HANNA instruments HI9810422 Wireless pH Tester for Field Instruction Manual

June 4, 2024
HANNA instruments

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Wireless pH Tester for Field
with a built-in specialized electrode
HANNA instruments HI9810422 Wireless pH Tester for
Field
INSTRUCTION MANUAL

HI9810422 Wireless pH Tester for Field

Dear
Customer
Thank you for choosing a Hanna Instruments product.
Please read this instruction manual carefully before using this instrument.
This manual will provide you with the necessary information for the correct use of this instrument, as well as a precise idea of its versatility.
If you need additional technical information, do not hesitate to e‑mail us at tech@hannainst.com or view our contact list at www.hannainst.com.
All rights are reserved. Reproduction in whole or in part is prohibited without the written consent of the copyright owner,
Hanna Instruments Inc., Woonsocket, Rhode Island, 02895, USA.

PRELIMINARY EXAMINATION

Remove the tester and accessories from the packaging and examine them carefully. For further assistance, please contact your local Hanna Instruments office or email us at tech@hannainst.com.
Each HI9810422 is supplied with a starter kit consisting of:

  • pH 4.01 buffer solution, 20 mL sachet (2 pcs.)
  • pH 7.01 buffer solution, 20 mL sachet (2 pcs.)
  • Electrode cleaning solution, 20 mL sachet (2 pcs.)
  • Electrode storage solution, 13 mL dropper bottle (1 pc.)
  • 3V Lithium battery – CR2032
  • Instrument quality certificate and Instruction manual
    Note: Save all packing material until you are sure that the tester works correctly. Any damaged or defective item must be returned in its original packing material with the supplied accessories.

SPECIFICATIONS

Range pH 0.00 to 12.00 pH
mV * pH/mV conversion
Temperature** –5.0 to 70.0 °C (23.0 to 158.0 °F)
Resolution pH 0.01 or 0.1 pH
mV * 0.1 or 1 mV
Temperature 0.1 °C; 0.1 °F
Accuracy pH ±0.05 pH
Temperature ±0.5 °C; ±0.9 °F
Calibration Up to three points or four points *
Temperature compensation Automatic (ATC) or Manual (MTC) *
Body material Polyetherimide (PEI) resin
Glass Low Temperature (LT)
Junction Ceramic
Reference cell Double, Ag/AgCl
Electrolyte Gel
 Tip / Shape Dome
Outer diameter 12 mm (0.47”)
Length 100 mm (3.9”)
Battery type 3V Lithium – CR2032
Battery life Approximately 1000 hours (500 hours with Bluetooth enabled)
Environment 0 to 50 °C (32 to 122 °F)
Casing IP65 ingress protection
Dimensions 51 x 175 x 21 mm (2.0 x 6.9 x 0.8”)
Weight 50 g (1.8 oz.)

* Available with Hanna Lab App
Measuring outside the recommended operating temperature range may damage the gel electrolyte and void the product warranty.
Note:** The tester can display measurements from –2.00 to 16.00 pH. Measurements outside of the pH range will flash. In this case, assess the integrity of the tester and the type of measured sample.

GENERAL DESCRIPTION & INTENDED USE

HI9810422 is a professional wireless pH tester, part of the Hanna Instruments HALO2 family.

  • The integrated Bluetooth module allows the tester to be connected to a compatible smart device with the Hanna Lab App.
  • The tester has a compact, waterproof casing, and automatic pH calibration at up to three points, or four points when used with the Hanna Lab App.
  • Automatically compensated temperature readings are displayed on a large LCD.
  • Accurate and easy to use, the tester is ideal for field measurements due to its durability.

Operating Modes
The HI9810422 can be used as a stand-alone pH tester or connected to the Hanna Lab App.
The Hanna Lab App turns a compatible smart device into a full-featured pH meter. Features include electrode condition,
GLP with time-stamp, live readings, mV resolution, manual temperature compensation, stability criteria, calibration reminder, pH (mV) and temperature alarms, tester ID, and data sharing.
Probe Features
The HI9810422 features a PEI resin body that is easy to clean and resistant to many aggressive chemicals.
The double junction design presents a silver-free electrolyte solution interacting with the sample, making the electrode less susceptible to clogging and guaranteeing a fast response and stable reading.
A built-in temperature sensor at the tip of the pH electrode allows for rapid determination of the sample temperature and a high-accuracy temperature reading.

