sends the weight and
unit to the instrument in textual format:
· Messages end with
1. Set the RS232 parameters on the balance to:
· 9600 baud · no parity · no handshake · 8 data bits · 1 stop bit 2. Connect
the balance to the serial port on the rear of the instrument (refer to
Instrument connections on page 8) using an applicable cable. 3. From the home
screen, select Settings > Options and make sure that the Balance option is
checked.
21
Install accessories
4.4 Install PC software
The optional PC software connects with the TitraLab® workstation through an
Ethernet network. The software can be used to: · Control a TitraLab®
workstation to start and stop analyses · Control a sample changer to start and
stop analyses · Control a balance for accurate sample weighing · Show run-time
data directly from the workstation · Manage data stored locally or on a server
(search, compare, delete, print, etc.) · Export data to files for use in other
software applications
Full product documentation and on-line help is available with the software.
4.5 Install the syringe verification kit
The optional syringe verification kit enables the verification of the
dispensing system based on the ISO8655 standard. The test adds different
volumes of liquid on a vessel put on a balance. The weights are used to
calculate the real volume added. The real volume is compared with the nominal
volume. The results are used to calculate the error in the volume added and
the syringe precision. There are three verification modes available:
· Fully automated–The balance is connected to the instrument. The system makes
the additions and calculates the results.
· Partially automated–The balance is not connected to the instrument. The user
does the balance readings and the system calculates the results.
· Dispense only–The system only makes the additions. The user does the balance
readings and calculates the results.
The syringe verification kit includes all of the necessary items: dispensing
tips, tubes, syringe holder, pipette holder, support stand, software key and
label with the license number. Make sure to keep the label with the license
number. A license key is necessary to enable the syringe verification option
on the instrument. The first time the option is selected, the instrument shows
the MAC address and the Firmware version. Send the MAC address, firmware
version and the license number to the manufacturer or a sales representative
to get the license key. Note: The license key is only necessary when the
option is selected for the first time. Items to collect:
· Analytical balance with resolution 0.1 mg, repeatability 0.2 mg and
uncertainty 0.2 mg · Temperature sensor · Deionized water “quality 3” (ISO
3696)
Prepare the syringe verification kit as follows:
1. Put an empty beaker on the balance. Refer to the illustrated steps that
follow. 2. For the fully automated mode, connect the balance to the
instrument. 3. Install the support stand near the balance. Put the pipette tip
adapter above the
beaker on the balance. 4. Connect the tube from the pipette holder to the
syringe outlet port. 5. Connect the tube from the water bottle to the syringe
inlet port. 6. On the instrument, manually enter the temperature. As an
alternative, connect and
put a temperature sensor on the water bottle to get the temperature
automatically. Note: The temperature setting is necessary for the fully
automated and partially automated modes. The dispense only mode does not
adjust the temperature.
22
Install accessories
23
Install accessories
24
Section 5 User interface and navigation
5.1 Keypad
1 Power 2 Printer Key Power Printer
Selection keys (contextual) Navigation keys
Home
3 Selection keys 4 Navigation keys
5 Home key
Description
Sets the instrument power to on or off. Push the key for 2 seconds to set the
power to off.
The printer key only operates if a printer is connected to the instrument.
Sends the data currently shown on the display to a connected printer when
pushed. A sound is heard if the current display cannot be printed. A graph is
automatically printed at the end of the measurement, if the option is selected
(Settings > Options).
Used to select options shown above them in the footer bar. The options
available are applicable to the current operation (e.g. calibration,
measurement, etc.).
Scrolls through menus and data, enter numbers and letters, enter checkbox
settings and set options for the syringe and the pump.
Push this key at any time to go directly to the home screen. A sound is heard
if the key is disabled (e.g. during a calibration or measurement).
5.2 Home screen
1 Available options from this screen
2 If two syringes are installed, shows applications for syringe 2
5 Screen name 6 Information icons (refer to Table 4)
3 Applications for syringe 1 4 Screen icon
7 Option available by pushing the selection key below 8 Arrow keys available for use in the screen
Table 4 shows the information icons that can be shown in the header bar.
25
User interface and navigation
Icon Description
Table 4 Information icons
A printer is connected to the instrument
A USB key is connected to the instrument
A sensor is connected to sensor port 1
A sensor is connected to sensor port 2
The data log file is full. Refer to Manage the data log on page 39 for the options available to manage the data log file.
A measurement is in operation using the PC software. The keyboard is locked.
5.3 Menu structure
Option
The three primary menus are shown in Table 5, Table 6 and Table 7. Table 5
Home menu
Description
Data log
Manage the data log file
Calibration
Electrode and titrant calibration procedures
Settings
See the table entry below
Maintenance
See the table entry below
Purge Option
Applications
Remove air from the syringe, and from the syringe and pump tubes
Table 6 Settings menu Description Manage the installed applications
Operators Date & Time
Set up and manage the instrument operators Set the date and time
26
Option Brightness
User interface and navigation
Table 6 Settings menu (continued) Description
Adjust the display brightness
Sounds
Set the sound on or off for specific operations
Language
Set the operating language
Network
Give a name to identify the instrument
Legacy settings
Specify the legacy sensor data
Show instrument and attached hardware information Info
Restore defaults
Set the instrument to the default configuration
Options
Set the operating parameters
Security Option
Syringe activation
Set a password and specify which options are password protected
Table 7 Maintenance menu Description Make sure that the syringe is working
correctly
Pump activation
Make sure that the pump is working correctly
Stirring activation
Make sure that the stirrer is working correctly
Live measure
Quickly check measurement data for connected sensors. Not available for all sensors
Syringe management
Replace the syringe or change the syringe volume
27
User interface and navigation
Option
Table 7 Maintenance menu (continued) Description
Replace the pump cassette for installed pumps Pump cassette replacement
Reagent replacement
Use this option when replacing reagents
Maintenance schedule Maintenance summary
Manage the maintenance tasks
See the number of days remaining on specified devices before maintenance is
required
Syringe verification
When enabled, starts the syringe verification procedure.
28
Section 6 Startup
CAUTION
Chemical exposure hazard. Obey laboratory safety procedures and wear all of
the personal protective equipment appropriate to the chemicals that are
handled. Refer to the current safety data sheets (MSDS/SDS) for safety
protocols.
CAUTION
Chemical exposure hazard. Dispose of chemicals and wastes in accordance with
local, regional and national regulations.
CAUTION
Personal injury hazard. Never use the instrument without the syringe cover
installed.
6.1 Configure the instrument
1. From the home screen, select Settings. Refer also to Menu structure on page 26. 2. Select an option, then push Select.
Option Applications
Operators Date + Time Brightness Sounds Language Network
Description
Changes (refer to Change the application settings on page 38), makes copies,
exports and removes application data. Make sure that the duplication function
does not make more than five applications for each syringe installed.
Adds, changes and removes operators.
Sets the instrument date and time.
Sets the brightness of the display.
Sets the sound options.
Sets the language.
Give a name to the instrument. This name is used to connect the instrument to
a PC. If a printer is connected, this name is printed on the hard-copy output.
Restart the instrument if the name is changed.
Legacy settings Specify the sensor data when the legacy adapter is used.
Info
Shows information about the instrument and the attached hardware.
Restore Defaults
Sets the instrument to the default configuration. The restored settings are:
· The language is set to English · All password security is removed · The
security password is set to 0000 · No sound on: Key press, Information and
Analysis results OK · Sound on: Instrument ready, Instrument switch off,
Errors and
Analysis results not OK · The application parameters view is set to basic mode
· Sets the syringe to empty when the instrument is set to off · The
temperature display unit is set to °C · No print of the measurement curve · No
print of the derivative curves · No balance is connected · No propeller
stirrer is connected · The default stirring is set to 10% · The user is set to
“Default user”
29
Startup
Option Options
Security
3. Push Back.
Description
Sets the following options:
· Set the application parameters view to expert or basic mode · When the
instrument is set to off, sets the syringe to empty into the
titrant bottle · Changes the temperature display unit · Prints the measurement
and derivative curves if a printer is connected · Specify if a balance is
connected · Specify if an external propeller stirrer is connected.
Note: When the instrument is set to on, the application parameters view is
always set to basic mode. Changes made to application data with the instrument
in expert mode are kept.
Change the password. Specify which of these options are password protected:
· Settings (all items except Info) · Maintenance schedule and summary · Delete
data log · Export data log · Electrode calibration · Titrant calibration ·
Sample volume calibration · Syringe verification test
6.2 Install the applications
Use the supplied USB key to install the applications. The instrument can
install a maximum of five applications for each syringe installed. For two
syringes, the installed applications shown on the top line of the display
refer to syringe one and the installed applications shown on the second line
refer to syringe two.
If any errors occur during installation, refer to Troubleshooting on page 49.
1. Push Home to go to the main menu. 2. Connect the USB key to the USB port
on the side of the instrument. The applications
on the USB key show on the display.
3. Push the arrow keys to highlight and select an application to install.
Push the left or right arrow key to select it. Do this step again to select
additional applications to install.
4. Push Import to install the selected applications. 5. Push OK to complete
the installation. The installed applications show on the home
screen. Note: To install more applications, push Home to go to the home
screen, then remove the USB key and reconnect it.
6.3 Prepare the instrument for measurement
1. From the home screen, select Purge. All attached devices are listed. 2.
Select All elements to purge all the attached devices, or select one device to
purge.
Push Select. Air is removed from the device and filled with liquid from the
bottle. 3. Push OK when the operation has completed. 4. Make sure that there
are no air bubbles in the device. Do step 2 again if there are any
air bubbles.
30
Startup
5. Select the next device to purge if individual devices are being selected.
6. Push Exit when all the tubes are filled with reagent and the device has no
air
bubbles. Note: If a few small air bubbles can be seen on the inner wall and/or
piston of the syringe, they can be left without effecting system performance.
31
Startup
32
Section 7 Standard operations
CAUTION
Multiple hazards. Only qualified personnel must conduct the tasks described in
this section of the document.
CAUTION
Chemical exposure hazard. Obey laboratory safety procedures and wear all of
the personal protective equipment appropriate to the chemicals that are
handled. Refer to the current safety data sheets (MSDS/SDS) for safety
protocols.
CAUTION
Chemical exposure hazard. Dispose of chemicals and wastes in accordance with
local, regional and national regulations.
CAUTION
Personal injury hazard. Never use the instrument without the syringe
protection cover in place.
CAUTION
Chemical exposure hazard. Never remove the stir bar from the beaker before the
end of a titration.
7.1 Calibration
7.1.1 Calibrate the sensor
1. From the home screen, select Calibration, then push Electrode calibration.
2. If more than one sensor is installed, push the up and down arrow keys to
highlight the sensor to use, then push Select.
3. If more than one application includes calibration parameters for the
sensor, push the up and down arrow keys to highlight the application to use,
then push Select. Calibration information shows on the display.
4. If necessary, select an icon for more information or to change some data.
Option
Description
Electrode
Shows more information about the sensor.
Operator
Changes the operator ID. Select from a list of applicable operators.
Buffer or Standard Shows more information about the buffer set or standard.
5. Do the instructions that show on the display, then push Start to start the
calibration. Calibration data shows on the display.
6. If the default stirring speed needs to be adjusted, push the up and down
arrow keys to increase or decrease the speed. Note: This adjustment only
applies to the current operation. The standard default stirring speed for the
calibration is not changed.
7. Select Stop at any time to stop the calibration. Results are then
calculated from the calibration data available before Stop is selected.
33
Standard operations
8. For pH sensors only:
Option Description
Yes Continue with the next calibration buffer solution in the sequence.
No
Stop the calibration. The calibration can still be validated if at least one buffer
calibration was successful.
9. When the calibration is complete, push the left and right arrow keys to
see the different measurement views.
10. Push Reject or Validate.
Option Reject
Description
Select Cancel to go back to the result display or Confirm to reject the
calibration and use the default or previous calibration value.
Validate The calibration is accepted and the new values stored.
7.1.2 Calibrate the titrant
1. From the home screen, select Calibration, then push Titrant calibration.
2. If more than one titrant is installed, push the up and down arrow keys to
highlight the titrant to calibrate, then push Select.
3. If more than one application contains a titrant calibration method, push
the up and down arrow keys to highlight the application to use, then push
Select.
4. Calibration information shows on the display. If necessary, select an icon
for more information or to change some data.
Option
Description
Information Shows more information about the calibration.
Operator
Changes the operator ID. Select from a list of applicable operators.
5. Fill a beaker with the recommended standard amount that shows on the
display. If necessary, add more of the solvent specified in the application
note until the sensor is correctly installed in the sample.
6. Carefully put a magnetic stir bar into the beaker. Make sure there is no
liquid spill.
7. Attach the beaker to the sensor holder.
8. Make sure that the icon at the bottom of the display is highlighted. Do
the instructions that show on the display adjacent to this icon. Refer to
Connect the sensor on page 15 to make sure that the tubes and sensor are
correctly aligned.
9. Push Start to start the calibration. Calibration data shows on the
display.
10. If the default stirring speed needs to be adjusted, push the up and down
arrow keys to increase or decrease the speed. Note: This adjustment only
applies to the current operation. The standard default stirring speed for the
application is not changed.
34
Standard operations
11. Two options are available during the procedure:
Option Description
Stop Aborts the calibration and no results are calculated. If selected during the Replicate Sample option, then all data in the series is lost.
Skip
Stops the current operation and goes directly to the next step in the procedure. Results are then calculated from calibration data available before Skip is selected. Results can be less accurate using this option.
12. Push Reject or Continue.
Option Description
Reject
Rejects the calibration. Select Cancel to go back to the result display or Confirm to reject the calibration. If this is the first calibration, select Confirm to reject the calibration and use the default or previous calibration values. If this is a Replicate Standard calibration, select Confirm to reject only the current calibration in the series.
Continue Select from one of these options:
· Replicate Standard: Do the calibration again using the same standard
· Save & Exit: Keep the calibration results and exit the calibration procedure
· Reject & Exit: Reject the calibration results and use the default or
previous calibration values, and exit the calibration procedure
7.1.3 Auto leveling calibration
This option is only available when at least one installed application contains
an auto leveling calibration method and the method is set to active. The
calibration makes sure that the sample volume in the measurement cell is the
same before each titration.
An external pump must be installed for this procedure.
1. From the home screen, select Calibration, then push Autoleveling
calibration.
2. If more than one application contains an auto leveling calibration method,
push the up and down arrow keys to highlight the application to use, then push
Select.
3. Calibration information shows on the display. If necessary, select an icon
for more information or to change some data.
Option
Description
Information Shows more information about the calibration.
Operator
Changes the operator ID. Select from a list of applicable operators.
4. Make sure that the external pump and tubes are correctly installed (refer
to Install an external pump on page 19).
5. Make sure that the sensor, tubes and stir bar are correctly installed in
an empty beaker, as if preparing for a standard measurement.
6. Accurately measure the necessary volume of sample and pour it into the
empty beaker.
7. Adjust the position of the tube from the external pump (refer to Figure 3
on page 21) so that it touches the surface of the liquid. Then add more sample
until the end of the tube is immersed in 5 to 10 mm of the liquid.
8. Push Start to start the calibration.
9. The leveling procedure starts and sample is removed for the preset time.
Make sure that this time is large enough for all the necessary sample to be
removed and for air to be removed for some seconds at the end.
35
Standard operations
10. The titration measurement starts after the leveling procedure completes.
If the default stirring speed needs to be adjusted, push the up and down arrow
keys to increase or decrease the speed. Note: This adjustment only applies to
the current operation. The standard default stirring speed for the calibration
is not changed.
11. Two options are available during the calibration procedure:
Option Description
Stop Aborts the calibration and no results are calculated. If selected during
a Replicate Standard calibration, then all data in the series is lost.
Skip Stops the leveling operation and goes directly to the next step in the
procedure. Results are then calculated from the data available before Skip is
selected.
12. When the calibration is complete, push the left and right arrow keys to
see the different measurement views. The result of the titration is the
calculated volume of sample.
13. Push Reject or Continue.
Option Description
Reject
Rejects the calibration. Select Cancel to go back to the result display or Confirm to reject the calibration. If this is the first calibration, select Confirm to reject the calibration and use the default or previous calibration values. If this is a Replicate Standard calibration, select Confirm to reject only the current calibration in the series.
Continue Select from one of these options:
· Replicate Standard: Do the calibration again using the same sample
· Save & Exit: Keep the calibration results and exit the calibration procedure
· Reject & Exit: Reject the calibration results and use the default or
previous calibration values, and exit the calibration procedure
14. If the calibration is successful, the calculated volume of sample is kept
in the application parameters. This value is shown in the measurement start
view for that
application and is used in the next titration calculations of the application.
7.2 Sample preparation
When this application is installed (refer to Install the applications on page
30), use it to prepare one or more measurement samples. Note: If the PC
software is installed (refer to Install PC software on page 22) and the AS1000
sample changer is installed, sample preparation can be done with or without
leveling. But if the sample preparation is done without the software and
sample changer, then leveling must be deactivated (Active = No). It is
recommended to read the related “Application Note” from the USB applications
key for more instructions.
1. From the home screen, select the sample preparation application, then push
Select. 2. Make sure that the reagent used to prepare the sample is installed
with the correct
pump. Note: The application parameters can be changed in basic or expert mode.
Refer to Change the application settings on page 38. 3. Obey the instructions
on the display. 4. Push Next to prepare more samples or Exit to go back to the
home screen.
7.3 Get a sample measurement
Use this option to get sample measurements with one of the installed
applications.
36
Standard operations
1. From the home screen, select the measurement application, then push
Select. Application information shows on the display.
2. Read the related “Application Note” from the USB applications key for more
instructions.
3. If necessary, select an icon for more information or to change some data.
Option
Description
Information Shows more information about the application.
Operator Changes the operator ID. Select from a list of applicable operators.