FUNCTIONAL DESCRIPTION & LCD DISPLAY

Front & Back view

HANNA instruments HI9810422 Wireless pH Tester for Field - LCD
DISPLAY

LCD display

HANNA instruments HI9810422 Wireless pH Tester for Field - LCD DISPLAY
1

1 Calibration indicator 6 Temperature compensation
2 Stability indicator 7 Second LCD line
3 Battery percentage indicator 8 Temperature unit
4 Battery icon 9 First LCD line
5 Bluetooth icon 10 Measurement unit

GENERAL OPERATIONS

Turning the Tester On & Off

  • Turn the tester face down on a clean, dry surface. Rotate the battery cover on the back of the tester counterclockwise and set it aside. Remove the battery insulation film.
  • Press the ON/OFF button to turn the tester on or off. The initialization screen displays all LCD segments, followed by the battery percentage. The tester enters measurement mode. Before the tester turns off, “OFF PWR” is displayed briefly.
  • Press and hold the ON/OFF button to turn the tester off when connected to Bluetooth.

Battery Replacement

  1. Turn off the tester. Turn the tester face down and rotate the battery cover counterclockwise.

  2. Set the battery cover aside. Press the metallic pin to push the old battery out.

  3. Place the new battery with a positive (+) sign facing out.

  4. Reset the date and time in setup, or connect to the Hanna Lab App to update it automatically.

  5. Align the mark on the cover with the open lock icon (   ) on the case. Rotate the cover clockwise until the mark on the cover aligns with the closed lock icon ( ). Metallic pin
    Note: Only use specified battery type. Dispose of old batteries in accordance with local regulations.

SETUP

The Setup button is located inside the battery compartment. After the Setup configuration, replace the cover.
Setup Menu Navigation

  • Press the Setup button to enter Setup mode and navigate menu items.
  • To exit Setup mode, press the Setup button after the “**SEE TIME”** option is displayed.
  • Press the ON/OFF button to configure menu item options.

Temperature Unit
Option: °C or °F
Press the ON/OFF button to select desired temperature unit.

HANNA instruments HI9810422 Wireless pH Tester for Field -
Icon3

Auto-Off Interval
Option: 8, 60 min., or “—-” (disabled)
Press the ON/OFF button to select the desired interval.
To save battery life, after the selected auto-off interval has elapsed, the tester will automatically turn off.
Calibration PointsHANNA instruments HI9810422 Wireless pH Tester for
Field - Icon4

Option: 2P or 3P
Press the ON/OFF button to select between up to two- or up to three-point calibration.
Buffer Set

HANNA instruments HI9810422 Wireless pH Tester for Field -
Icon5

Option: 7.01 pH (Hanna) or 6.86 pH (NIST)
Press the ON/OFF button to select the calibration buffer set (Hanna or NIST).
pH Resolution
Option: 0.01 pH or 0.1 pH
Press the ON/OFF button to select resolution.
Bluetooth Wireless Mode
HANNA instruments HI9810422 Wireless pH Tester for Field -
Icon6

Option: On, PAIr, or OFF
Press the ON/OFF button to select the Bluetooth option at start-up.
Bluetooth Pairing
Option: dEL PAIr
Press the ON/OFF button to delete the saved paired device.
Date & Time
Option: SEt TIME
Press the ON/OFF button to set the date and time.
Option: YEAR, MO, DAY, HOUR, and MIN
HANNA instruments HI9810422 Wireless pH Tester for Field -
Icon8Use the Setup button to select the option and press the ON/OFF button to change the selected option.

BLUETOOTH

With “ or “On BLU” selected in Setup, the Bluetooth icon (&) will blink for up to 45 seconds, indicating the tester is in discoverable mode. Once connected, the icon will stop blinking. If not connected, the icon is not displayed.

  • Select “ ”, to enable Bluetooth without bonding.
  • Select “ ”, to enable Bluetooth with bonding. A 6-digit bonding pin is displayed the first time the tester and smart device are paired. Once the devices are paired, the bonding pin is not required when reconnected.
  • Select “ ”, to disable Bluetooth.
  • Select “ ”, to delete all paired devices. If PAIr BLU is enabled, a bonding pin will need to be re-entered.

HANNA LAB APPLICATION

  • The Hanna Lab App is available on the App Store ®and on Google Play.
  • Consult the Help section of the application for information on calibration, measurement, data logging, and sharing.
  • When the tester is in discoverable mode, it will appear in the list of “Available Devices”.
  • Within the application, tap “Connect” to pair the tester with the device. All readings are transmitted directly to the application.