Sample
Sample Name: Change the specified name of the sample.
Type: Push the left and right arrow keys and select the sample type (Sample,
QC or Define blank) to be used for the measurement. If Define blank has been
selected before, two more sample types are available (QC with blank and Sample
with blank).
4. Fill a beaker with the recommended sample amount that shows on the
display. If necessary, add more of the solvent specified in the application
note until the sensor is correctly installed in the sample.
5. Carefully put a magnetic stir bar into the beaker. Make sure there is no
liquid spill.
6. Attach the beaker to the sensor holder.
7. Make sure that the icon at the bottom of the display is highlighted. Do
the instructions that show on the display adjacent to this icon. Refer to
Connect the sensor on page 15 to make sure that the tubes and sensor are
correctly aligned.
8. Push Start to start the measurement. Measurement data shows on the
display.
9. If the default stirring speed needs to be adjusted, push the up and down
arrow keys to increase or decrease the speed. Note: This adjustment only
applies to the current operation. The standard default stirring speed for the
application is not changed.
10. Two options are available during the procedure:
Option Description
Stop Aborts the measurement and no results are calculated. If selected during the Replicate Sample option, then all data in the series is lost.
Skip
Stops the current operation and goes directly to the next step in the procedure. Results are then calculated from measurement data available before Skip is selected. Results can be less accurate using this option.
11. When the measurement is complete, push the arrow keys to see the
different measurement views.
12. Push Next for these options:
Option
Replicate Sample
Description
Use this option to start the same titration on the same sample. This is used
to study the repeatability by successively analyzing several parts of the same
sample. At the end of each measurement, a window shows the average value, the
standard deviation and the relative standard deviation.
New Sample Use this option to start the same titration on a new sample. No standard deviation or relative standard deviation measurements will be done.
13. Push Exit to go back to the home screen.
37
Standard operations
7.4 Change the application settings
NOTICE
The applications installed on the instrument have been pre-defined to optimize
the measurement process. Changing these default application parameters will
have an effect on the measurement process and measurement results. Only
qualified personnel should change these parameters or use the instrument in
Expert mode. Refer to the application note before changing any parameters.
NOTICE
In Basic mode changes to parameters are secure. In Expert mode changes to
parameters are not secure and can cause the application to run incorrectly.
Refer to Change application parameters on page 63 for a list of parameters
that can be changed in basic and expert mode. Refer to Sample name on page 38
for special features on the sample name.
1. From the home screen, select Settings. 2. Select Applications followed by
Edit. 3. If more than one application is installed, choose an application to
change from the
installed list and then push Edit. 4. Push the left and right arrow keys to
jump to the previous or next parameter group.
Push the up and down arrow keys to scroll through the application parameters
in the parameter group. 5. The Edit key is only available when a parameter can
be changed. Push Edit to change the parameter. Enter the new details or select
from a list. Note: A description of the selected parameter is shown on the
bottom of the display.
7.4.1 Sample name
The two wildcard characters ? (question mark) and (asterisk) can be used to
automatically increment the sample name. Use the question mark character to
increment the name using an integer. For example, where Water is the name of
the sample:
· Select Settings > Applications > Edit and change the sample name to Water ?
· The sample name for the first measurement is Water 1 · The sample name for
the next measurement is Water 2, etc. · The integer value is always set back
to 1 when the instrument is set to off
Use the asterisk character in the name to increment the name using the
instrument date and time in YYMMDDHHMMSS format. For example, where Water is
the name of the sample:
· Select Settings > Applications > Edit and change the sample name to Water
· The sample name for the first measurement made on 27th February 2015 at
15:30:25 is Water 150227153025 · The sample name for the next measurement made
on 28th February 2015 at
16:32:47 is Water 150228163247, etc. · The value is not reset when the
instrument is set to off
Use both characters in the name to increment the name using an integer and the
instrument date and time. For example, where Water is the name of the sample:
· Select Settings > Applications > Edit and change the sample name to Water ?
- · The sample name for the first measurement made on 27th February 2015 at
15:30:25 is Water 1 150227153025
38
Standard operations
· The sample name for the next measurement made on 27th February 2015 at
17:01:27 is Water 2 150227170127, etc.
· The integer value is always set back to 1 when the instrument is set to off
7.5 Manage the data log
To select data to view, delete or export, specify data filters
1. From the home screen, select Data log. 2. Select an option, then push Select.
Option
Description
View data log Views measurement data. Select individual lines of data to view more content.
Export data log Exports measurement data from the system to an external device. Preview data selection before it is exported. Make sure that an external device is connected to the instrument (e.g., a USB key, external hard drive, etc.).
Delete data log Removes measurement data from the system. Previews data selection before it is removed.
3. Specify the data selection parameters. Push the left and right arrow keys to make a selection. Push the up and down arrow keys to select an option.
Option
Description
Result type
Sets the type of result available.
Application
Sets the available applications.
Date
Sets the date range.
Operator
Sets the available operators.
4. If View data log was the selected option, push View to see the selected data.
· Push the up and down arrow keys to select a line of data and push Detail to
see more data
· If Electrode calibration is selected as the Result type, push the left and
right arrow keys to select the sensor if more than one sensor is installed.
Push the up and down arrow keys to select a line of data, then push the left
and right arrow keys to see related graphs
· If only one Application is selected push the up and down arrow keys to
select a line of data and push Detail to see more data, or push the left and
right arrow keys to see related graphs
5. If Export data log or Delete data log was the selected option, push
Preview to see the selected data, then push Export or Delete to start the
procedure.
7.6 Purge
Use this procedure to remove air bubbles from the system. Refer to Prepare the instrument for measurement on page 30 for instructions.
39
Standard operations
40
Section 8 Maintenance
CAUTION
Multiple hazards. Only qualified personnel must conduct the tasks described in
this section of the document.
NOTICE
Do not disassemble the instrument for maintenance. If the internal components
must be cleaned or repaired, contact the manufacturer.
8.1 Maintenance schedule
Table 8 shows the recommended schedule of maintenance tasks. Facility requirements and operating conditions may increase the frequency of some tasks.
Table 8 Maintenance schedule
Task
1 day 7 days 12 months
Clean the instrument on page 41. Also do this procedure immediately after any liquid spills on the instrument.
x
Clean the sensor on page 41.
x
If applicable, Replace desiccant cartridge contents on page 42.
x
Replace the syringe. Refer to Syringe management on page 43.
x
Replace syringe electro-valve block. Refer to Replace the syringe electro- valve block on page 42.
x
Examine the syringe connections and inlet and outlet tubes for leaks and damage. Replace as
necessary. Refer to Replacement parts and accessories on page 57 for part numbers and to
x
Replace the tubes on page 42.
Replace the pump cassettes. Refer to Pump cassette replacement on page 44.
x
Examine the pump connections and inlet and outlet tubes for leaks and damage. Replace as
necessary. Refer to Replacement parts and accessories on page 57 for part numbers and to
x
Replace the tubes on page 42.
Examine the bottle caps and connections for leaks and damage. Replace as necessary. Refer to Replacement parts and accessories on page 57 for part numbers.
x
8.2 Clean the instrument
NOTICE
Never use flammable or corrosive solvents to clean any part of the instrument.
Use of these solvents can degrade the environmental protection of the
instrument and may void the warranty.
Clean the exterior surface with a moist cloth or with a mixture of water and
mild detergent. Dry with a soft cloth.
8.3 Clean the sensor
Obey the cleaning instructions given in the documentation supplied with the
sensor, and any other instructions given in the application note.
41
Maintenance
8.4 Replace the tubes
After installing a new tube, make sure that it is correctly installed by
turning the tube connectors on the inlet and outlet ports of the syringe or
pump until they click. Refer also to Connect the tubes on page 14.
8.5 Replace desiccant cartridge contents
When used, it is recommended to replace the desiccant cartridge contents
weekly, but this will vary depending on the humidity of the laboratory. A
humidity indicator, such as color changing silica gel crystal, can be used to
show when replacement is necessary.
8.6 Replace the syringe electro-valve block
DANGER
Electrocution hazard. Remove power from the instrument before this procedure
is started.
NOTICE
It is recommended that this procedure is only done by a qualified service
engineer. Refer to the illustrated steps that follow.
8.7 Maintenance menu
Select Maintenance from the home screen. 42
Maintenance
Refer also to Table 7 on page 27.
8.7.1 Syringe activation
Do a check of the syringe. Make sure the syringe fills and empties correctly.
1. From the maintenance menu, push Syringe activation. Push the arrow keys to select an option.
Option
Description
Fill
Fills the syringe with titrant solution. The process stops automatically when
the syringe is full.
Empty to bottle Discards the contents of the syringe into the titrant bottle.
Empty to beaker Discards the contents of the syringe into the beaker. Make sure that the tube from the outlet port of the syringe is inside the beaker.
Stop
Stops the operation.
If a second syringe is installed, the Toggle option is shown on the display.
Push Toggle to change to the second syringe, or to operate both syringes.
8.7.2 Pump activation
This option only applies to instruments with pumps installed. Do a check of
the pump. Make sure the pump fills and empties correctly.
1. From the maintenance menu, push Pump activation. Push the up and down
arrow keys to select an option.
Option Description
Start Starts the pump. The reagent is pumped through the tubes into the
beaker. Make sure that the tube from the outlet port of the pump is in the
beaker.
Stop Stops the operation.
If more than one pump is installed, the Toggle option is shown on the display. Push Toggle to change to the second pump, to an external pump or to operate all pumps.
8.7.3 Syringe management
Use this option to replace the syringe, or change the syringe volume.
1. From the maintenance menu, push Syringe management.
Option Syringe replacement
Syringe volume change
Description
If two syringes are installed, select the syringe to replace. Select to
discard the contents of the syringe into the titrant bottle or the beaker, and
then obey the instructions on the display. Refer also to Install the syringe
on page 12 for the installation.
If two syringes are installed, select the syringe to change. Select the new
syringe volume.
8.7.4 Syringe verification
Use the syringe verification option to examine the syringe accuracy based on
the ISO 8655 standard. For the best results, follow the procedure in the
application note supplied with the syringe verification kit. Note: A license
key is necessary to enable the syringe verification option on the instrument.
Contact the manufacturer or a sales representative to get a license key.
1. From the home screen, select Settings, then push Select. 2. From the
settings screen, select Options, then push Select.
43
Maintenance
3. Push the left or right arrow key to select the expert mode, then push
Done.
4. From the home screen, select Maintenance, then push Select.
5. From the maintenance screen, select Syringe verification, then push
Select. Note: When the option is selected for the first time, enter the
license key.
6. Push the up and down button to select and change the syringe test options.
Option
Description
Syringe
Selects the syringe. Used when there are two syringes. Shows the syringe information: syringe number and volume.
Operator
Selects the operator ID
Configuration Sets the test settings: test volume and number of replicates. The total dispensed liquid for the test shows when the two parameters are set. Note: Make sure to use the applicable beaker and balance for the test based on the amount of total dispensed liquid.
A field to write the test conditions is available in the test conditions settings.
Start
Starts the syringe verification procedure.
7. Push Start to start the syringe verification procedure. Follow the
procedure supplied with the syringe verification kit.
8. To cancel the syringe verification test and not save data to the data log,
push Stop.
9. To cancel the syringe verification test and save the syringe verification
results for fully tested volumes to the data log, push Skip.
10. When the test is complete Pass or Fail shows. Push the left or right
arrow to show the results for the different volumes. Push the up and down
arrow to show more results data for the selected volume.
8.7.5 Pump cassette replacement
DANGER
Electrocution hazard. Remove power from the instrument before this procedure is started.
This option only applies to instruments with pumps installed.
44
Maintenance
To replace the pump cassette, refer to the illustrated steps that follow and
obey the instructions on the display.
8.7.6 Other maintenance options
1. Select an option, then push Select.
Option
Description
Stirring activation Do a check of the magnetic stirrer. Push the up and down arrow keys to increase or decrease the stirring speed.
45
Maintenance
Option Live measure
Reagent replacement Maintenance schedule Maintenance summary
Description
This option is not available for all sensors. The option shows continuous
measurement data with connected sensors to quickly check measurements. The
installed applications and the automatic additions to the sample are set to
off. Continuous measurements are not temperature compensated, so measurement
differences may occur in the same sample between continuous measurements and
measurements that use installed applications with temperature compensation.
Use this option to replace the reagents. Obey the instructions on the display.
See the list of maintenance tasks. Push Edit to change the default value.
See the number of days remaining for maintenance tasks. After doing a task,
push Reset to set the number of days remaining to the default value.
8.8 Storage and transportation
8.8.1 Prepare the instrument for storage
CAUTION
Chemical exposure hazard. Obey laboratory safety procedures and wear all of
the personal protective equipment appropriate to the chemicals that are
handled. Refer to the current safety data sheets (MSDS/SDS) for safety
protocols.
CAUTION
Chemical exposure hazard. Dispose of chemicals and wastes in accordance with
local, regional and national regulations.
1. Remove the sensor from the sensor holder and disconnect it from the sensor
port on the rear of the instrument.
2. Clean the sensor. Refer to Clean the sensor on page 41.
3. Put the sensor in a storage tube that contains a storage solution. Refer
to the sensor documentation for storage instructions.
4. From the home screen, select Maintenance > Syringe activation and empty
the contents of the syringe.
5. If a second syringe is installed, push Toggle to select it and empty the
contents.
6. Set the instrument power to off.
7. Carefully remove the tubes from the titrant bottle. If pumps are
installed, remove the tubes from the reagent bottles. Seal the bottles with
the original bottle cap.
8. Flush the tubes with water or an applicable cleaning solution (refer to
the application note for more information).
9. Drain the used beakers and clean with deionized water.
10. If storing the instrument for more than a week, remove the syringe from
the instrument (refer to Install the syringe on page 12). Flush the syringe
with water or an applicable cleaning solution and store in its box.
46
Maintenance 8.8.2 Prepare the instrument for short-term storage
CAUTION
Chemical exposure hazard. Obey laboratory safety procedures and wear all of
the personal protective equipment appropriate to the chemicals that are
handled. Refer to the current safety data sheets (MSDS/SDS) for safety
protocols.
CAUTION
Chemical exposure hazard. Dispose of chemicals and wastes in accordance with
local, regional and national regulations. Use this procedure if storing the
instrument overnight or over a weekend. 1. Carefully clean the measurement
cell using an applicable organic solvent to dissolve any residue and oil. 2.
Fill the measurement cell with a new working medium. 3. Add titrant to the
working medium until it becomes brown in color. 4. Check that the measurement
cell is tightly installed. 5. Check the position of all the elements in the
sensor holder. 6. Set the instrument power to off.
8.8.3 Prepare the instrument for shipment
1. Refer to Prepare the instrument for storage on page 46. 2. Put the
instrument and the necessary accessories in a package with all the packaging
materials. 3. Ship the instrument at a temperature 5 to 40 °C (23 to 104 °F)
and relative humidity
up to 80%. 4. Make sure that the storage location for the instrument does not
have dust,
condensation or chemical evaporation.
47
Maintenance
48
Section 9 Troubleshooting
Refer to the following tables for problem messages and possible causes and solutions.
Table 9 Measurement
Error/Warning
Description
Possible solution
Measurement unstable
The measurement from the sensor is not stable
Make sure that there are no bubbles around the sensor element or junction
Measurement out of range
The sample concentration is outside the sensor measurement limits
Adjust the sample preparation to be inside the sensor measurement range
Use a different sensor with a more applicable measurement range
Temperature out of range
The sample temperature is outside the sensor measurement limits
Adjust the sample temperature to be inside the sensor measurement range
Use a different sensor with a more applicable measurement range
Make sure that the sensor is operating correctly
Max. ordinate reached
The titration is stopped because the measured signal is above or below the ordinate stop point set for this application, depending on the curve direction
Refer to the application note for best practices and do the titration again
Adjust the maximum ordinate for the application (refer to Change application
parameters on page 63)
Below minimum range
This message is specific to amperometric applications; the equivalence point has not been found
Select an application range more adapted to the sample
Above maximum range
This message is specific to amperometric applications; the equivalence point has not been found
Select an application range more adapted to the sample
This message is specific to amperometric Insufficient curve resolution
applications; the equivalence point has not
been found
Refer to the application note for best practices and do the titration again
Clean the sensor using the recommended procedures in the sensor documentation
Not enough excess titrant
This message is specific to amperometric applications with back titration; the equivalence point has not been found
Refer to the application note for best practices and do the titration again
Check the excess titrant defined in the application file and adjust if
necessary or select an application range more adapted to the sample
Too much excess titrant
This message is specific to amperometric applications with back titration; the equivalence point has not been found
Refer to the application note for best practices and do the titration again
Check the excess titrant defined in the application file and adjust if
necessary or select an application range more adapted to the sample
Flat signal
The titration is stopped because the amount of sample is below the detectable limit of the application
Refer to the application note for best practices and do the titration again
Select an application range more adapted to the sample
Analysis skipped
The titration has been stopped manually by the user; the equivalence point has not been found
Preferably use an automatic end titration detection instead of a manual skip
49
Troubleshooting
Table 9 Measurement (continued)
Error/Warning
Description
Possible solution
Refer to the application note for best practices and do the titration again
Equiv. point not found
The titration fails to determine the equivalence point
Adjust the equivalence point detection value for the application (refer to Change application parameters on page 63)
Contact technical support
Out of range
The computed result is outside the accepted limits
Refer to the application note for best practices and do the titration again
Adjust the result minimum and maximum values for the application (refer to
Change application parameters on page 63)
Equation calc. error
An equation variable is unknown (e.g. the ordinate of the equivalence point is unknown or the volume of the equivalence point is unknown)
Make sure that all the equation variables are available (refer to the application note for the equation description and values)
A required electrode is not connected!
Application {application name}
Electrode: Type: {type}:
Name: {name}:
The applicable IntelliCAL electrode type for Connect the IntelliCAL electrode specified in the
the application is not connected.
application note.