Tag a Measurement
Once connected to the application, the ON/OFF button can be pressed to tag the current reading.

  • Press the ON/OFF button from measurement mode. The display shows “ ”, followed by “- TAG”.
  • The reading on the application will flash green and the note icon ( ) will be displayed. Tap the note icon ( ) to add an annotation.
    HANNA instruments HI9810422 Wireless pH Tester for Field -
Icon116

CALIBRATION

Preparation & Guidelines

  1. Unscrew the top collar to vent the cap before removing the probe from the plastic storage tube. Save cap and collar for probe storage.
  2. Rinse off any storage solution or salts that may be on the body.
  3. Verify there is solution inside the pH bulb by shaking the probe down to restore continuity as the solution may have moved up the stem during shipping.
  4. For best results, use a rinse beaker and a separate calibration beaker for each buffer. Discard rinsing buffers after use. Procedure
    For most applications, it is recommended to start with a pH 7.01 buffer (or pH 6.86).
    To restore factory defaults, press and hold the ON/OFF button. “ R” is displayed.
    Note: It is recommended to calibrate the electrode with buffers at the temperature it will be used at.
    App Store is a trademark of Apple, Inc.
    Google Play and the Google Play logo are trademarks of Google LLC.

Stand-Alone Tester (Up to Three-Point Calibration)

  1. Rinse the electrode tip with purified water and blot dry. Then rinse with the buffer being used for calibration.

  2. Press and hold ON/OFF button until “CAL MODE” is displayed.

  3. When  USE” or “ ” is displayed with “ ” tag blinking, place the tip of the electrode in the correct buffer.

  4. When the buffer has been recognized, “REC“ is displayed.
    “WAIT” is displayed with the stability indicator ( ) blinking until the reading is stable. Wait until the measurement is stored and the stability indicator disappears.
    HANNA instruments HI9810422 Wireless pH Tester for Field -
Icon22

  5. To save a one-point calibration and return to measurement mode, press the ON/OFF button.
    “CAL SAVE” is displayed briefly. With 2P option selected

  6. Place the tip of the electrode in the second buffer rinse beaker, then in the second calibration buffer. Wait until the measurement is stored and the stability indicator disappears.

  7. After the second point has been stored, “CAL SAVE” is displayed briefly and the tester will return to measurement mode automatically.
    With the 3P option selected

  8. Place the tip of the electrode in the second buffer rinse beaker, then in the second calibration buffer. Wait until the measurement is stored and the stability indicator disappears.
    7. Place the tip of the electrode in the third buffer rinse beaker, then in the third calibration buffer. Wait until the measurement is stored and the stability indicator disappears.
    8. After the third point has been stored, “CAL SAVE” is displayed briefly and the tester will return to measurement mode automatically.

With Hanna Lab App (Up to Four-Point Calibration)
Connect the tester to the Hanna Lab App and follow the calibration procedure.
See the App Help section for the calibration procedure.

CARE & MAINTENANCE

  • Never immerse the tester over the maximum immersion level.
  • Fresh buffers should be used for each calibration. Once the sachets are opened the buffer value can change over time.
  • If the electrode is slow or sluggish, soak it in the cleaning solution for 20 minutes. Rinse with water and hydrate the electrode in storage solution for a minimum of 30 minutes before calibrating.
  • If measurements are taken successively, rinse the probe thoroughly in distilled or deionized water to eliminate cross-contamination between measurements.

Storage
To ensure a quick response, the glass tip and junction should be kept hydrated.

  1. When not in use, add a few drops of storage solution to the storage cap. If a storage solution is not available, a pH 4.01 or pH 7.01 buffer can be used.
    Note: Do not store the electrode in distilled or deionized water.

  2. Place the probe tip into the cap and gently tighten the collar.

WARNING & ERROR MESSAGES

| “—- WRONG” displayed during calibration.
Invalid buffer.
Check the buffer value and use a fresh buffer.
---|---
| The measured value displayed blinking.
The measured value is out of the electrode range.
Clean the electrode to improve the condition.
| Battery icon (!) displayed blinking.
If the battery is below 10 %, replace the battery.
| “BAtt DEAD” and the tester turns off.
Depleted battery, replace the battery.