The “Sensor name” set in the legacy adapter Change the “Sensor name” setting in the legacy
settings does not agree with application
adapter setting to agree with the sensor name
settings.
specified in the application note.
Electrode calibration has expired
A titration or titrant calibration has been done with an expired sensor calibration date
Calibrate the sensor and if necessary adjust the calibration frequency (refer to the application note for the recommended frequency)
Titrant calibration has expired
A titration has been done with an expired titrant calibration date
Calibrate the titrant and if necessary adjust the calibration frequency (refer to the application note for the recommended frequency)
The titrant used by an application has been modified and this application became incompatible with applications already installed. Please go to application management to solve the issue
The application data has been changed and the application cannot be used
Remove the application or change the titrant to a titrant that is already installed
System error
A system error causes the titration to stop (e.g. a sensor has been disconnected or the volume of reagent is too low)
Make sure that all the system elements are connected and working correctly (refer to Maintenance menu on page 42)
Max. vol. reached
Refer to the application note for best practices
The titration is stopped because the supplied and do the titration again
volume of reagent is more than the maximum Adjust the maximum volume stop point for the
quantity
application (refer to Change application
parameters on page 63)
No titrant information
There is no description of the titrant
Install the application again
50
Troubleshooting
Error/Warning
No measure received
The stirrer/propeller stirrer does not operate
Printer: communication error Burette fails to deliver Burette fails to fill
Burette failed to read delivered volume System failure
Table 9 Measurement (continued)
Description
Possible solution
Make sure that the sensor is correctly connected to the instrument
No measurement can be done
Disconnect the sensor and connect it again
Change the sensor if no measurement is received using the Live Measure option
(refer to Other maintenance options on page 45)
The stirrer (or the propeller stirrer) does not automatically start when the measurement starts.
Make sure that the stirrer configuration is set correctly. Identify if the applicable stirrer is selected in the Settings>Options menu.
The red LED on the printer flashes to show that the printer is in error mode. There is no paper in the printer.
Replace the paper roll in the printer. Refer to the printer documentation.
Syringe cannot deliver any reagent
Contact technical support
Syringe cannot be filled with reagent
Contact technical support
Syringe cannot calculate the delivered volume of reagent
Contact technical support
Operational failure
Contact technical support
Table 10 Calibration
Error/Warning
Description
Possible solution
Temperature variation too high
The variation in temperature is too high across all the calibration solutions when more than one is used
Make sure that the maximum temperature variation across all the calibration solutions is no more than 5 °C before starting a calibration
Temperature out of range
The temperature of the calibration solution is Make sure that the temperature of the calibration outside the specified temperature range for solution is inside the specified range before the buffer or standard used in the calibration starting a calibration
Calibration solution already The calibration solution has already been
used
used for a calibration
Use another calibration solution
Slope out of range
The pH sensor calibration slope is outside the accepted limits
Make sure that there are no bubbles around the sensor element or junction
Clean the sensor using the recommended procedures in the sensor documentation
Offset out of range
The pH sensor calibration offset is outside the accepted limits
Make sure that there are no bubbles around the sensor element or junction
Clean the sensor using the recommended procedures in the sensor documentation
Buffer value under electrode detection limit
The value of the calibration solution is less than the low limit for sensor detection
Use a calibration solution that is inside the sensor measurement range
Cell constant out of range
The calibration value of the cell constant is outside the accepted limits
Make sure that the cell constant minimum and maximum values are correct for the application and adjust them if incorrect (refer to Change application parameters on page 63)
The connected electrode cannot be calibrated or there is no application that contain calibration parameters
There is no installed application that contains calibration parameters, or the sensor is not a sensor that can be calibrated (e.g. PtPt or ORP sensors)
Make sure that at least one application that contains calibration parameters for the sensor has been installed, and that the sensor is a sensor that can be calibrated (e.g. pH or conductivity sensors)
51
Troubleshooting
Error/Warning No titrant to calibrate
Table 10 Calibration (continued)
Description
Possible solution
There is no method to calibrate the titrant into the application. If more than one application is installed, there is no method to calibrate the titrant into all the applications.
The titrant cannot be calibrated with the current application. Refer to the related application note to find if the titrant calibration is available.
The titrant calibration has been deactivated (Basic or Expert mode: Active = No)
Activate the titrant calibration (Active = Yes)
Table 11 USB storage device
Error/Warning
Description
Possible solution
Exporting {application name} access forbidden to the applications folder on USB flash drive
Error when exporting data to the USB storage device
Make sure that the USB storage device is correctly installed and the USB icon
can be seen in the header bar (refer to Table 4 on page 26)
Remove the USB storage device and make sure the USB icon is no longer seen in
the header bar, then install the device again and make sure that the icon can
be seen (refer to Table 4 on page 26)
Exporting {application name} read only access to the applications folder on USB flash drive
The USB storage device is read only
Unlock the storage device or use another one
Exporting {application name} error during writing. Verify USB flash drive is not full
Error when exporting data to the USB storage device
Make sure that the USB storage device has enough available space or use another one
USB flash drive is not installed. Install and export applications again
The instrument cannot find a USB storage device
Make sure that the USB storage device is correctly installed and the USB icon
can be seen in the header bar (refer to Table 4 on page 26)
Remove the USB storage device and make sure the USB icon is no longer seen in
the header bar, then install the device again and make sure that the icon can
be seen (refer to Table 4 on page 26)
Application {application name}: maximum number of applications is reached
The maximum number of applications for each line has been reached when copying applications to the instrument from the USB storage device
Remove any unwanted applications, then push the Home key to return to the home screen. Remove the USB storage device and make sure the USB icon is no longer seen in the header bar, then install the device again and import the new application again
52
Troubleshooting
Table 11 USB storage device (continued)
Error/Warning
Description
Possible solution
Application {application name}: requires at least one titrant that cannot be installed
The titrant needed by the application cannot be installed on the instrument because the applications currently installed use another titrant
Single syringe instrument:
Remove all installed applications, then push the Home key to return to the
home screen. Remove the USB storage device and make sure the USB icon is no
longer seen in the header bar, then install the device again and import the
new application again
Two syringe instrument where the application uses only one titrant:
Remove all installed applications from the line of applications using that
titrant and then push the Home key to return to the home screen. Remove the
USB storage device and make sure the USB icon is no longer seen in the header
bar, then install the device again and import the new application again
Two syringe instrument where the application uses two titrants:
· If the two titrants are not already used by the installed applications,
remove all installed applications, then push the Home key to return to the
home screen. Remove the USB storage device and make sure the USB icon is no
longer seen in the header bar, then install the device again and import the
new application again
· If one of the two titrants is already installed, remove all installed
applications from the line of applications using the other titrant and then
push the Home key to return to the home screen. Remove the USB storage device
and make sure the USB icon is no longer seen in the header bar, then install
the device again and import the new application again
Application {application name}: requires too many titrants for this instrument model configuration
The instrument has a single syringe and the application needs a two syringe instrument
Change to a two syringe instrument
Error while saving application {application name}
Error when copying from the USB storage device to the instrument memory
Contact technical support
Unable to read applications from device. Applications have been removed, please load them from USB flash drive
While updating the application tiles on the display, an installed application has been detected as corrupt
Remove the corrupt application and try to load it again
Application {application name} The selected application file is
corrupted
invalid
Try to load the original application file again, or contact technical support for a replacement file
Application {application name} The hardware does not support
incompatible with hardware
the application
Change to a compatible instrument
Application {application name} (too new model)
This selection is not allowed because the instrument software only supports older application files
Update the instrument software
53
Troubleshooting
Error/Warning Application {application name} (untrusted)
Application {application name} (obsolete)
Application {application name} (syringe to replace)
Error while serializing data
Cannot write to USB mass storage
Table 11 USB storage device (continued)
Description
Possible solution
This selection is not allowed because the application has not been authenticated
Contact technical support to get an authenticated application file
The selection is allowed. When the The automatic update will set the new application
application is exported, it will
parameters to the default values. It is not
automatically update to the latest recommended to use an obsolete application, but to
version
install the latest version
The selection is allowed but the syringe recommended in the application file is not the one installed on the instrument
Change the installed syringe to the one recommended by the application (refer to Syringe management on page 43)
Error when creating a file on the USB storage device
Change or format the USB storage device and try the export again
Remove the USB storage device and make sure the USB storage device is not
installed USB icon is no longer seen in the header bar, then
install the device again try the export again
USB storage device is corrupt
Change or format the USB storage device and try the export again
Error/Warning
Edit user failed. Be sure that name {user name} is not already used
Fail to save the modification of the application
Impossible to remove application {application name}
Table 12 Data updates Description The update to the operator name cannot be
done The update to the application data cannot be done
The application cannot be erased
Error while deleting data
The data cannot be erased
Possible solution
Check that the name is not already used
Try again, if the problem continues, contact technical support Try again, if
the problem continues, contact technical support Try again, if the problem
continues, contact technical support
Table 13 Battery
Error/Warning
Description
Possible solution
Battery voltage low
Battery voltage is below 2.2 V. The date and time are no longer available
Contact technical support
Set the date and time again. If the date and time Realtime clock has been lost
The date and time are no longer available are not available the next time the
instrument is
set to on, contact technical support
Table 14 Balance
Error/Warning
Description
Possible solution
Format of message received from the balance is not supported
The data received from the balance is not compatible with the format of messages accepted by the instrument
Configure the balance to be compatible with the format of messages accepted by the instrument (refer to Install a balance on page 21)
No connection with balance
The instrument is not receiving data from the balance
Check the balance cable is installed correctly
The measurement received is out The weight sent by the balance is not in the Adjust the sample. Adjust the acceptance
of range
acceptance limits
limit for the application
54
Troubleshooting
Table 15 Syringe verification
Error/Warning
Description
Possible solution
Format of message received from the balance is not supported
The data received from the balance is not compatible with the format of messages accepted by the instrument (fully automated mode only).