ABBREVIATIONS

ATC Automatic Temperature Compensation
GLP Good Laboratory Practice
MTC Manual Temperature Compensation
NIST National Institute of Standards and Technology

ACCESSORIES

Ordering Information Product Description

pH Buffer Solution
HI50016-02| pH 1.68 buffer solution, 20 mL sachet (25 pcs.)
HI70004P| pH 4.01 buffer solution, 20 mL sachet (25 pcs.)
HI70006P| pH 6.86 buffer solution, 20 mL sachet (25 pcs.)
HI70007P| pH 7.01 buffer solution, 20 mL sachet (25 pcs.)
HI70009P| pH 9.18 buffer solution, 20 mL sachet (25 pcs.)
HI70010P| pH 10.01 buffer solution, 20 mL sachet (25 pcs.)
HI77400P| pH 4.01 & 7.01 buffer solution, 20 mL sachet (10 pcs., 5 each)
HI770710P| pH 10.01 & 7.01 buffer solution, 20 mL sachet (10 pcs., 5 each)
Electrode Cleaning Solution
HI700601P| Electrode cleaning solution for general use, 20 mL sachet (25 pcs.)
HI7073L| Protein cleaning solution, 500 mL
HI7074L| Inorganic cleaning solution, 500 mL
HI7077L| Oil & Fat cleaning solution, 500 mL
Electrode Storage Solution
HI70300L| Electrode storage solution, 500 mL
HI70300M| Electrode storage solution, 230 mL
HI70300S| Electrode storage solution, 30 mL dropper
HI9072| Electrode storage solution, 13 mL dropper

RECOMMENDATIONS FOR USERS
Before using this product, make sure it is entirely suitable for your specific application and for the environment in which it is used. Any variation introduced by the user to the supplied equipment may degrade the tester’s performance. For your and the tester’s safety do not use or store it in hazardous environments.
WARRANTY
HI9810422 is warranted for a period of one year against defects in workmanship and materials when used for its intended purpose and maintained according to instructions.  This warranty is limited to repair or replacement free of charge. Damage due to accidents, misuse, tampering, or lack of prescribed maintenance is not covered. If service is required, contact your local Hanna Instruments office. If under warranty, report the model number, date of purchase, serial number, and the nature of the problem.
If the repair is not covered by the warranty, you will be notified of the charges incurred. If the tester is to be returned to Hanna Instruments, first obtain a Returned Goods  Authorization (RGA) number from the Technical Service department and then send it with shipping costs prepaid. When shipping any product, make sure it is shipped back in compliance with shipping regulations, thoroughly cleaned and free of any chemicals, and is properly packaged for complete protection.
CERTIFICATION
All Hanna Instruments conform to the CE European Directives.
Disposal of Electrical and Electronic Equipment. The product should not be treated as household waste.
Instead, hand it over to the appropriate collection point for the recycling of electrical and electronic equipment, which will conserve natural resources.
Disposal of waste batteries. This product contains batteries, do not dispose of them with other household waste. Hand them over to the appropriate collection point for recycling. Ensuring proper product and battery disposal prevents potential negative consequences for the environment and human health. For more information, contact your city, your local household waste disposal service, or the place of purchase.
Regulatory Notices for the stand-alone, Bluetooth, low-energy module.
United States (FCC ) FCC ID: 2AA9B04. This device complies with FCC Rules, Part 15 Subpart C “Intentional Radiators” and Subpart B, Chapter §15.105. This equipment has been tested and found to comply with the limits for a Class A digital device, pursuant to part 15 of the FCC Rules. These limits are designed to provide reasonable protection gainst harmful interference when the equipment is operated in a commercial environment. This equipment generates, uses, and can radiate radio frequency energy and, if not installed and used in accordance with the instruction manual, may cause harmful interference to radio communications. Operation of this equipment in a residential area is likely to cause harmful interference in which case, users are required to correct the interference at their own expense.
Canada (ISED) IC: 12208A-04. This device complies with Industry Canada license-exempt RSS standard(s). Operation is subject to the following two conditions: (1) this device may not cause interference, and (2) this device must accept any interference, including interference that may cause undesired operation of the device.
Australia / New Zealand (RCM) BMD-300 complies with the AS/NZS 4268:2017.
Japan (MIC)
South Korea (KCC)
Brazil (ANATEL):
Contains ANATEL-approved module # 00820-21-05903.
Mexico (IFETEL): Este equipo contiene el módulo con IFT #: NYCE/CT/0146/17/TS.
Hanna Instruments reserves the right to modify the design, construction or appearance of its products without advance notice.

HANNA LOGO World
Headquarters
Hanna Instruments Inc.
Highland Industrial Park
584 Park East Drive
Woonsocket, RI 02895 USA
www.hannainst.com
MAN9810422
Printed in ROMANIA

References

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