Configure the balance to be compatible with the format of messages accepted by
the instrument (refer to Install a balance on page 21)
Make sure that the weight measurement is stable and did not get to the maximum
weight.
No connection with balance
The instrument is not receiving data from the balance (fully automated mode only).
Make sure that the balance cable is installed correctly.
Temperature sensor not detected
The instrument is not receiving data form the temperature sensor (fully and partially automated modes only)
Make sure that the temperature sensor is installed and connected correctly.
Incorrect input value
The input value is out of range (fully and partially automated modes only).
Make sure that the syringe verification configuration values are correct.
No operator recorded
The operator value is not defined on the syringe verification screen.
Set an operator on the syringe verification configuration.
Serialization error
There was an error during the results export.
Remove the USB storage device and make sure the USB icon is no longer seen in the header bar, then install the device again try the export again. Try again, if the problem continues, contact technical support.
USB mass storage writting Error when exporting data to the USB
error
storage device
Make sure that the USB storage device is correctly installed and the USB icon can be seen in the header bar (refer to Table 4 on page 26).
55
Troubleshooting
56
Section 10 Replacement parts and accessories
WARNING
Personal injury hazard. Use of non-approved parts may cause personal injury, damage to the instrument or equipment malfunction. The replacement parts in this section are approved by the manufacturer.
Note: Product and Article numbers may vary for some selling regions. Contact the appropriate distributor or refer to the company website for contact information.
Table 16 Replacement parts and accessories
Description
Item no.
Syringe 2.5 mL, glass Syringe 5 mL, glass Syringe 10 mL, glass Syringe 25 mL, glass
LZE100 LZE101 LZE102 LZE103
O-ring for 2.5 mL syringe O-ring for 5 mL syringe O-ring for 10 mL syringe O-ring for 25 mL syringe
LZE104 LZE105 LZE106 LZE107
Set of beakers 50 mL (5x) Set of beakers 150 mL (5x)
LZE108 LZE109
Delivery tubing with anti-diffusion tip
LZE112
Set of tubes (2x) for syringe, suction & delivery
Set of tubes (2x) for pump, suction & delivery
LZE114 LZE115
57
Replacement parts and accessories
Table 16 Replacement parts and accessories (continued)
Description
Item no.
Bottle stopper GL25 Bottle stopper GL45 Bottle stopper S40 Bottle stopper GL32
LZE116 LZE117 LZE118 LZE186
Glass bottle, 1L
LZE119
Desiccant tube empty with cotton
Desiccant tube filled with molecular sieve
LZE120 LZE121
Conical adapter NS14.5/23
Conical adapter, large cut (for 7.5 mm diameter)
LZE122 LZE182
Tube fitting (2x)
LZE124
Spare pump cassette
LZE125
58
Replacement parts and accessories
Table 16 Replacement parts and accessories (continued)
Description
Item no.
Magnetic stir bar, PTFE, 20 x 6 mm (5x) LZE136
Tube holder, 4 positions
LZE141
Sample leveling pump
LZE142
Propeller stirrer, 70 mm shaft
LZE143
Power supply (without power cable)
LZE144
Power cable (EU)
YAA080
59
Replacement parts and accessories
Table 16 Replacement parts and accessories (continued)
Description
Item no.
Power cable (US)
XLH055
Power cable (UK)
XLH057
RS-232 adapter cable
LZE145
Syringe protection cover
LZE156
Electro-valve block and connector
LZE165
Sensor storage tubes
LZE185
60
Replacement parts and accessories
Table 16 Replacement parts and accessories (continued)
Description
Item no.
RS-232 cable for balance connection to LZE196 TitraLab
Thermo-Drucker USB printer
AT1000/KF1000 syringe volume verification kit
LQV161.99.10000 LZE228
Table 17 Electrodes and electrode accessories
Description
MTC301, platinum combined electrode, 1 m cable MTC306, silver combined
electrode, 1 m cable MTC695, Pt-Pt electrode, 1 m cable PHC705, pH probe, red
rod, glass, general purpose, standard PHC725, pH probe, glass PHC805, pH
probe, glass, general purpose CDC401 conductivity probe, standard, 1 m cable
ISECa calcium combined selective Legacy adapter OPT300 photocolorimetric probe
PTM450, NP photocolorimetric titration module, without power pHG311-9 pH
electrode, pH 0-14, FX pHG301-9 pH electrode, glass REF251 reference
electrode, red rod, double junction, banana CL114 cable FX/COAX/1m/BNC REF361
reference electrode, Ag/AgCl, reverse sleeve, FX Adaptor BNC male to banana
REF451 reference electrode, calomel, double junction, FX ISE25Cu-9 ion
selective, copper, FX CL111 cable FX/COAX/1m/banana
Item no.
MTC30101 MTC30601 MTC69501 PHC70501 PHC72501 PHC80501 CDC40101 LZW9660C.97.002
LZV662 E71T001 X61T005 E11M004 E11M001 E21M001 A94L114 E21M003 LZE184 E21M005
E41M006 A94L111
61
Replacement parts and accessories
62
Appendix A Change application parameters
Parameter Name Advisable syringe
NOTICE
The applications installed on the instrument have been pre-defined to optimize
the measurement process. Changing these default application parameters will
have an effect on the measurement process and measurement results. Only
qualified personnel should change these parameters or use the instrument in
Expert mode. Refer to the application note before changing any parameters.
NOTICE
In Basic mode changes to parameters are secure. In Expert mode changes to
parameters are not secure and can cause the application to run incorrectly.
NOTICE
The Active parameter is available to change in some parameter groups. It
specifies if the method should be used during the analysis. Changing this from
Yes to No means that the method will not be used which will have an effect on
the measurement process and measurement results.
NOTICE
The Hide result parameter (e.g. R2 hide, R3 hide, etc.) is available to change
in some parameter groups. It specifies if the result is shown on the display.
Changing this from Yes to No means that the calculated measurement result will
not be shown. This will not have an effect on the measurement process and
measurement results.
The parameters available for change can be different for each instrument configuration and the application being edited. The parameters marked with an “x” are available for change.
Table 18 Application
Description
Basic mode Expert mode
Name of the application
x
x
The application has been designed with this type of syringe
Parameter Name Amount Unit Min. amount Max. amount Resolution
Table 19 Sample Description Name of the sample Amount of the sample Unit of the sample Minimum permitted sample amount Maximum permitted sample amount Number of decimals to show for the sample amount
Basic mode x x
Expert mode x x x x x x
Parameter Name
Description Name of the QC
Table 20 QC Basic mode x
Expert mode x
Parameter Description
Description Description of the blank
Table 21 Blank
Basic mode x
Expert mode x
63
Change application parameters
Table 22 Electrode
Parameter
Description
Basic mode Expert mode
Type
Type of measurement electrode
Part of name
Part of the name used to identify matching electrodes if the preferred electrode is not connected
Recommended electrode Recommended electrode to be used for this analysis
x
Calibration frequency
Recommended frequency of calibration (0 = no reminder)
x
x
Stability criterion
Refer to the working procedure for the recommended value
x
Max. stability time
Maximum time limit for the stability check
x
Stirring speed
Speed of the stirrer during electrode calibration
x
x
pH electrode parameters
Stirring duration
Stirring duration before buffer measurement (0 = buffer
x
measurement with stirring)
Max. temp. variation
Maximum permitted temperature variation during calibration
Min. slope
Minimum permitted slope limit for the calibration result
x
Max. slope
Maximum permitted slope limit for the calibration result
x
Min. offset
Minimum permitted offset limit for the calibration result
x
Max. offset
Maximum permitted offset limit for the calibration result
x
Calibration mode
Set the electrode calibration mode
x
Buffer set
List of available buffers for electrode calibration
x
x
Number fixed buffers
The number of fixed buffers to use
Fixed buffer #n
Buffer to be used during calibration
x
Conductivity electrode parameters
Calibration mode
Set the electrode calibration mode
x
Standard
Standard used for electrode calibration
x
x
Min. cell constant
Minimum permitted cell constant for the calibration result
x
Max. cell constant
Maximum permitted cell constant for the calibration result
x
Temp. compensation
Follow Natural Water Standards ISO/DIS_7888
x
Linear temp. coeff.
Coefficient for linear temperature compensation mode
x
Reference temp.
Reference temperature for linear temperature compensation mode
x
PtPt electrode parameters
Working mode
Specify if the probe is used in imposed voltage/current (AC or DC)
x
Current (sample analysis) Set the value of the imposed current during sample analysis
x
Current (titrant calibration) Set the value of the imposed current during titrant calibration
x
Voltage (sample analysis) Set the value of the imposed voltage during sample analysis
x
Voltage (titrant calibration) Set the value of the imposed voltage during titrant calibration
x
64
Change application parameters
Parameter
Description
Table 23 Titrant
Name
Name of the titrant
Titrant concentration Nominal concentration of the titrant
Resolution
Number of decimals of the nominal concentration of the titrant
Unit
Unit of the titrant
Real concentration Real concentration of the titrant used for result calculation
Resolution
Number of decimals of the real concentration of the titrant
Location
The syringe that contains the titrant
Titrant calibration
Active
Select No to skip this method during titrant calibration
Calibration frequency Recommended frequency of titrant calibration (0 = no reminder)
Stirring speed
Speed of the stirrer during titrant calibration
Incremental addition
Predose type
Type of the predose (in volume or in ordinate)
Predose volume
Titrant volume added at the beginning of the titration
Predose ordinate
Ordinate measurement to reach to stop the predose
Predose speed
Speed in mL/min during the predose in ordinate
Delay
Stirring time before the titration starts
Max. vol. stop point Stops the titration when this volume is reached
Ordinate stop point Stops the titration when this ordinate is reached
Stop on last EQP
Stops the titration on the last equivalent point detection
Min. ordinate
Contact technical support before changing. The minimum ordinate value is used in the regulation algorithm during the dynamic addition
Max. ordinate
Contact technical support before changing. The maximum ordinate value is used in the regulation algorithm during the dynamic addition
Min. angle
Contact technical support before changing. The minimum tangent angle value is used in the regulation algorithm during the dynamic addition
Max. angle
Contact technical support before changing. The maximum tangent angle value is used in the regulation algorithm during the dynamic addition
Min. stability time
Minimum time after an increment addition
Max. stability time Maximum time after an increment addition
Stability criterion
Stability criterion after an increment addition
Increment size
Increment size when the addition is monotonic
Min. increment size Minimum increment volume when the addition is dynamic
Max. increment size Maximum increment volume when the addition is dynamic
EP detection
EP1 ordinate
Ordinate of this end point
Basic mode
x
Expert mode
x x x x x x
x
x
x
x
x
x
x x x x x x x x x
x
x
x
x x x x x x
x
65
Change application parameters
Parameter
Description
Table 23 Titrant (continued)
IP detection
Derivative filter
Contact technical support before changing. Number of points used for building the derivative
Detection threshold Contact technical support before changing. The minimum value of the derivative for inflexion point detection
IP1 min. ordinate
Minimum permitted value for this inflexion point
IP1 max. ordinate
Maximum permitted value for this inflexion point
Angle detection
Maximum abscissa
Contact technical support before changing. The maximum abscissa is used in the algorithm for equivalence calculation
Curve filter
Contact technical support before changing. Number of points used for building the titration curve
Curvature filter
Contact technical support before changing. Number of points used for the curvature calculation
Detection threshold Contact technical support before changing. The minimum value of the curvature for equivalence detection
Linearity threshold
Contact technical support before changing. The minimum value of the curvature used in the algorithm for equivalence calculation
EQP min. ordinate Minimum permitted value for this equivalence point
EQP max. ordinate Maximum permitted value for this equivalence point
Stop on flat signal Stops titration when a flat signal is detected
Derivative filter
Contact technical support before changing. Number of points used for building the derivative used in flat signal detection
Min. derivative
Contact technical support before changing. Minimum threshold on derivative for flat signal detection
Max. derivative
Contact technical support before changing. Maximum threshold on derivative for flat signal detection
Derivative number
Contact technical support before changing. Number of derivative values between the minimum and maximum thresholds to stop the titration on a flat signal
Titration calculation
Resolution
Maximum number of decimals to show for the real concentration of the titrant
Titrant cal. limit check Activate the titrant calibration result boundary check
Min. titrant conc.
Minimum value of the real concentration of the titrant
Max. titrant conc.
Maximum value of the real concentration of the titrant
Titrant cal. EQP index Index of the equivalence point used for the titrant calibration calculation
Standard name
Name of the standard
Standard amount
Amount of standard to be used for titer determination
Unit
Unit of the standard amount
Min. amount
Minimum amount of the standard
Basic mode
Expert mode
x x x x
x x x x x x x x x x x x
x
x x x x x x x x
66
Change application parameters
Parameter
Description
Table 23 Titrant (continued)
Max. amount
Maximum amount of the standard
Concentration
Concentration value of the standard
Unit
Unit of the concentration value of the standard
Resolution
Number of decimals of the concentration value of the standard
Standard equivalents Number of exchanged equivalents of the standard (H+; e-; …)
Titrant equivalents Number of exchanged equivalents of the titrant (H+; e-; …)
Molar weight
Molar weight of the standard
Basic mode
x
Expert mode
x x x x x x x
Parameter
Active Time Stirring speed Message
Active Reagent Pump ID Time Stirring speed
Active Time
Solution name Solution concentration Unit Resolution
Active Message Stirring speed
Active Message Stirring speed
Table 24 Methods Description
Agitation method Select No to skip this method during analysis Duration of the
stirring Speed of the stirrer during this method Information shown during the
analysis
Auxiliary addition method Select No to skip this method during analysis Name
of the reagent to add Pump identifier Duration of the pump activation Speed of
the stirrer during the addition
Leveling method Select No to skip this method during analysis Duration of the
pump activation
Autoleveling calibration Name of the solution used for autoleveling
calibration Concentration value of the standard Unit of the concentration
value of the standard Number of decimals for the concentration value of the
standard
Message method Select No to skip this method during analysis Information shown
during the analysis Speed of the stirrer during this method
Input value method Select No to skip this method during analysis Information
shown during the analysis Speed of the stirrer during this method
Basic mode Expert mode
x
x
x
x
x
x
x
x
x
x
x
x
x
x
x
x
x
x
x
x
x
x
x
x
x
x
x
x
x
x
x
x
x
67
Change application parameters
Parameter Resolution Hide Min. value Max. value
Active Max. stability time Stability criterion Stirring speed Result 1 (R1)
name R1 max. resolution R1 hide R1 limit check R1 min. R1 max. R1 QC min. R1
QC max.
Stirring duration Pump ID Addition duration Preparation duration
Addition
Active Stirring speed Measured parameter Predose type Predose volume Predose
ordinate Predose speed Delay Addition mode Min. ordinate
Table 24 Methods (continued)
Description
Basic mode Expert mode
Maximum number of decimals for the input value
The result is not shown if Yes is selected
x
x
Minimum permitted input value
x
Maximum permitted input value
x
Measurement method
Select No to skip this method during analysis
x
x
Time limit for the stability check
x
Refer to the working procedure for the recommended value
x
Speed of the stirrer during the measurement
x
x
Name of the result
x
x
Maximum number of decimals to show for the result
x
The result is not shown if Yes is selected
x
x
Activate the sample result boundary check
x
Minimum permitted result value
x
Maximum permitted result value
x
Minimum permitted QC result value
x
Maximum permitted QC result value
x
Sample batch preparation method
Duration of the stirring during the addition
x
x
Pump identifier
x
x
Duration of the addition of reagent by the pump
x
x
Duration of the sample batch preparation
x
x
Excess titrant addition method
Excess addition done immediately at application start or just before titration
x
x
Analysis titration method
Select No to skip this method during analysis
x
x
Speed of the stirrer during titration
x
x
Parameter measured by the probe
Type of the predose (in volume or in ordinate)
x
Titrant volume added at the beginning of the titration
x
x
Measurement ordinate to reach to stop the predose
x
x
Speed in mL/min during the predose ordinate
x
Stirring time before the titration starts
x
x
Titrant addition mode (monotonic or dynamic)
x
Contact technical support before changing. The minimum ordinate
x
value is used in the regulation algorithm during the dynamic
addition
68
Change application parameters
Table 24 Methods (continued)
Parameter
Description
Basic mode Expert mode
Max. ordinate
Contact technical support before changing. The maximum ordinate
x
value is used in the regulation algorithm during the dynamic
addition
Max. vol. stop point
Stops the titration when this volume is reached
x
Ordinate stop point
Stops the titration when this ordinate is reached
x
Stop on last EQP
Stops the titration on last equivalent point detection
x
Min. angle
Contact technical support before changing. The minimum tangent
x
angle value is used in the regulation algorithm during the dynamic
addition
Max. angle
Contact technical support before changing. The maximum tangent
x
angle value is used in the regulation algorithm during the dynamic
addition
Min. stability time
Minimum time after an increment addition
x
Max. stability time
Maximum time after an increment addition
x
Stability criterion
Stability criterion after an increment addition
x
Increment size
Increment size when the addition is monotonic
x
Min. increment size
Minimum increment volume when the addition is dynamic
x
Max. increment size
Maximum increment volume when the addition is dynamic
x
Back titration mode
Excess addition mode
x
Excess vol.
Volume of the excess titrant
x
Excess titrant name
Name of the excess titrant
Excess titrant conc.
Nominal concentration of the excess titrant
x
Resolution
Number of decimals of the concentration value of the excess titrant
x
Excess titrant conc. unit Unit of the excess titrant concentration
x
Real conc. of excess titrant Real concentration of the excess titrant
x
x
Excess equivalents
Number of exchanged equivalents of the excess (H+; e-; …)
x
Sample equivalents
Number of exchanged equivalents of the sample (H+; e-; …)
x
Titrant equivalents
Number of exchanged equivalents of the titrant (H+; e-; …)
x
EP detection
EP1 ordinate
Ordinate of this end point
x
IP detection
Derivative filter
Contact technical support before changing. Number of points used
x
for building the derivative
Detection threshold
Contact technical support before changing. The minimum value of
x
the derivative for inflexion point detection
IP1 min. ordinate
Minimum permitted value for this inflexion point
x
IP1 max. ordinate
Maximum permitted value for this inflexion point
x
Angle detection
Maximum abscissa
Contact technical support before changing. The maximum
x
abscissa is used in the algorithm for equivalence calculation
69
Change application parameters
Parameter Curve filter
Curvature filter
Detection threshold
Linearity threshold
EQP min. ordinate EQP max. ordinate Stop on flat signal Derivative filter
Min. derivative
Max. derivative
Derivative number
Result x (Rx) name Rx max. resolution Rx hide Rx limit check Rx min. Rx max.
Rx QC min. Rx QC max. Rx unit Rx EQP index Rx molar weight Rx sample
equivalents Rx titrant equivalents
Result x (Rx) name Rx max. resolution Rx hide Rx limit check Rx min.
Table 24 Methods (continued)
Description
Basic mode Expert mode
Contact technical support before changing. Number of points used
x
for building the titration curve
Contact technical support before changing. Number of points used
x
for the curvature calculation
Contact technical support before changing. The minimum value of
x
the curvature for equivalence detection
Contact technical support before changing. The minimum value of
x
the curvature used in the algorithm for equivalence calculation
Minimum permitted value for this equivalence point
x
Maximum permitted value for this equivalence point
x
Stops titration when a flat signal is detected
x
Contact technical support before changing. Number of points used
x
for building the derivative used in flat signal detection
Contact technical support before changing. Minimum threshold on
x
derivative for flat signal detection
Contact technical support before changing. Maximum threshold on
x
derivative for flat signal detection
Contact technical support before changing. Number of derivative
x
values between the minimum and maximum thresholds to stop the
titration on a flat signal
Titration calculation
Name of the result
x
x
Maximum number of decimals to show for the result
x
The result is not shown if Yes is selected
x
x
Activate the sample result boundary check
x
Minimum permitted result value
x
Maximum permitted result value
x
Minimum permitted QC result value
x
Maximum permitted QC result value
x
Unit of the result
x
Index of the equivalence point used for the result calculation
x
Molar weight of analyte used for the result calculation
x
Number of exchanged equivalents of the sample (H+; e-; …)
x
Number of exchanged equivalents of the titrant (H+; e-; …)
x
Titration calculation using an equation
Name of the result calculated with the equation
x
x
Maximum number of decimals to show for the result
x
The result is not shown if Yes is selected
x
x
Activate the sample result boundary check
x
Minimum permitted result value
x
70
Parameter Rx max. Rx QC min. Rx QC max. Rx equation Rx unit Rx user value
Change application parameters
Table 24 Methods (continued) Description Maximum permitted result value Minimum permitted QC result value Maximum permitted QC result value Equation used for the result shown Select the result unit Value that may be used in the equation computation as Fx
Basic mode Expert mode x x x
x
x
x
x
71
Change application parameters
72
Appendix B Frequently asked questions
Table 25 Application files
Question
Cause
Procedure
Why can’t I load any applications
Wrong file placement on the USB storage device
The user is not in the home screen
Make sure that the file path on the USB storage device is correct
Push the Home key to make sure that you are in the home screen before
connecting the USB storage device
Why is the instrument not recognizing the applications USB storage device, even though I have removed and reconnected the device and I see the USB icon in the header bar
Reconnecting the device has been done too quickly
Remove the device and wait until the icon disappears from the header bar, then push the Home key to make sure that you are in the home screen before reconnecting the device
Question
Why does the volume delivered not correspond to the volume displayed
Cause
Table 26 Titration
The volume of the installed syringe is different from the syringe configuration
Procedure
Use the recommended syringe for the application and make sure the volume is
correct
Table 27 Mechanical
Question
Cause
Procedure
Why is the equivalent point not being detected at the expected volume
Air bubbles are trapped in the tubes
Select the Purge option on the instrument to purge the tubes of air bubbles (refer to Prepare the instrument for measurement on page 30)
How can I remove an air bubble that is trapped on top of the syringe
Air bubbles are trapped in the syringe
Select the Purge option on the instrument to purge the syringe of air bubbles (refer to Prepare the instrument for measurement on page 30)
Why is titrant leaking along the sealing above the electrovalve
The tubes have not been correctly installed
Turn the tube connector until a “click” is heard
Why is titrant leaking along the sealing below the electrovalve
The syringe has not been installed tight enough
The electrovalve is leaking
Make sure that the syringe is installed correctly
Change the electrovalve as described in Replace the syringe electro-valve
block on page 42
Why is the titrant not being delivered into the tubes
The titrant bottle is empty or the tube is not correctly installed in the bottle
Make sure that the titrant bottle is installed correctly
The electrovalve is blocked Change the electrovalve as described in Replace
or defective
the syringe electro-valve block on page 42
On my two syringe instrument, why is the titrant not being delivered into the beaker but back into the titrant bottle
The procedure is not being done on the correct syringe
Select the Syringe activation option on the instrument, and Toggle the
syringes to make sure that the correct syringe is being used in the
application
The active syringe is not the correct syringe
Erase all the installed applications and install them again. The applications on line 1 will be allocated to syringe 1 and the applications on line 2 will be allocated to syringe 2. Make sure the titrant and installation is correct for the syringe (refer to Install the titrant and the reagent on page 16)
73
Frequently asked questions
Question
On my two pump instrument, using the Pump activation option, why is the
reagent not being delivered into the beaker
Table 27 Mechanical (continued)
Cause
Procedure
The procedure is not being done on the correct pump
Select the Pump activation option on the instrument, and Toggle the pumps to make sure that the correct pump is being used
The active pump is not the Change to expert mode and change the name of
correct pump
the pump
The pump is defective
Change the pump as described in Pump cassette replacement on page 44
Table 28 Password Question How can I retrieve my password to access expert mode
Procedure Contact technical support
74
Section 13 Configure the instrument
1. From the home screen, select Settings. Refer also to Menu structure on page 26. 2. Select an option, then push Select.
Option
Description
Applications
Changes (refer to Change the application settings on page 38), makes copies, exports and removes application data. Make sure that the duplication function does not make more than five applications for each syringe installed.
Operators Date + Time Brightness Sounds Language
Adds, changes and removes operators. Sets the instrument date and time. Sets the brightness of the display. Sets the sound options. Sets the language.
Network
Give a name to the instrument. This name is used to connect the instrument to a PC. If a printer is connected, this name is printed on the hard-copy output. Restart the instrument if the name is changed.
Legacy settings Specify the sensor data when the legacy adapter is used.
Info
Shows information about the instrument and the attached hardware.
Restore Defaults
Sets the instrument to the default configuration. The restored settings are:
· The language is set to English · All password security is removed · The
security password is set to 0000 · No sound on: Key press, Information and
Analysis results OK · Sound on: Instrument ready, Instrument switch off,
Errors and
Analysis results not OK · The application parameters view is set to basic mode
· Sets the syringe to empty when the instrument is set to off · The
temperature display unit is set to °C · No print of the measurement curve · No
print of the derivative curves · No balance is connected · No propeller
stirrer is connected · The default stirring is set to 10% · The user is set to
“Default user”
75
Configure the instrument
Option Options
Security
3. Push Back.
Description
Sets the following options:
· Set the application parameters view to expert or basic mode · When the
instrument is set to off, sets the syringe to empty into the
titrant bottle · Changes the temperature display unit · Prints the measurement
and derivative curves if a printer is connected · Specify if a balance is
connected · Specify if an external propeller stirrer is connected.
Note: When the instrument is set to on, the application parameters view is
always set to basic mode. Changes made to application data with the instrument
in expert mode are kept.
Change the password. Specify which of these options are password protected:
· Settings (all items except Info) · Maintenance schedule and summary · Delete
data log · Export data log · Electrode calibration · Titrant calibration ·
Sample volume calibration · Syringe verification test
76
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